Exxonmobil Chemical Patents Inc.

Exxon Chemical Patents, Inc.

John Richard Shutt

Hubertus Joseph Beckers

Raphael Frans Caers

Eddy Theophile Van Driessche

Peijun Jiang

Robert Olds Hagerty

Charles Stanley Speed

John Stephen Godsmark

Georges Marie Mathys

Luc Roger Marc Martens

Pradeep P Shirodkar

Luc R M Martens

Michael Peter Nicoletti

Patrick Brant

Stephen Harold Brown

Larry Lee Iaccino

Terry John Burkhardt

Kevin Bruce Stavens

Georges M K Mathys

David Ritchie Lumgair

Lawrence Carl Smith

Gerhard Luft

Randall B Laird

Jeffrey Alan Kabin

Anne Vera Macedo

Minquan Cheng

Douglas J McLain

Jeffrey J Phillips

Keith Holroyd Kuechler

Stephen Neil Vaughn

Kenneth Lewtas

Cor F Van Egmond

William Alois Weber

Helmut Fritz

Marcel Johannes Janssen

Jeffrey Lawrence Brinen

Steven E Silverberg

Luc Roger Martens

David R Lumgair, Jr

Michael J Veraa

Josef Kunkel

Raphael Frans Ivo Caers

Eddy Theophyle Andrea Van Driessche

Wilfried Borgmann

Gerhard Lauermann

Klaus Muller

Roland Walzl

Kenneth Lewias

Eddy Theophile Andrea Van Driessche

Luc Roger Mare Martens

Georges Maria Mathys

Benoit M Touzard

Roland Walzi

Luc RM Martens

Wilried Borgmann

Luc M R Martens

Hubertus J Beckers

Gerhard Franz Luft

Mixed butene streams containing butene-1 and isobutylene and optionally butene-2 are hydroformylated under conditions that hydroformylates all the monomers to yield a mixture of valeraldehydes. Higher temperatures and/or longer residence times and/or higher partial pressure of carbon monoxide than in conventional processes are used to ensure hydroformylation of all the monomers.

Hydroformylation of butenes

Mixed butene streams containing butene-1 and isobutylene and optionally butene-2 are hydroformylated under conditions that hydroformylates all the monomers to yield a mixture of valeraldehydes.

Processes related to the hydroformylation of butenes

Hydroformylation of butenes comprising isobutylene

This invention relates to a process to polymerize olefins comprising contacting a catalyst or catalyst system with olefin(s) in the presence of a fluorocarbon at a temperature above the onset melting point of the polymer. This invention also relates to a solution process to polymerize olefins comprising contacting a catalyst or catalyst system with olefin(s) in the presence of a fluorocarbon at a temperature above the onset melting point of the polymer.

Polymerization process

This invention, in one embodiment, is drawn to a process for forming olefin product by contacting an oxygenate with an olefin-forming catalyst under supercritical conditions to form an olefin product. This invention also relates to methods for activating molecular sieve catalyst, regenerating molecular sieve catalyst, and forming and/or disposing a co-catalyst within a molecular sieve catalyst, each under supercritical conditions.

Oxygenate to olefins process involving supercritcal conditions

This invention relates to a process comprising contacting an polymerization reactor effluent with a fluorinated hydrocarbon and thereafter recovering olefin polymer, where the fluorinated hydrocarbon is present at 5 volume % to 99 volume % based upon the volume of the effluent and the fluorinated hydrocarbon, and where the polymerization is a continuous polymerization of at least 75 mole % of hydrocarbon monomers, based upon the total moles of monomer present in the reactor.

Polymer recovery method

This invention relates to a multiple phase polymerization process to produce polyolefins comprising contacting olefins and a homogeneous catalyst or catalyst system at a temperature between the melting point of the dry polymer and 80&#xb0; C. below the melting point of the dry polymer in the presence of a fluorinated hydrocarbon. This invention also relates to a process to produce polyethylene comprising contacting a homogeneous catalyst or catalyst system with ethylene and from 0 to 40 weight % of one or more C3 to C40 olefin comonomer(s) in the presence of a fluorinated hydrocarbon and optionally a hydrocarbon solvent at a temperature below the reaction medium melting point. This invention also relates to a process to produce polypropylene comprising contacting a homogeneous catalyst or catalyst system with propylene and from 0 to 50 weight % of one or more of ethylene and C4 to C40 olefin comonomer(s) in the presence of a fluorinated hydrocarbon and optionally a hydrocarbon solvent at a temperature below the reaction medium melting point.

This invention is directed to a method of removing dimethyl ether from an olefin stream. The method includes distilling the olefin stream so that the dimethyl ether is separated out of the olefin stream with propane. The olefin stream can then be further distilled to provide a polymer grade ethylene stream and a polymer grade propylene stream, with each stream containing not greater than about 10 wppm dimethyl ether.

Method of removing dimethyl ether from an olefin stream

This invention relates to a continuous process to prepare olefin impact copolymers comprising producing a semi-crystalline olefin polymer in a first reactor and then transferring the reactor contents to a second reactor where a low crystallinity olefin polymer is produced in the presence of the semi-crystalline polymer, where a fluorinated hydrocarbon is present in the polymerization medium of the first reactor, the second reactor or both reactors.

Impact copolymers

Propylene streams obtained by the conversion of oxygenates to olefins are used as feeds for hydroformylation. The streams may contain measurable amounts of dimethyl ether without adversely impacting the hydroformylation.

Propylene hydroformylation

This invention is directed to methods of removing water and other condensable materials, as well as solids particles such as catalyst particles, from olefin product streams so as to reduce fouling in the liquid and vapor separation equipment. In order to reduce fouling or contamination in the condensing or quenching process, this invention includes adding a hydrocarbon to at least a portion of the condensed liquid fraction in an amount that effects separation of the liquid fraction into upper and lower fractions.

Separation of olefin vapor from liquid fraction to reduce fouling

This invention relates to a process to polymerize olefins comprising contacting, in a polymerization system, olefins having three or more carbon atoms with a catalyst compound, activator, optionally comonomer, and optionally diluent or solvent, at a temperature above the cloud point temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system, where the polymerization system comprises any comonomer present, any diluent or solvent present, the polymer product, where the olefins having three or more carbon atoms are present at 40 weight % or more.

Polymer production at supercritical conditions

This invention relates to a process to increase the amount of polymer solute in a polymerization medium or effluent comprising introducing a fluorocarbon into the polymerization medium or effluent in an amount effective to increase the amount of polymer solute in the polymerization medium or effluent by at least 3% without causing precipitation of polymer solute from the polymerization medium or effluent, as compared to the same polymerization medium or effluent without the fluorocarbon present. This invention also relates to a process to reduce the viscosity of a polymerization medium or effluent comprising introducing a fluorocarbon into the polymerization medium or effluent in an amount effective to reduce the viscosity of the polymerization medium or effluent by at least 3% without causing precipitation of polymer solute from the polymerization medium or effluent, as compared to the same polymerization medium or effluent without the fluorocarbon present.

The present invention provides various processes for producing polypropylene from an oxygenate-contaminated propylene-containing feedstock, preferably derived from an oxygenate to olefin reaction system. In one embodiment, the process includes providing a propylene-containing stream from an oxygenate to olefin reaction system, wherein the propylene-containing stream comprises propylene and an oxygenate. The propylene in the propylene-containing stream contacts a polymerization catalyst in a polymerization zone under conditions effective to polymerize the propylene to form the polypropylene.

Processes for forming polypropylene from an oxygenate-contaminated monomer feedstock

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Merchtem, Belgium

John Richard Shutt