Teledyne Industries, Inc.

John R Peterson

John C Haygarth

William A Crocker

Jon A Riesen

Lloyd J Fenwick

David R Lee

Timothy R McQueary

Matthew A Rossback

Kenneth C Ash

Bernard F Kieffer

Richard Myers

Robert S Yih

Richard S Puopolo

Donald Morris

Niobium, Nb, is refined from FeNb by electron beam melt refining. The amount of the impurities in the FeNb which form suboxides with oxygen is optionally determined. Sufficient oxygen is added to form oxides with these impurities. The electron beam melt refining process is carried out at a sufficiently high temperature and under a sufficiently low vacuum so that the impurities are removed as oxides from the liquid Nb and the purified Nb is recovered. Preferably the oxygen is added as an oxygen-containing compound such as Nb.sub.2 O.sub.5. The recovered Nb can be subjected to additional electron beam melt refining cycles to obtain the desired purity.

Electron-beam melt refining of ferroniobium

Ferroniobium, ferrotantalum and ferrovanadium alloys are hydrogenated to facilitate crushing then nitrided, and then acid-leached to produce a soluble iron nitride leachate and a niobium, tantalum or vanadium nitride residue which residue can be denitrided to yield the metal which can be recovered by melting.

Recovery of niobium metal

A process for separating a feed mixture of zirconium and petroleum coke containing traces amount of radioative materials by flotation process utilizing a plurality of flotation cells. The process comprises grinding the feed mixture, slurrying the ground feed mixture with water, treating the slurry with a flotation agent and a collector for the coke and subjecting the treated slurry to air sparging and agitation to create an overflow and an underflow. The overflow is then filtered to collect substantially zircon-free coke for further processing.

Method for separating coke from a feed mixture containing zirconium and

A process for the recovery of substantially pure zirconium values from zircon sand which also contains Ra, U, Hf, Pb and other metal values, comprising contacting zircon sand in a chlorinator with a chlorination medium to form an off-gas stream containing chlorides of Zr, Hf, Si, and tract U. The off-gas stream is passed to a condenser to remove volatile Si chlorides and thereby provide a product stream containing condensed chlorides of Zr, Hf and tract U, treating the product stream in acidic aqueous medium in a separation stage to separate the principal Hf values from the principal Zr values. Adjusting the pH of the resulting effluent to between about 3 to about 7 in a second stage to precipitate the trace U values. The residue stream is treated by

Zirconium-hafnium separation and purification process

A binderless coating comprising substantially pure zirconium oxide suspended in an aqueous zirconyl nitrate and ammonium hydroxide gel.

Zirconium-containing coating composition

A process relating to the hydrolysis of metal halides and their production of corresponding metal oxides by the hydrolysis of their chlorides and the calcining of the hydrolysis product is disclosed. Novel aspect including obviating the neutralizing step for the hydrochloric acid by using ammonia and disposing of the resulting ammonium chloride and the two step addition initially of metal halides to water until there is no observable positive heat of reaction and then adding the metal halide in amounts up to the stoichiometric quantity for the hydrolysis product obtained.

Method of hydrolyzing metal halides

A paint or coating composition which contains only pure Ziroconium containing compounds, and a small amount of NH.sub.4 (OH).sub.2 and acid is applied to the vertical walls of a vacuum arc furnace Copper crucible to form a stable, substantially uniform, coating thereon. The Zirconium coating composition of the present invention is free of Aluminum and Aluminum compounds and consists essentially of Zirconium Oxide suspended in a water-based Zirconyl Nitrate gel, to which small amounts of base and acid have been sequentially added. This coating eliminates the introduction of spurious impurities into the surface of the zirconium ingot formed during vacuum are melting of a zirconium compact.

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Salem, OR, United States of America

John R Peterson