Exxonmobil Chemical Patents Inc.

John Patrick Soisson

Robert Norman Webb

Michael Brendan Rodgers

Weiqing Weng

Molly Westermann Johnston

Michael B Rodgers

Yuan-Ju Chen

Jo Ann M Canich

Periagaram Srinivasan Ravishankar

Sunny Jacob

Porter Clarke Shannon

David Yen-Lung Chung

Oscar Oansuk Chung

Florin Barsan

Michael Francis McDonald

Richard Dwight Hembree

Marvin C Hill

Shawn W Mowry

Luke P Stephens

Christopher B Friedersdorf

Yuan-Ju (Ray) Chen

Kyle B Hancock

Molly W Upton

A process for producing a thermoplastic vulcanizate, the process comprising: (i) charging a reactor with an oil-extended olefinic copolymer rubber, where the rubber is synthesized by a single-site catalyst, characterized by a multi-modal molecular weight distribution, and includes greater than 10 parts by weight extender oil per 100 parts by weight rubber; (ii) charging the reactor, contemporaneously or sequentially with respect to the rubber, with a thermoplastic resin, an oil, and a cure system to provide a pre-vulcanized mixture; and (iii) mixing the rubber, thermoplastic resin, oil, and cure system at a temperature above the melt temperature of the thermoplastic resin to thereby cause dynamic vulcanization of the rubber and produce the thermoplastic vulcanizate.

Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM

The invention relates to purification of plasticizer, particularly for use in a polymer production process and plant. More particularly, the invention relates to purification of plasticizer, such as by gas stripping, for use in a process for in-line blending of polymer and plasticizer.

Purification of plasticizer and use thereof in a polymer production process and plant

To obtain an elastomeric composite crumb having a majority of the particle size distribution greater than 0.33 cm, the crumb is obtained by a process whereby the elastomeric composite comprises less than about 0.5 phr of a salt of a Cto Ccarboxylic acid, or 10 to 20 phr of a tackifying resin or a combination of both an absence of carboxylic acid and the presence of the tackifying resin. The use of one or both methods permits control of crumb particle size distribution in emulsion or solution processes for producing elastomeric nanocomposites. The elastomeric composite is also disclosed.

Filled elastomeric composite and process to control composite crumb size

An elastomeric nanocomposite contains: (a) at least one elastomer comprising units derived from isoolefins having from 4 to 7 carbon atoms; (b) at least 10 phr of a carbon black; and (c) at least 1 phr of a nanoclay; wherein when the nanocomposite is used in an article, the article has a gas permeation coefficient of 80.0 cc*mm/[m-day] at 40&#xb0; C. The carbon black may be graphitized to reduce interactions between the carbon black and the nanoclays. The elastomeric nanocomposite may, with or without the use of the graphitized carbon black, may calendared or extruded in such a manner as to orient the nanoclay platelets within the composition such that the oriented nanoclay elastomer nanocomposite has an orientation parameter of greater than 0.15.

Elastomeric nanocomposites, nanocomposite compositions, and methods of manufacture

A nanocomposite is formed from at least one copolymer and at least one nanofiller. The copolymer is formed of units derived from isoolefins having from 4 to 7 carbon atoms and multiolefins. The nanofiller comprising a surfactant wherein the surfactant has the structure of (RRRR)Nwherein Ris benzyl derived unit, which may or may not be substituted, wherein Ris selected from Cto Calkyls, Cto Calkenes, and Cto Caryls, and wherein Rand Rare the same or different and are independently selected from Cto Calkyls, Cto Calkenes, and Cto Caryls.

A nanocomposite comprising at least one elastomer and at least one nanofiller. The elastomer comprises units derived from isoolefins having from 4 to 7 carbon atoms and at least one multiolefin. The nanofiller comprise a layered filler and an amine modifier wherein the nanofiller is substantially free of any unassociated amines. By eliminating unassociated amines in the nanofiller, prior to contact with the elastomer, the nanocomposite has improved processability characteristics while maintaining desired impermeability characteristics.

An elastomeric nanocomposite is produced from an isobutylene-based polymer and a layered nanofiller. The process of preparing the nanocomposite includes the steps of a) polymerizing isobutylene monomers and multiolefin monomers to produce an isobutylene-based polymer; b) completing at least one mass transfer dependent stage in the process wherein, after completion of the stage and prior to any recovery of the polymer, the polymer is dissolved in a solvent to create a polymer cement; c) contacting the layered nanofiller and the polymer solvent to obtain the nanocomposite; and d) recovering the nanocomposite. The layered nanofiller may be in a slurry prior to contacting with the polymer cement.

Elastomeric nanocomposite manufacturing

The invention relates to a new catalyst system that improves the heat transfer capability of a butyl reactor slurry process system in the production of isobutylene-based polymers in continuous slurry polymerization processes. The process is carried out in an anhydrous polymerization system containing a mixture of the monomers in a polar diluent along with a Lewis acid and a Cor greater initiator having a tertiary halide.

Growing community of inventors

Houston, TX, United States of America

John Patrick Soisson