Other

Uop Lcc

John P S Mowat

Wharton Sinkler

Benjamin D Yuhas

Melissa M Galey

Mimoza Sylejmani-Rekaliu

Kristine N Wilson

Christopher P Nicholas

Stuart R Miller

Susan C Koster

Gregory John Lewis

Lisa M Knight

A unique crystalline mixed transition metal tungstate material has been developed material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Mixed transition metal tungstate

A family of crystalline microporous metallophosphates designated AlPO-90 has been synthesized represented by the empirical formulaRMEPSiOwhere R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties for various hydrocarbon conversion processes, and characteristics suitable for efficient adsorption of water vapor in a variety of applications, including adsorption heat pumps. A parameter data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of a parameter of a data of a parameter of at least one unit or stream in fluid communication with and downstream from or upstream to a conversion process comprising at least one reaction catalyzed by SAPO-90.

Crystalline metallophosphates, their method of preparation, and use

A unique crystalline transition metal molybdotungstate material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Crystalline oxy-hydroxide transition metal molybdotungstate

A new family of crystalline microporous metallophosphates designated AlPO-90 has been synthesized. These metallophosphates are represented by the empirical formulaRMEPSiOwhere R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-90 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

A new crystalline aluminosilicate zeolite comprising a new framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula:MRAlESiOwhere M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions. The calcined zeolite is used in hydrocarbon conversion reactions.

Composition of matter and structure of zeolite UZM-55

A new crystalline aluminosilicate zeolite comprising a novel framework has been synthesized that has been designated UZM-55. This zeolite is represented by a three-dimensional framework of at least SiOtetrahedral units and an empirical composition in the as-synthesized and anhydrous basis expressed by an empirical formula of:MRAlESiOwhere M represents a metal or metals from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table, R is a structure directing agent or agents such as 1,6-bis(N-methylpiperidinium)hexane, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions including methanol to hydrocarbons (MTH).

Zeolite having a one-dimensional channel system, 10-membered rings and 12-membered rings

A new family of crystalline microporous metallophosphates designated AlPO-77 has been synthesized. These metallophosphates are represented by the empirical formulaHMEPSiOwhere M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-77 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for adsorption applications.

A new family of crystalline microporous metallophosphates designated AlPO-78 has been synthesized. These metallophosphates are represented by the empirical formulaRMEPSiOwhere R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-78 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

A new family of crystalline microporous metallophosphates designated AlPO-91 has been synthesized. These metallophosphates are represented by the empirical formulaCAMEPSiOwhere M is a divalent framework metal such as magnesium or zinc, C is a cyclic organoammonium cation, A is an acyclic organoammonium cation, and E is a trivalent framework element such as aluminum or gallium. The AlPO-91 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

A new family of crystalline microporous metallophosphates designated AlPO-92 has been synthesized. These metallophosphates are represented by the empirical formulaCAMEPSiOwhere M is a divalent framework metal such as magnesium, C is a cyclic organoammonium cation, A is an acyclic organoammonium cation, and E is a trivalent framework element such as aluminum or gallium. The AlPO-92 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.

A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-55. This zeolite is represented by the empirical formula:MRAlESiOwhere M represents a metal or metals selected from zinc or Group 1 (IUPAC 1), Group 2 (IUPAC 2), Group 3 (IUPAC 3) or the lanthanide series of the periodic table including sodium, potassium or a combination of sodium and potassium cations, R is an organic structure directing agent or agents derived from reactants R1 and R2 such as where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-55 have utility in various hydrocarbon conversion reactions.

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Arlington Heights, IL, United States of America

John P S Mowat