The Celotex Corporation

John P Oliver

David G Gluck

Alberto DeLeon

Thomas G Soukup

Wayne E Laughlin

Kenneth P Klapper

Thermoformable polyisocyanurate foams are prepared by reacting together under foam-forming conditions an organic polyisocyanate and an isocyanate-reactive compound, especially an aromatic polyester polyol, the equivalent ratio of isocyanate groups to isocyanate reactive groups being at least about 1.2:1. The foams and faced composites thereof can be thermoformed for a wide range of uses, such as in the interior of motor vehicles, aircraft, ships and other transport means, and of both residential and commercial buildings.

Thermoformable polyisocyanurate foam laminates for interior finishing

A process for the manufacture of a rigid, closed-cell polyisocyanurate foam from a foam forming mixture comprising an organic polyisocyanate, a polyol, a blowing agent, and a catalyst, utilizing a polyester polyol as the sole polyol, and chlorodifluoromethane or a mixture of chlorodifluoromethane and at least one co-blowing agent as the blowing agent.

Polyisocyanurate foams made with polyester polyols and

Rigid polyisocyanurate foams are prepared by (a) bringing together on a continuously advancing conveyor an organic polyisocyanate, a minor amount of a polyester polyol, a blowing agent and, in an organic solvent, a catalyst mixture comprising: (i) a salt of a low molecular weight carboxylic acid selected from the group consisting of an alkali metal salt and an alkaline earth metal salt and mixtures thereof, and (ii) a tertiary amine, the amount of the salt of the low molecular weight carboxylic acid being sufficient and the molecular weight of the carboxylic acid of the salt being sufficiently low to provide a firm foam having a non-friable surface, and (b) foaming the foam-forming mixture.

Catalyst mixtures for polyisocyanurate foam

A method for continuously producing an insulation board comprising a rigid plastic foam core having two major surfaces and a facing material on one or both of the major surfaces, the method including conveying a facing material along a production line, depositing a partially expanded froth foam of a plastic mixture, which contains at least one frothing agent, on the facing material, and further expanding and curing the froth foam in contact wiht the facing material to form the insulation board. The board is particularly useful as roof insulation.

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St. Petersburg, FL, United States of America

John P Oliver