Aluminum Company of America

John M Stinson

Vito Cedro, Iii

Edward S Martin

William E Horn

Thomas L Levendusky

Mark L Weaver

Roy B Steidley

Vincent J Downard

David A Smith

Susan A Stanton

Gary J DiFranco

John R McAllister

William F Forster

James H Richardson

There is provided a flash activated hydrotalcite which, when extruded to sizes of about 1/16 inch or more, has a crush load strength of at least about 7 pounds. The process for making this extrudate includes: (a) providing a hydrotalcite compound; (b) heating said compound for less than two seconds to one or more temperatures above about 482.degree. C. (900.degree. F.); (c) cooling said heated compound; (d) collecting said cooled compound; (e) forming said compound into an extrudate; and (f) reactivating said extrudate by heating to one or more temperatures above about 400.degree. C. (752.degree. F.) for about 20 minutes or more. Further strength improvements are achieved by exposing these extrudates to steam for at least about 8 hours prior to step (f).

Process for making flash activated hydrotalcite

There is provided a method for making a monovalent inorganic anion-intercalated hydrotalcite-like material by first reacting a magnesium-containing powder and a transition alumina powder in a carboxylic acid-free, aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a monovalent inorganic anion, in its acid or soluble salt form, to make a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include a bromide-, chloride-, nitrate- or vanadate-intercalated, hydrotalcite-like material.

Two powder synthesis of hydrotalcite and hydrotalcite-like compounds

There is provided a method for making a polyvalent inorganic anion-intercalated hydrotalcite-like material by first reacting a magnesium-containing powder and a transition alumina powder in a carboxylic acid-free, aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a polyvalent inorganic anion, in its acid, acid salt or ammonium salt form, to make a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include a borate- metatungstate- and paramolybdate-intercalated hydrotalcite-like material.

There is provided an improved method for making synthetic hydrotalcite by first reacting a divalent metal compound with a trivalent metal oxide powder in a carboxylic acid-free, aqueous solution or suspension to form an intermediate. This intermediate is then contacted with an anion source such as carbon dioxide; a carbonate-containing compound; an acid or an ammonium salt to form a layered double hydroxide having the formula: A.sub.1-x B.sub.x (OH).sub.2 C.sub.z.mH.sub.2 O, where A represents a divalent metal cation, B represents a trivalent metal cation, C represents a mono- to polyvalent anion, and x, z and m satisfy the following conditions: 0.09&lt;x&lt;0.67; z=x/n, where n=the charge on the anion; and 2&gt;m&gt;0.5. Said layered double hydroxide is typically separated from the suspension by filtering, centrifugation, vacuum dehydration or other known means.

Two powder synthesis of hydrotalcite and hydrotalcite like compounds

There is provided an improved method for making synthetic hydrotalcite by first reacting powdered magnesium oxide with a high surface area, transition alumina in a solution or suspension to form a meixnerite-like intermediate. This intermediate is then contacted with an anion source such as an acid, and most preferably carbon dioxide, to form the layered double hydroxide which is separated from the suspension by filtering, centrifugation, vacuum dehydration or other known means. On a preferred basis, the transition alumina combined with activated magnesia consists essentially of an rehydratable alumina powder having a surface area of 100 m.sup.2 /g or greater. To make related double hydroxide compounds, still other reactants such as bromides, chlorides, boric acids, or salts thereof, may be substituted for the carbon dioxide gas fed into this suspension.

There is provided a method for making a divalent inorganic anion-intercalated hydrotalcite-like material by first reacting a magnesium-containing powder and a transition alumina powder in a carboxylic acid-free aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a divalent inorganic anion, in its acid, acid salt or ammonium salt form, to make a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include a sulfate- and metavanadate-intercalated hydrotalcite-like material.

There is provided a method for making monovalent organic anion-intercalated hydrotalcite-like materials by first reacting a magnesium-containing powder and a transition alumina powder in a carboxylic acid-free, aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a monovalent organic anion to form a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include a stearate-, acetate- or benzoate-intercalated hydrotalcite-like material.

There is provided a method for making a divalent or polyvalent organic anion-intercalated hydrotalcite-like materials by first reacting a magnesium-containing powder and a transition alumina powder in an aqueous suspension to form a meixnerite intermediate. This intermediate is then contacted with a dicarboxylate or polycarboxylate anion to form a hydrotalcite-like material. The latter is then separated from the suspension. Representative materials include an oxalate-, succinate- or terephthalate-intercalated hydrotalcite-like material.

Two powder synthesis of hydrotalcite-like compounds with divalent or

A method for extrusion coating both sides of a metal strip. A metal strip, such as aluminum alloy strip, is moved through a pre-conditioner, two extrusion dies, a post heater and a cooling system. Both sides of the strip are coated with thin coatings of polyester material. The coated metal strip is useful for containers, such as cans and can ends, as well as for automobiles, appliances, aerospace, construction and electrical devices.

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Murrysville, PA, United States of America

John M Stinson