Mineral Process Licensing Corp. B.v.

John Lumsden

Philip J Gabb

Charles E Shackleton

Hayden Monk

The invention relates to the recovery of chlorine values as ferric chloride from iron chloride dust which is obtained as a by-product from the chlorination of a titaniferous material containing more than 5% by weight iron oxide, such as ilmenite. The method comprises heating the iron chloride dust to a temperature above 275.degree. C. in the presence of chlorine and iron oxide and recovering the ferric chloride volatilized from the iron chloride dust together with the ferric chloride obtained from ferrous chloride present in the iron chloride dust by reaction with the chlorine and ferric chloride obtained from other metal chloride contaminants by reaction with the iron oxide.

Recovery of chlorine values

The invention relates to a method for the reduction of ferric chloride to produce ferrous chloride. The method involves using as the reducing agent sulphur monochloride optionally in combination with sulphur or sulphur dichloride to produce ferrous chloride and sulphur dichloride. The sulphur monochloride may be introduced as a gas or as a liquid and the reaction is conveniently performed in a fluidized bed. According to a particular aspect, the ferric chloride reduction forms part of a process for the recovery of chlorine values from iron chloride by-produced by industrial processes such as the chlorination of a titaniferous or aluminous material.

Reduction of ferric chloride

A process for the chlorination of a material containing iron and titanium chemically combined with oxygen, comprising feeding the material to be chlorinated, in particulate solid form, into a reaction bed of solids containing ferrous chloride, and reacting it within that bed, at a temperature below the melting point of ferrous chloride, with a controlled amount of chlorine in the presence of sulphur in free or combined form, to produce solid ferrous chloride, titanium chloride, which is volatile at a temperature of operation, and sulphur dioxide, as the principal products of the process.

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Bristol, United Kingdom

John Lumsden