Gulf Research & Development Company

Chevron Research Company

John J Stanulonis

Roger F Vogel

Harold E Swift

Joseph A Tabacek

Elizabeth H Reynolds

Johann G Schulz

Raynor T Sebulsky

Henri K Lese

Allen Evarts Somers

William R Wajert

Ronald W Plesko

A catalyst composition comprising an alumina-aluminum phosphate-silica support bearing a halogen, a Group VI metal and a Group VIII metal in which the support has an average pore radius of from about 10 .ANG. to about 300 .ANG., a surface area ranging from about 50 m.sup.2 /g to about 400 m.sup.2 /g and a pore volume of about 0.1 to about 1.5 cc/g. The catalyst composition is used for hydroprocessing oils and possesses significant hydrodenitrification activity.

Catalyst composition and hydroprocessing of oils using same

An aqueous, alkaline impregnating solution for the one-step impregnation of nickel and molybdenum onto a catalyst support is provided by admixing nickel sulfate, preferably an ammoniacal solution of nickel sulfate and an ammoniacal solution of Mo.sup.+VI oxide to form a compatible impregnating solution. Nickel and sulfate ions are present in a ratio of substantially 1 to 1. The use of nickel sulfate in a predissolved ammoniacal solution for admixture with the ammoniacal solution of the Mo.sup.+VI oxide permits a higher metals loading of the impregnating solution and renders the resulting impregnating solution highly suitable for impregnation of nickel and molybdenum onto a catalyst support by the incipient wetness technique in one-step. The catalyst produced using the present impregnating solution is highly active for desulfurization of naphthas, middle distillate oils and asphalt-containing oils.

Impregnating solution for hydrogenation catalyst manufacture and

A tungsten-free hydrotreating catalyst is produced by contacting a refractory metal oxide support with an aqueous impregnating solution formed from an ammoniacal solution of nickel fluoride, preferably predissolved, and an Mo.sup.+VI oxide. The impregnating solution consists essentially of NH.sub.4.sup.+, Ni.sup.++, Mo.sup.+VI and F.sup.-, said Ni.sup.++ and F.sup.- being supplied from nickel fluoride and preferably contains nickel and fluoride ions in a ratio of substantially 1 to 2, and is used in an amount necessary for impregnating by the incipient wetness technique in a one-step impregnation. The impregnated catalyst support is then heated to a temperature sufficient to drive off ammonia and thereby deposit fluorine, nickel and molybdenum. The resulting catalyst is highly active for hydrotreating lube oil feedstocks.

Hydrotreating catalyst and manufacture thereof

A nickel-molybdenum catalyst composite is formed by a process which consists essentially of contacting a refractory inorganic oxide support with an aqueous, alkaline impregnating solution consisting essentially of NH.sup.+.sub.4, Ni.sup.++, SO.sub.4 .sup.- and MO.sup.+VI, with substantially all of the Ni.sup.++ being supplied from nickel sulfate, and heating said impregnated support to dry and calcine the catalyst composite. The calcination is an oxidative calcination conducted in the presence of an oxygen-containing gas at a temperature in the range of 427.degree. and about 566.degree. C. such that sulfate remains on said support. The resulting catalyst is used to desulfurize naphthas, middle distillate oils and asphaltic oils.

Supported nickel-molybdenum catalyst, preparation thereof, and

An aqueous, alkaline impregnating solution for the one-step impregnation of fluorine, nickel and molybdenum onto a catalyst support is provided by admixing nickel fluoride, preferably an ammoniacal solution of nickel fluoride and an ammoniacal solution of Mo.sup.+VI to form a compatible impregnating solution consisting essentially of NH.sub.4.sup.+, Ni.sup.++, Mo.sup.+VI and F.sup.-. Nickel and fluorine ions are present in a ratio of substantially 1 to 2. The use of nickel fluoride in a predissolved ammoniacal solution for admixture with the ammoniacal solution of the Mo.sup.+VI renders the resulting impregnating solution highly suitable for impregnation of fluorine, nickel and molybdenum onto a catalyst support by the incipient wetness technique in one-step. The catalyst produced using the present impregnating solution is highly active for hydrotreating lubricating oils.

Impregnating solution for hydrotreating catalyst manufacture and

A lube oil feedstock is subjected to hydrotreating in the presence of hydrogen and a fluorine-promoted catalyst comprising nickel and molybdenum on a support wherein the nickel and fluorine are derived from an ammoniacal solution of nickel fluoride. The catalyst can be prepared by contacting the support with an alkaline impregnating solution consisting essentially of NH.sub.4.sup.+, Ni.sup.++, MO.sup.+VI and F.sup.-, said Ni.sup.++ and F.sup.- being supplied from nickel fluoride, in a single step employing the incipient wetness technique. The impregnated support is thereafter heated to drive off the alkaline component of the solution and thereby deposit the fluorine, nickel and molybdenum on the support.

Lubricating oil hydrotreating process

A process for producing a novel composition of matter which comprises oxidizing a hydrocarbon oil with aqueous nitric acid, separating from the resulting oxidation product an aqueous phase and an oxidized hydrocarbon phase as the novel composition of matter. The novel composition of matter can itself be used as a fuel or it can be a component of a novel fuel composition.

Novel compositions of matter and process for utilizing same

A catalyst for cracking gasoline feedstock with greater selectivity to gasoline production and greater metals tolerance comprising an alumina-aluminum phosphate-silica matrix composited with a zeolite having cracking activity.

Alumina-aluminum phosphate-silica-zeolite catalyst

A catalyst for cracking gasoline feedstock with superior selectivity to gasoline production and greater metals tolerance comprising a magnesia-alumina-aluminum phosphate matrix composited with a zeolite having cracking activity.

Magnesia-alumina-aluminum phosphate-zeolite catalyst

A process for cracking gasoline feedstock with superior selectivity to gasoline production and greater metals tolerance wherein said gasoline feedstock is brought into contact with a fluid cracking catalyst comprising a zeolite dispersed in a magnesia-alumina-aluminum phosphate matrix, wherein said matrix has outstanding thermal stability.

Fluid cracking catalyst process using a zeolite dispersed in a

A process for cracking gasoline feedstock with greater selectivity of gasoline production and greater metals tolerance wherein, said gasoline feedstock is brought into contact with a catalyst comprising a zeolite dispersed in an alumina-aluminum phosphate-silica matrix, said matrix having outstanding thermal stability.

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Pittsburgh, PA, United States of America

John J Stanulonis