The University of Chicago

The United States of America As Represented by the United States

Uchicago Argonne, LLC

Arch Development Corporation

John J Picciolo

Dileep Singh

Kenneth C Goretta

Joseph T Dusek

Terry Alan Cruse

Bryant J Polzin

P Subraya Maiya

Uthamalingam Balachandran

Stephen E Dorris

Michael T Lanagan

Donald E Busch

James E Emerson

Jawana J James

Jitendra P Singh

Terry D Claar

A method for producing composite ceramic material is provided wherein a core ceramic structure is produced and simultaneously enveloped with a sleeve of similar material.

Fibrous ceramic monoliths made from multi-phase ceramic filaments

Method for fabricating ceramic composites

An improved highly oxygen permeable substrate is provided comprising Sr--Fe--Co-oxide and a metal combined with said material. Also provided is a method for producing an improved membrane to facilitate oxidation of compounds comprising combining metal or metal alloys with Sr--Fe--Co-oxide to create a mixture, and sintering the mixture so as to allow the metal to melt within the mixture. The membrane is also utilized in a method for converting methane to syngas whereby a fluid containing oxygen is contacted to a first surface of the membrane for a sufficient period of time so as to cause some of the oxygen to be transported to a second surface of the membrane; and contacting methane to the second surface for a sufficient period of time to cause oxidation of the methane.

Dense ceramic membrane material for conversion of methane to syngas

For a combination of a membrane of SrFeCo.sub.0.5 O.sub.x and an Inconel alloy, a high-temperature seal is formed between the membrane and the alloy. The seal is interposed between the alloy and the membrane, and is a fritted compound of Sr oxide and boric oxide and a fritted compound of Sr, Fe and Co oxides. The fritted compound of SrFeCo.sub.0.50 O.sub.x is present in the range of from about 30 to 70 percent by weight of the total sealant material and the fritted compound of Sr oxide and boric oxide has a mole ratio of 2 moles of the Sr oxide for each mole of boric oxide. A method of sealing a ceramic to an Inconel metal alloy is also disclosed.

High temperature seal for joining ceramics and metal alloys

The present invention is directed to a process for producing high temperature superconducting ceramic materials. More particularly, the present invention is directed to a process that enhances the densification of Bi.sub.1.8 Pb.sub.0.4 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.10 'BSCCO' ceramics.

Synthesis of increased-density bismuth-based superconductors with cold

To reduce thermal stress and improve bonding in a high temperature monolithic solid oxide fuel cell (SOFC), intermediate layers are provided between the SOFC's electrodes and electrolyte which are of different compositions. The intermediate layers are comprised of a blend of some of the materials used in the electrode and electrolyte compositions. Particle size is controlled to reduce problems involving differential shrinkage rates of the various layers when the entire structure is fired at a single temperature, while pore formers are provided in the electrolyte layers to be removed during firing for the formation of desired pores in the electrode layers. Each layer includes a binder in the form of a thermosetting acrylic which during initial processing is cured to provide a self-supporting structure with the ceramic components in the green state. A self-supporting corrugated structure is thus formed prior to firing, which the organic components of the binder and plasticizer removed during firing to provide a high strength, high temperature resistant ceramic structure of low weight and density.

Formation of thin walled ceramic solid oxide fuel cells

A high chromia refractory composite has been developed with improved thermal shock resistance and containing about 5-30 wt. % of unstabilized ZrO.sub.2 having a temperature-dependent phase change resulting in large expansion mismatch between the ZrO.sub.2 and the chromia matrix which causes microcracks to form during cooling in the high chromia matrix. The particle size preferably is primarily between about 0.6-5 microns and particularly below about 3 microns with an average size in the order of 1.2-1.8 microns.

High temperature refractory of MgCr.sub.2 O.sub.4 matrix and

Growing community of inventors

Lockport, IL, United States of America

John J Picciolo