Rohm and Haas Company

John J Miller

Sheldon N Lewis

Thomas W Hutton

Richard E Baus

Richard E Zdanowski

John D Guerin

Lawrence K Wempe

Polymers of a polymerizable mixture comprising an ethylenically unsaturated acid and an oligomer of an allyl-containing ester of acrylic acid or methacrylic acid are useful as thickening and bodying agents when partially or completely neutralized.

Carboxylic polymeric thickeners

Novel polyacrylic hot melt adhesives prepared by blending a polymer having a Tg of -85.degree. to 0.degree. C. with a polymer having a Tg of 20.degree. to 150.degree. C. are disclosed.

Method of utilizing polyacrylic hot-melt adhesives

Polyacrylic hot melt adhesives

Polymeric materials which comprise a hydroxyalkyl ester of acrylic acid or methacrylic acid, a monoethylenically .alpha.,.beta.-unsaturated carboxylic acid, and an alkyl ester or esters of acrylic and/or methacrylic acid are partially neutralized, isolated, and powdered to give useful powder coating compositions. The composition may be utilized for coating metallic articles.

Coated metal article

Compositions comprising an oxazolidine and a polyanhydride cure in the presence of moisture to afford polymeric materials. The compositions can be used in forming caulks, films, fibers, paints, seamless flooring, coatings, impregnants and adhesives for both natural and synthetic materials.

Hydrocurable oxazolidine polyanhydride compositions

Polymeric materials are disclosed which comprise a hydroxyalkyl ester of acrylic acid or methacrylic acid, a monoethylenically .alpha.,.beta.-unsaturated carboxylic acid, and an alkyl ester or esters of acrylic and/or methacrylic acid are partially neutralized, isolated, and powdered to give useful powder coating compositions. The compositions are particularly adapted to provide coatings on metals, a method for accomplishing this being disclosed.

Method of coating metal substrates

Polymeric materials which comprise a hydroxyalkyl ester of acrylic acid or methacrylic acid, a monoethylenically .alpha.,.beta.-unsaturated carboxylic acid, and an alkyl ester or esters of acrylic and/or methacrylic acid are partially-neutralized, isolated, and powdered to give useful powder coating compositions.

Thermosetting powder coatings composition

The invention provides new copolymers of (I) monounsaturated or diunsaturated addition polymerizable polyester monomers and (II) vinyl monomers. The resulting copolymer is considered to be a vinyl polymer (e.g., an acrylic polymer) containing a pendant polyester plasticizer as an integral part of the polymer. It is not essential that the copolymer be crosslinked or thermoset, and yet the plasticizer is a permanent part of the polymer--not subject to being leached out of the polymer, as is the case with an external plasticizer. While thermosetting or crosslinked compositions are known which bind external plasticizers to the substrate, the very object of attaining flexibility is to a large extent defeated by the binding agent itself when present in large amounts. Also provided are new monomers in the form of unsaturated polyesters having one or two double bonds per molecule. Textile articles characterized by improved water-resistance, wet abrasion or crock resistance, softness of hand, wet and dry peel strengths, washfastness, drycleanability and higher flock density, are obtained by following the invention. One of the important advantageous properties of the polymer of the invention is the cold flexing strength of products such as flocked fabrics made therewith. Other coated, bonded, impregnated, and laminated articles are provided.

Growing community of inventors

Warminster, PA, United States of America

John J Miller