Texaco Inc.

John H Estes

Ernest P Buinicky

Sheldon Herbstman

Tansukhlal G Dorawala

Edward L Cole

William Smolin

Leon F Koniz

Robert M Suggitt

Russell R Reinhard

Edwin R Kerr

Joseph A Durkin

Burton H Bartley

John T Nolan, Jr

Babu Y Rao

Allen N Webb

Stanley Kravitz

John T Brandenburg

Para-xylene may be recovered as raffinate by contacting a C-8 aromatic hydrocarbon mixture, in the presence of toluene desorbent, with a synthetic crystalline lithium aluminosilicate zeolite HP (formed by ion exchange from a sodium aluminosilicate zeolite HP having a lattice constant of 25.02-25.10 .ANG.)--preferably in the presence of a pyridine.

Zeolite adsorbent for separation of para-xylene

Para-xylene may be separated as extract product by contacting charge C-8 aromatic hydrocarbon mixture with a synthetic crystalline barium or barium/potassium aluminosilicate zeolite HP, formed by ion exchange from a sodium aluminosilicate zeolite HP having a lattice constant of 25.02-25.10 .ANG. and a ratio of silicon atoms to aluminum atoms of less than 1.0.

Adsorbent for separation of para-xylene

Para-xylene may be recovered as raffinate by contacting a C-8 aromatic hydrocarbon mixture, in the presence of toluene desorbent, with a synthetic crystalline sodium aluminosilicate zeolite HP, containing pyridine in amount of at least about 3.3 wt. % of said zeolite, having a lattice constant of 25.02-25.10.ANG..

A novel crystalline zeolite composition is prepared by conducting the hydrothermal crystallization and, preferably, a preliminary aging step, at high pressure, i.e. pressures in excess of 20,000 psig (ca 138 MPa) and preferably above about 40,000 psig (ca 276 MPa megaPascals). The crystalline zeolite, designated zeolite HP, has a higher aluminum content than zeolite X and a lattice constant of above 24.94 A up to 25.10 A.

Crystalline zeolite HP

A process for the desulfurization of a hydrocarbon fraction having unsaturated hydrocarbons and sulfur compounds comprising the steps of contacting the hydrocarbon fraction with hydrogen gas and a fluorided platinum catalyst in the presence of an oxygen-containing hydrogenation moderator which is either water or an oxygen-containing material which is hydrogenatable to water and whose hydrogenation products will not poison the platinum catalyst. The oxygen-containing hydrogenation moderator should be present in sufficient quantity to substantially prevent the saturation of the unsaturated hydrocarbons without seriously affecting the desulfurization of the hydrocarbon fraction. A preferred oxygen-containing hydrogenation moderator is carbon monoxide.

Hydrodesulfurization of hydrocarbons with fluorided platinum

A method and apparatus for thermally treating shale rock which holds an amount of hydrocarbon. The shale, preferably in a reduced size and form, is contacted by a hot molten metal bath at a sufficiently high temperature to release the hydrocarbon segment. The latter rises to the bath surface in liquid form to be skimmed, drained, or otherwise separated from residual rock material which is further conveyed from the lead bath.

Method for extracting hydrocarbons from oil shale

A novel crystalline zeolite composition is prepared by conducting the hydrothermal crystallization and, preferably, a preliminary aging step, at high pressure, i.e. pressures in excess of 20,000 psig (ca 138 MPa) and preferably above about 40,000 psig (ca 276 MPa megaPascals). The crystalline zeolite, designated zeolite HP, has a higher aluminum content than zeolite X and a lattice constant of above about 25.02 A.

In accordance with certain of its aspects, this invention relates to a finely-divided, high surface area supported catalyst containing a metal of the platinum-palladium group and a metal of the iron group wherein each of said metals is substantially uniformly distributed throughout the body of said supported catalyst--and to the use of this catalyst to prepare methane by the reaction of hydrogen and hydrocarbons.

Catalyst for the preparation of methane

A process for recovering bitumen, or heavy petroleum, from admixture with sand and similar inorganic materials wherein said bitumen-sand mixture is mixed with an aqueous solution of an ammonium salt selected from ammonium sulfite, ammonium bisulfite and mixtures thereof to form a second mixture comprising said aqueous ammonium salt solution, bitumen and sand; wherein said second mixture is heated to a temperature in the range of about 120.degree. F. (45.degree. C.) to about 260.degree. F. (127.degree. C.) and is separated into a bitumen phase free of sand, an aqueous phase and a sand phase.

Recovery of bitumen from tar sand

Alkylaromatic charge hydrocarbons such as toluene are steam dealkylated in the presence of catalyst which typically contains oxides of nickel, chromium, and potassium on an activated high-purity alumina. It is a feature of this invention that the high-purity alumina is activated by calcining followed by addition thereto of alkaline earth metal such as calcium or magnesium. A test is disclosed according to which it may be determined which high-purity aluminas are suitable for use.

Novel method of testing a charge calcined alumina to determine its

An enhanced oil recovery method comprising injecting an aqueous solution of ammonium salts selected from the group consisting of ammonium sulfite, ammonium bisulfite, and mixtures thereof into a petroleum-bearing earth formation, heating said injected aqueous solution to a temperature in the range of about 120.degree.-300.degree. F., or higher in the presence of said petroleum-bearing earth formation, flowing said heated aqueous solution through said petroleum bearing earth formation to drive petroleum to a recovery well, and producing increased amounts of petroleum from said earth formation through said recovery well.

Method for enhanced recovery of petroleum

An Enhanced Oil recovery method comprising injecting an aqueous ammonium bisulfite (NH.sub.4 HSO.sub.3) solution into a petroleum-bearing earth formation, heating said injected aqueous solution to a temperature in the range of about 120.degree.-300.degree. F., or higher in the presence of said petroleum-bearing earth formation, flowing said aqueous solution through said petroleum bearing earth formation to drive petroleum to a recovery well, and producing increased amounts of petroleum from said earth formation through said recovery well.

Enhanced recovery of petroleum

A method of and a catalyst for the conversion of petroleum distillate fractions to high heating value fuel gases suitable for use as town gas or pipeline gas by reacting a petroleum derived feedstock containing paraffins with hydrogen in the presence of a lanthanum-cobalt/Y zeolite catalyst at elevated temperature and pressure.

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Wappingers Falls, NY, United States of America

John H Estes