United Technologies Corporation

Utc Fuel Cells, LLC

John G Smeggil

David A Litton

Michael J Maloney

Kevin W Schlichting

Melvin Freling

David B Snow

Norman S Bornstein

Wayde R Schmidt

Xia Tang

David C Jarmon

Tania Bhatia

Michael A DeCrescente

Jean Yamanis

Tania Bhatia Kashyap

Harry E Eaton

Raymond C Benn

Roscoe A Pike

David N Duhl

William Patrick Allen

Stephen Chin

Sunil Govinda Warrier

Harry Edwin Eaton, Jr

Sonia Tulyani

Abdus S Khan

Clyde O Brown

Shihong Gary Song

Donald R Parille

Venkata R Vedula

Donald R Senterfitt

Larry D Hamner

Norman J Becker

James Roy Mullaly

David Snow

A process for applying an oxidation resistant coating to an article includes the steps of mixing at least about 10% by volume to up to about 99% by volume of a slurry at least one silica based material having a viscosity of about 1&#xd7;10poise to about 1&#xd7;10poise at a temperature of about 1,292&#xb0; F. (700&#xb0; C.) to about 3,272&#xb0; F. (1,800&#xb0; C.) at least about 1% by volume to up to about 90% by volume of the slurry at least one oxygen scavenger, and a liquid medium to form the slurry; coating an article with the slurry to form a slurry coated article; and heat treating under an inert atmosphere the slurry coated article to form an article having at least one oxidation resistant coating layer containing the at least one oxygen scavenger.

Oxidation resistant coatings, processes for coating articles, and their coated articles

A method for depositing a protective coating on a complex shaped substrate includes the steps of: (1) dipping a complex shaped substrate into a slurry to form a base coat thereon, the slurry comprising an aqueous solution, at least one refractory metal oxide, and at least one transient fluid additive present in an amount of about 0.1 percent to 10 percent by weight of the slurry; (2) curing the dipped substrate; (3) dipping the substrate into a precursor solution to form a top barrier coat thereon; and (4) heat treating the dipped, cured substrate to form a protective coating.

Dense protective coatings, methods for their preparation and coated articles

A process of coating an article includes the steps of (1) forming a layer of a ceramic based compound on an article; (2) providing a solution containing a metal as a particulate having a diameter of about 10 nanometers to about 1000 nanometers and present in an amount of about 25 percent to about 50 percent by volume of the solution; (3) contacting the ceramic based compound layer with the solution; (4) drying the article; and (5) optionally repeating steps (3) and (4).

Thermal barrier coating application processes

A method for providing a component with protection against sand related distress comprises the steps of: providing a substrate; and forming a thermal barrier coating system by depositing at least one layer of a first material selected from the group consisting of a zirconate, a hafnate, a titanate, and mixtures thereof, which first material has been mixed with at least one oxide so that each layer contains from about 25 to 99 wt% of at least one oxide.

Process of forming durable reactive thermal barrier coatings

A method for providing a component with protection against sand related distress includes the steps of: providing a substrate; depositing a layer of a yttria-stabilized zirconia material on the substrate; and forming a molten silicate resistant outer layer over the yttria-stabilized zirconia material.

Method for forming a yttria-stabilized zirconia coating with a molten silicate resistant outer layer

A thermal barrier coating system for use on a turbine engine component which reduces sand related distress is provided. The coating system comprises at least one first layer of a stabilized material selected from the group consisting of zirconia, hafnia, and titania and at least one second layer containing at least one of oxyapatite and garnet. Where the coating system comprises multiple first layers and multiple second layers, the layers are formed or deposited in an alternating manner.

Silicate resistant thermal barrier coating with alternating layers

A turbine engine component has a substrate, a thermal barrier coating deposited onto the substrate, and a sealing layer of ceramic material on an outer surface of the thermal barrier coating for limiting molten sand penetration.

Thermal barrier coating with a plasma spray top layer

A turbine engine component is provided which has a substrate and a thermal barrier coating applied over the substrate. The thermal barrier coating comprises alternating layers of yttria-stabilized zirconia and a molten silicate resistant material. The molten silicate resistant outer layer may be formed from at least one oxide of a material selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, indium, zirconium, hafnium, and titanium or may be formed from a gadolinia-stabilized zirconia. If desired, a metallic bond coat may be present between the substrate and the thermal barrier coating system. A method for forming the thermal barrier coating system of the present invention is described.

CMAS resistant thermal barrier coating

A turbine engine component has a substrate and a thermal barrier coating deposited onto the substrate. The thermal barrier coating comprises a ceramic material having a sodium containing compound incorporated therein. The sodium containing compound is present in a concentration so that when molten sand reacts with the coating, sodium silicate is formed as the by product.

High sodium containing thermal barrier coating

A turbine engine component is provided which has a substrate, a yttria-stabilized zirconia coating applied over the substrate, and a molten silicate resistant outer layer. The molten silicate resistant outer layer is formed from gadolinia or gadolinia-stabilized zirconia. A method for forming the coating system of the present invention is described.

Yttria-stabilized zirconia coating with a molten silicate resistant outer layer

A turbine engine component is provided which has a substrate and a thermal barrier coating applied over the substrate. The thermal barrier coating comprises at least one layer of a first material selected from the group consisting of a zirconate, a hafnate, a titanate, and mixtures thereof, which first material has been mixed with, and contains, from about 25 to 99 wt % of at least one oxide. The at least one oxide comprises at least one oxide of a material selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, indium, and yttrium. If desired, a metallic bond coat may be present between the substrate and the thermal barrier coating system. A method for forming the thermal barrier coating system of the present invention is described.

Durable reactive thermal barrier coatings

A process of coating an article includes the steps of (1) applying a ceramic based compound to at least one surface of an article to form a layer of ceramic based compound; (2) applying at least one inert compound upon the ceramic based compound layer to form a protective layer, wherein the at least one inert compound is composed of a first inert compound having a cubic crystalline structure of formula (I) ABXO, or a second inert compound comprising a hexagonal crystalline structure of formula (II) ABXO, or a mixture of the first inert compound and the second inert compound; (3) optionally drying the coated article; (4) optionally repeating steps (2) and (3); and (5) heat treating the coated article.

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Simsbury, CT, United States of America

John G Smeggil