Allied Colloids Limited

Amcol International Corporation

Ab Cdm

John G Langley

Kenneth Charles Symes

Peter Flesher

Kishor Kumar Mistry

David Farrar

Malcolm Hawe

Brian Dymond

Anthony P Allen

Peter Chamberlain

Philip Anson Ford

Sten Forsmo

David Holroyd

Adrian Swinburn Allen

John Oliver Stockwell

Timothy Guy Bingham

Peter Lowry

Brian Frederic Satterfield

Thomas Adrian Cauley

Norma Rosier

Ken C Symes

Edward Litchfield

Stephen Robert Tremont

Adrian Nixon

Jean Cluyse

Peter Holm

Ingvar Eriksson

Ahmed Atef Rasheed

Paper is made by providing an anionic aqueous emulsion of a size, usually a reactive anhydride size, and mixing it into a cellulosic suspension prior to drainage of the suspension to form a sheet which is then dried to provide paper (including paper board). The emulsion is preferably stabilised wholly or mainly by 0.5 to 30 parts by weight (per part by weight size) of water soluble, anionic, polymeric stabiliser, which is preferably anionic starch. Alternatively, the emulsion may be added to the cellulosic suspension while it is anionic, before mixing retention into it. The emulsion may be added to the cellulosic suspension after cationic retention aid has been added to it, the emulsion being added with, before or after mixing anionic microparticulate material or other anionic bridging aid, prior to drainage of the suspension.

Paper and materials and processes for its production

Paper or paper board is made by adding cationic polymeric retention aid to a cellulosic supension, shearing the suspension to degrade the resultant flocs, aggregating the suspension by adding an aqueous composition of bentonite or other anionic bridging coagulant in the presence of anionic dye, pigment or optical brightening agent, and forming paper from the aggregated suspension.

Production of paper and paper board

Enzyme dispersions, their production and compositions containing them

Release of an active ingredient can be controlled and the active ingredient can be protected from the environment during storage, by distributing it throughout a matrix containing a relatively large amount of polymeric material that is soluble and swellable in aqueous alkali but less soluble and swellable at a lower pH value and which is in the form of a dried oil-in-water emulsion of the polymer or a relatively insoluble partial salt of the polymer with a volatile amine, the full salt of the polymer being relatively soluble. The composition is of particular value for the protection of detergent enzymes.

Polymeric compositions and methods of producing them

A mill waste or deinking waste or other suspension containing cellulosic material and hydrophobic material is flocculated by a cationic polymeric flocculant and the flocculated material, is then aggregated by a swelling clay or other anionic colloidal material, optionally further cationic flocculant is added, and the aggregated material is then separated by belt pressing or other pressure filtration as a cake.

Dewatering of aqueous suspensions

A process of de-inking waste paper can be operated under conditions using a simple combination of chemicals to result in a waste liquor that is substantially environmentally friendly. The process comprises forming a pulp from the waste paper in a aqueous medium that has a pH of between 6 and 9 and that is substantially free of dissolved phosphate and that includes an ink-dispersing amount of polycarboxylic acid dispersing agent, and separating the ink from the pulp. The use of a cationic surfactant for promoting flotation is particularly desirable.

Treatment of cellulosic material and compositions for use in this

Paper is made by adding nonionic or anionic polymeric retention aid to a suspension that contains a high electrolyte content, shearing the flocculated suspension, aggregating the sheared suspension by adding anionic particulate material (especially bentonite), and draining the suspension.

Production of paper

Polymeric matrix particle compositions containing coacervate polymer

A particulate composition comprises particles having a substantially anhydrous core comprising an active ingredient. Generally the core comprises a matrix polymer with the active ingredient distributed throughout this. Generally there is an outer protection shell of polymer, generally formed by coacervation. The invention is a value for the production of powders, dispersions in non-aqueous liquids (for instance when the active ingredient is a detergent enzyme) and dispersions in water (for instance when the active ingredient is an agrochemical.

Particulate composition comprising a core of matrix polymer with active

A liquid composition is disclosed which comprises a substantially stable dispersion in a liquid phase of particles comprising a detergent enzyme and a protective polymeric material that is impermeable to liquid detergent concentrates but releases the enzyme when agitated in aqueous wash liquor and comprises an outer polymeric shell and/or a polymeric matrix through which the enzyme is distributed.

Polymeric compositions

Bentonite swelling clay is provided to a paper making mill as a fluid concentrate containing more than 15% bentonite wherein swelling of the bentonite is prevented by inorganic electrolyte in the concentrate, and the bentonite swells upon dilution either before addition of the cellulosic suspension or after addition.

Clay compositions and their use in paper making

Water soluble polymerizable acrylic prepolymers can be formed from ethylenically unsaturated monomers that include monomers that provide a pendant group that is a blocked, saturated, ethylenic group, followed by unblocking the pendant saturated ethylenic group to leave a pendant ethylenically unsaturated group. These prepolymers can be copolymerized through these unsaturated groups, for instance after impregnation into a permeable substrate as in chemical grouting or shut off processes, to form cross linked solid polymers. The polymerizable monomers that are ethylenically unsaturated but which also include the blocked ethylenic group are also novel.

Water soluble acrylic polymerizable materials, polymers made from them,

Agrochemical and other particulate compositions are formed by coacervation. The coacervate is preferably formed from two water soluble coacervating polymers and stabilizes the particles against agglomeration. The coacervate is preferably formed from a relatively low molecular weight cationic polymer and a relatively high molecular weight anionic polymer.

Particulate materials, their production and use

Enzymes and other biologically produced materials are recovered from the fermentation broth or other liquor in which they are provided initially and simultaneously distributed throughout particles of a polymeric matrix by dissolving the polymer in the liquor, dispersing the resultant polymer solution in a non-aqueous liquor in the presence of a stabiliser, and azeotroping the dispersion to produce either dry beads or a dispersion of small particles in the non-aqueous liquid.

Methods of drying biological products

Water soluble, substantially linear, polymers having single point intrinsic viscosity above about 3 are formed from an ethylenically unsaturated monomer that includes a group --B.sub.n A.sub.m R where A is propoxy or butoxy, B is ethoxy, n is zero or an integer of 2 to 100 and m is zero or an integer less than n, and R is a hydrophobic group of at least 8 carbon atoms and comonomer selected from non-ionic monomers and dialkylamino alkyl (meth) -acrylates or -acrylamides wherein at least one of the monomers is tertiary amine acid addition or quaternary ammonium salt. The resultant water soluble, high molecular weight, cationic polymers are useful as flocculants and as viscosifiers of aqueous acid solutions such as downhole acid stimulation fluids.

Growing community of inventors

West Yorkshire, United Kingdom

John G Langley