Westinghouse Electric Corporation

John F Remark

Thomas G Bengel

High velocity reactor coolant water in a boiling water reactor or a pressurized water reactor transports radioactive ions and particles from a nuclear reactor vessel to the balance of the reactor coolant system where they deposit on chromium (III) oxide-containing surfaces. These radioactive deposits are removed in a dilute chemical decontamination process wherein permanganate ion-containing reactor coolant water is circulated throughout a reactor coolant system to oxidize chromium (III) oxide surfaces of the system to chromium (IV) oxide. Formic acid is added to the permanganate ion-containing reactor coolant water and then the formic acid-containing water is circulated throughout the reactor coolant system to reduce unreacted permanganate ions in the reactor coolant water to manganous ions.

Process for decontaminating a nuclear reactor coolant system

An alkaline-permanganate process for chemically decontaminating oxidized metal surfaces wetted by primary water circulating in cooling loops of nuclear reactors maintains permanganate-containing primary water at a temperature of about 90.degree. C. and at a pH of 9-12 to oxidize the wetted surfaces. Oxalic acid is then added to the water and the oxalic acid-containing primary water is maintained at a temperature of at least about 90.degree. C. and at a pH of about 5-7 while it is circulated to destroy the permanganate ions and manganese dioxide.

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Gainesville, FL, United States of America

John F Remark