Kodak Polychrome Graphics, Gmbh

John David Riches

Gareth Rhodri Parsons

Kevin Barry Ray

Anthony Paul Kitson

Christopher David McCullough

David Stephen Riley

Peter Andrew Reath Bennett

Alan Stanley Monk

Richard David Hoare

James Laurence Mulligan

Mark John Spowage

Carole-Anne Smith

Stuart Bayes

Alan Stanley Victor Monk

John Andrew Hearson

Martyn Lott

Ken Shimazu

Colin Shoesmith

Imageable articles comprising positive working polymeric coatings on substrates are given a heat treatment as part of their manufacture, notably at a moderate temperature for an extended period. This heat treatment improves the development characteristics of the coatings in use. It has been found that by carrying out the heat treatment on articles wrapped in a water-impermeable material or in a humidity-enhanced oven, development characteristics may be further improved, especially adjacent to the edges of articles. The imageable articles include precursors for lithographic printing plates and for printed circuits.

Articles having imagable coatings

A method of making a mask or an electronic part, for example a printed circuit, comprises the steps of delivering heat in a desired pattern to a precursor of the mask or electronic part, the precursor comprising a surface coated with a coating, the coating comprising a heat-sensitive composition itself comprising an aqueous developer soluble polymeric substance and a compound which reduces the aqueous developer solubility of the polymeric substance, wherein the aqueous developer solubility of the composition is not increased by incident UV radiation but is increased by the delivery of heat; then developing the precursor to remove the heat-sensitive composition in regions to which the heat was delivered. In the case of a printed circuit precursor the surface may be then etched in conventional manner to yield the required printed circuit.

Method of making masks and electronic parts

Pattern formation

Phenolic resin compositions formulated for use in lithographic exposure processes are given a heat treatment at 40-90&deg; C. for at least 4 hours shortly after their coating onto lithographic substrates, to produce lithographic printing forms. It is found that such a heat treatment improves later exposure processes, in particular by rendering the sensitivity of the compositions less variable, over time.

Manufacture of lithographic printing forms

A heat imagable article has, in a single layer polymeric coating or in an inner layer of a multi-layer polymeric coating on a substrate, a polymeric matrix material, for example a phenolic resin, and, dispersed therein, polymeric particles, for example of polyethylene or polytetrafluoroethylene. The coating may contain a radiation absorbing compound so that suitable electromagnetic radiation, preferably infra-red radiation, may be used to heat the coating imagewise. The presence of the particles increases the physical robustness of the layer.

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West Yorkshire, United Kingdom

John David Riches