Scintrex Limited

John D Kinrade

John C Robbins

The interference of ozone in the determination of nitrogen dioxide determinations by luminol chemiluminescence is eliminated by first passing the gas sample into contact with a selective reducing agent for ozone, particularly antimony trioxide.

Method of determining nitrogen dioxide concentration in a gas sample

This invention is a method that uses the previously undiscovered fact that the phosphorescent lifetime of the uranyl ion at very dilute concentrations in an aqueous solution is anomalously long in comparison to that of other commonly-occurring phosphorescent species, wherein the uranyl ions in the low concentration sample are excited by projecting electromagnetic energy into the sample, terminating the projection of electromagnetic energy into the sample and measuring the characteristics of the decaying uranium phosphorescence after termination of the incident electromagnetic radiation.

Method for uranium determination

A method of detecting uranium compounds in an aqueous sample, containing uranium compounds that phosphoresce in response to ultraviolet light and other compounds which luminesce but have a shorter lifetime of phosphorescence than uranium compounds comprising the steps of increasing the phosphorescent characteristics of the uranium compounds and simultaneously diminishing the quenching efficiency of interfering ions in the sample by adding a polyphosphate compound and a buffer; projecting ultraviolet light into the sample; terminating said projection of ultraviolet light into the sample; measuring intensity of the decaying uranium phosphorescence at a time delay after the termination of the ultraviolet light, the time delay being longer than the time for luminescence due to materials other than uranium compounds possibly in the sample to substantially decay.

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Ottawa, Canada

John D Kinrade