Baker Hughes Corporation

Petrolite Corporation

Baker Hughes, a Ge Compnay, LLC

Baker Hughes Holdings LLC

John A Schield

Michael I Naiman

Jerry J Weers

David J Poelker

Weldon John Cappel

JoAnn McMahon

Joseph L Stark

Glenn L Roof

Timothy J O'Brien

Waynn C Morgan

Lei Zhang

Jianzhong Yang

Corina Sandu

Lawrence J Cunningham

Paul J Biggerstaff

Yun Bao

Ross Poland

Gary A Scherubel

Tauseef Salma

Philip L Leung

Ksenija Babić-Samardzija

Matthew T Barnes

Robert A Steele

Joann McMahon

Corina L Sandu

Haze may be removed from a biofuel or biofuel intermediate by using a clarifier. The clarifier includes copolymer prepared using a formulation comprising an alpha olefin and maleic anhydride. The clarifier may also be used with admixtures of biofuels, biofuel intermediates, or biofuel feedstocks with conventional hydrocarbons.

Process for clarifying biofuels

A composition useful for scavenging hydrogen sulfide by admixing metal carboxylates which have high viscosity due to polymerization and a viscosity improver selected from the group consisting of glycol ethers having from about 4 to about 10 carbons and alkyl alcohols having from about 1 to about 4 carbons.

Low viscosity metal-based hydrogen sulfide scavengers

An effective hydrogen sulfide scavenger that produces little corrosion may be prepared by reacting glyoxal with a compound having at least two primary or secondary amine groups. The subject hydrogen sulfide scavengers may be used with both the production of crude oil and natural gas, and the refining of same.

Hydrogen sulfide scavenger for use in hydrocarbons

Compounds having the formulae and general formulae: wherein each R, R, Rand Rare the same or different and may be hydrogen, an alkyl group, an aryl group, a halogen, a nitro group, an alkyl or aryl ester, and an alkyl or aryl ether;compounds having the general formula: wherein R is an alkyl, aryl or electron withdrawing group; mixtures thereof; can be used as additives for crude oil and hydrocarbons. These compounds may be used to scavenge mercaptans, sulfides, cyanides, and primary or secondary amines; either alone or in combination.

Multifunctional scavenger for hydrocarbon fluids

Certain branched carboxylic acids may serve as improved lubricity additive compositions in distillate fuels, and in particular for cold weather applications. Suitable branched carboxylic acids may include, but are not necessarily limited to, isostearic acid, neodecanoic acid, isononanoic acid, neononanoic acid, neoundecanoic acid, isovaleric acid, pivalic acid, and the like and mixtures thereof. The branched carboxylic acids may be used alone or together with straight chain carboxylic acids, and optionally with an aromatic solvent.

Branched carboxylic acids as fuel lubricity additives

A clayish subterranean formation, such as may be encountered in rock surrounding a well bore during hydrocarbon recovery operations may be stabilized with relatively high molecular weight acid ammonium salts of an imide of polymaleic anhydride. The salts may be unneutralized or partially neutralized. The invention is particularly relevant to hydraulic fracturing fluids used in enhanced oil recovery. The compositions herein are made in the presence of a reactive solvent, such as a polyalkylene glycol, e.g. polyethylene glycol. The compositions of this invention are more environmentally friendly than some current technology.

High molecular weight polyamine salts as clay stabilizing agents

Disclosed is composition useful for reducing the concentration of mercaptans in hydrocarbons comprising: (A) a first diazo component and (B) a second component comprising a nucleophilic acceptor. The composition can be added to hydrocarbons such as fuel oil to reduce mercaptans without increasing turbidity or color. Triethylene diamine and 1,2-epoxyhexadecane are disclosed to be exemplary diazo and nucleophilic acceptor components.

Hydrocarbons having reduced levels of mercaptans and method and composition useful for preparing same

A clayish subterranean formation, such as may be encountered in rock surrounding a well bore during hydrocarbon recovery operations may be stabilized with a polyamine salt of an imide of polymaleic anhydride. The salt may be unneutralized or partially neutralized. The invention is particularly relevant to hydraulic fracturing fluids used in enhanced oil recovery. The compositions of this invention are more environmentally friendly than some current technology.

Polyamine salts as clay stabilizing agents

A clayish subterranean formation, such as may be encountered in rock surrounding a well bore during hydrocarbon recovery operations may be stabilized with relatively high molecular weight polyamine salts of an imide of polymaleic anhydride. The salts may be unneutralized or partially neutralized. The invention is particularly relevant to hydraulic fracturing fluids used in enhanced oil recovery. The compositions herein are made in the presence of a reactive solvent, such as a polyalkylene glycol, e.g. polyethylene glycol. The compositions of this invention are more environmentally friendly than some current technology.

The present invention provides a method for inhibiting the evolution of HS from sulfhydryl compounds in molten sulfur by using scavenging agents such as anhydrides and polymers thereof, conjugated ketones, carbonates, epoxides, monoesters and diesters of unsaturated dicarboxylic acids and polymers of these esters, and the like and mixtures thereof. In one embodiment, it is preferred that the scavenging agent is in liquid form at contact temperature with the molten sulfur. In another embodiment, the scavenging agent may be atomized into the vapor space over the molten sulfur to contact the sulfur with the agent.

Hydrogen sulfide abatement in molten sulfur

The present invention provides a method for inhibiting the evolution of H S from sulfhydryl compounds in molten sulfur by using scavenging agents such as anhydrides and polymers thereof, conjugated ketones, carbonates, epoxides, monoesters and diesters of unsaturated dicarboxylic acids and polymers of these esters, and the like and mixtures thereof. In one embodiment, it is preferred that the scavenging agent is in liquid form at contact temperature with the molten sulfur. In another embodiment, the scavenging agent may be atomized into the vapor space over the molten sulfur to contact the sulfur with the agent.

It has been discovered that less expensive, and in some cases synergistically effective anti-static additive blends may be added to hydrocarbon fuels to improve the conductivity thereof. The blend includes an anti-static amount of at least one hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer and an anti-static amount of at least one hydrocarbon soluble polysulfone copolymer of at least one olefin and sulfur dioxide. Optional ingredients include polymeric polyamines and aryl sulfonic acids.

Anti-static additive compositions for hydrocarbon fuels

Adding to a fuel oil a composition of from about 1 to about 40 parts by weight ethylene/vinyl acetate copolymer having a vinyl acetate content of from about 10% by weight to about 50% by weight and a weight average molecular weight of from about 2,000 to about 10,000, and 1 part by weight esterified copolymer of at least one generally linear .alpha.-olefin of from about 18 to about 50 carbon atoms and maleic anhydride in an .alpha.-olefin to maleic anhydride molar ratio of from about 4:1 to about 1:2, the copolymer having a weight average molecular weight of from about 2,000 to about 20,000, the esterified copolymer having been esterified with a plurality of aliphatic alcohols having from about four to about forty carbon atoms, imparts to the fuel oil surprisingly improved low temperature fluidity, provided that the alcohols include an eight carbon alcohol making up from about 50 to about 85 molar percent of the alcohols.

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Missouri City, TX, United States of America

John A Schield