Imperial Chemical Industries Limited

John A Milner

John Crosby

Roger M Turner

Process for the preparation of organic isocyanates in which a furoxan is heated in the presence of a vicinal diketo compound containing two adjacent keto carbonyl groups. When the furoxan ring is fused to an organic ring system di-isocyanates are produced. An adduct of the furoxan and the diketo compound may be isolated from the reaction mixture and used as a stable isocyanate precursor, for example, a 'one-pot' polyurethane composition.

Adducts of furoxan and vicinal diketones

An ore-treatment process for the recovery of metal concentrates from mineral ores containing one or more metals in the form of their sulphides and/or oxides in which the crushed ore is subjected to a froth flotation process in aqueous medium using, as collector, an orthophydroxy phenyl oxime of formula ##STR1## where R is hydrogen or a hydrocarbyl group, R.sup.1 is an electron-donating group, especially an alkyl group, and R.sup.11 is hydrogen or an alkyl, cycloalkyl or aralkyl group. The process is especially suitable for treatment of copper-containing ores.

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Runcorn, United Kingdom

John A Milner