W. R. Grace Co.-conn.

Nalco Chemical Company

Other

Betzdearborn, Inc.

Commonwealth Edison Company

Biotronics Technology, Inc.

John A Kelly

Chih M Hwa

Ralph L Minnis

Roger R Gaudette

Janet Neton

Patricia M Scanlon

David B Mitchell

Frederick S Mandel

Steven M Deboo

Thomas Peter Curran

Wun Ten Tai

James D Haff

Joseph D Bates

Phillip M Egerbrecht

Rashmi Patwardhan

Robert P Kreh

Cynthia A Soderquist

Walter F Lorenc

Mita Adhya

Joseph T Lundquist

Paul Young

Brian Greaves

Kenneth J Schlager

Wun T Tai

Lai-Duien Grace Fan

Vincent R Kuhn

David A Grattan

Alfred W Oberhofer

Gary G Engstrom

Wayne L Henry

John Richardson

Mary E Koutek

Larry M Kye

Mark D Brickhouse

Scott J Kahle

Malcolm T Kelly

Mary H Kelly

A novel high-purity polymer dispersant and sludge conditioner added to the feedwater entering the secondary side of a nuclear steam generator for minimizing the accumulation of metal-oxide deposits within the nuclear steam generator during the continuing operation of the generator is disclosed. The high-purity polymer is selected from a group consisting of acrylic acid polymer, methacrylic acid polymer, acrylate polymer, methacrylate polymer, copolymers, and terpolymers, acrylate/acrylamide copolymer, acrylate/methacrylate copolymer, terpolymers, and mixtures thereof. Methods of making and applying the polymer dispersant and sludge conditioner are described. Means for removing the metal oxides and polymer from the blowdown stream are disclosed.

Polymer dispersants and methods of use in a nuclear steam generator

There is provided a composition comprising tannin containing hydroxyl groups which has been (a) chemically modified by reaction of at least one of said hydroxyl groups with at least one member selected from the group consisting of an esterification agent (e.g. acetic anhydride), etherification agent (e.g. dichloromethane or quaternary organic amine such as N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride) to form the corresponding ester, or ether, through said hydroxyl group, and (b) derivatized. The chemically modified tannin is derivatized by reaction with aldehyhde (e.g. formaldehyde), or aldehyde and at least one member selected from the group consisting of ammonia and organic amine containing at least one primary or secondary nitrogen (e.g. cyclohexyl amine); said derivatized tannin being water soluble or dispersable at a pH below 7 and water insoluble at a pH above 7. The chemically modified tannins are useful for the coagulation and/or detackification of solid particles suspended in the aqueous system, such as paint particles suspended in the waste water of a paint spray booth operation. Such tannins also have utility for demulsifying oil-in-water emulsions.

Treatment of aqueous systems using a chemically modified tannin

There is provided a composition comprising tannin containing hydroxyl groups which has been (a) chemically modified by reaction of at least one of said hydroxyl groups with at least one member selected from the group consisting of an esterification agent (e.g. acetic anhydride), etherification agent (e.g. dichloromethane or quaternary organic amine such as N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride) to form the corresponding ester, or ether, through said hydroxyl group, and (b) derivatized. The chemically modified tannin is derivatized by reaction with aldehyhde (e.g. formaldehyde), or aldehyde and at least one member selected from the group consisting of ammonia and organic amine containing at least one primary or secondary nitrogen (e.g. cyclohexyl amine); said derivatized tannin being water soluble or dispersable at a pH below 7 and water insoluble at a pH above 7. The above modified tannins are useful for the coagulation and/or detackification of solid particles suspended in an aqueous system, such as paint particles suspended in the waste water of a paint spray booth operation. Such tannins also have utility for demulsifying oil-in-water emulsions.

Treatment of Aqueous systems using a chemically modified tannin

A picture hanger aligning device and method for locating and aligning one or more picture hangers on a wall. An elongated, vertical center member and an elongated horizontal member having hooks protruding outwardly therefrom are connected in a triangular fashion by two elongated side members. A picture is hung from hooks on the horizontal member or, alternatively, from a hook on the vertical member, and held in a desired position against a wall. The position of a scribe hole in the vertical member is marked by inserting a marking utensil through the scribe hole, the picture is removed from the device, and the device is held against the wall in the desired position by aligning the scribe hole with the corresponding mark on the wall. The position of the hooks from which the picture is hung is then marked on the wall by inserting a writing utensil through scribe holes associated with the hooks. Hangers can then be inserted in the wall at the aligned positions of the wall marks, resulting in aligned picture hangers from which the picture can be hung.

Picture hanger aid and aligning device

The present invention is directed to a novel method for analyzing aqueous systems to simultaneously quantify the concentrations of multiple active or inactive treating components which may be contained therein. The method comprises determining the absorbance or emission spectrum of the components in the aqueous system over the wavelength range of from 200 to 2500 nm, and then applying chemometrics algorithms to extract and analyze features in the spectrum that are specific to the qualitative and quantitative concentrations from the specific components to simultaneously determine the concentrations of the components.

Spectrophotometric monitoring of multiple water treatment performance

A method of comprising iron in an aqueous system comprising adding to the system a copolymer of styrene sulfonic acid and methacrylic acid or its water soluble salt in an amount effective to disperse the iron contained therein.

Method of dispersing iron

This invention relates to controlling corrosion in aqueous systems and more particularly to using certain calcium insensitive phosphonomethyl amine oxide compounds. The compounds of this invention are water soluble phosphonomethyl amine oxides having at least one oxidized tertiary amine group of the formula: ##STR1## and water soluble salts thereof and having a cloud point of at least about 25 ppm.

Control of corrosion in aqueous systems using certain phosphonomethyl

This invention relates to controlling scale formation in aqueous systems and more particularly to using certain calcium insensitive phosphonomethyl amine oxide compounds having at least one oxidized tertiary amine group of the formula: ##STR1## and water soluble salts thereof.

Control of scale in aqueous systems using certain phosphonomethyl amine

This invention relates to certain calcium insensitive phosphonomethyl amine compounds and their use as scale control agents for treating aqueous systems. The compounds of this invention are water-soluble phosphonomethyl amine compounds having the formula: ##STR1## and water soluble salts thereof selected from the group consisting of N-phosphonomethyl iminodiacetic acid, N,N-bis-phosphonomethyl- 2-(hydroxyethoxy)ethylamine, 4-(phosphonomethyl)-2-hydroxy-2-oxo-1,4,2-oxazaphosphorinane, N,N-bis-phosphonomethyl taurine and N,N-bis-phosphonomethyl ethylamine; and having a cloud point of at least about 25 ppm as determined by the CA500 cloud point test or a water soluble salt of said phosphonomethyl amine.

Control of scale in aqueous systems using certain phosphonomethyl amines

This invention relates to novel organic phosphonate compounds which can be used as water treatment agents. More specifically, this invention relates to the compound N,N-bis-phosphonomethyl taurine N-oxide which may be represented by the formula: ##STR1## and its water soluble salts, which can be employed for the control of scale and/or corrosion.

N,N-bis-phosphonomethyl taurine N-oxide and water-soluble salts thereof

A method of removing iron contaminants in an aqueous system by introducing and maintaining within the system at least one ortho dihydroxyaromatic compound having at least one electron withdrawing group pendant from the aromatic ring and, further, a method of inhibiting calcium scale formation in the presence of iron contaminants by utilizing at least one dehydroxyaromatic compound in combination with calcium scale inhibitors.

Corrosion control

This invention relates to a method for preventing corrosion and inhibiting the formation of scale deposition in aqueous systems. More specifically, it relates to using certain calcium insensitive phosphonomethyl amine compounds having the formula: ##STR1## wherein either R.sub.1 is selected from hydrogen, hydrocarbyl, hydroxy-substituted hydrocarbyl, alkoxy-substituted hydrocarbyl; and R.sub.2 is selected from hydrocarbyl, hydroxy-substituted hydrocarbyl, alkoxy-substituted hydrocarbyl, carboxyl-substituted hydrocarbyl, --CH.sub.2 PO.sub.3 H.sub.2, and --C.sub.2 H.sub.4 N(CH.sub.2 PO.sub.3 H.sub.2).sub.2 ; or R.sub.1 and R.sub.2 together form an alicyclic ring having 3 to 5 carbon atoms, optionally along with oxygen atoms, phosphorus atoms or both oxygen and phosphorus atoms in the ring, and water soluble salts thereof.

Growing community of inventors

Crystal Lake, IL, United States of America

John A Kelly