Hoechst Celanese Corporation

Honeywell International Inc.

Celanese Acetate Limited

Hna Holdings, Inc.

Mitsubishi Polyester Film Gmbh

Holechst Celanese Corporation

John A Flint

Gunilla E Gillberg-LaForce

Robert Bruce Sandor

Herman Leslie Lanieve

Scott W Thompson

Etheridge Odell Oakley, Jr

William F Clear

Michele C Carter

Edward R Kafchinski

Mohammed Ishaq Haider

M Ishaq Haider

Joseph J DiBiase

John Edward Cornetta

Larry F Charbonneau

Bodo Kuhmann

Cynthia Bennett

Michael L Jaffe

E-Won Choe

Eui W Choe

Helmut B Witteler

Garo Khanarian

O Richard Hughes

Robert E Johnson

James P Shepherd

George Collins

William M Pleban

Gabor D Kiss

Frank Haimbach, Iv

Cheng K Saw

Michael J Jaffe

Dieter K Kurschus

Bennett Clayton Ward

A fiber having increased cut resistance is made from a fiber-forming polymer and a hard filler having a Mohs Hardness Value greater than about 3. The filler is included in an amount of about 0.05% to about 20% by weight. In preferred embodiments, the fiber-forming polymer is poly(ethylene terephthalate) or a liquid crystalline polyester comprising monomer units derived from 6-hydroxy-2-naphthoic acid and 4-hydroxybenzoic acid. Preferred fillers include tungsten and alumina.

Cut-resistant gloves

The present invention discloses and claims a novel process for the formation of high denier as-spun and heat-treated multilobal filaments of a thermotropic liquid crystalline polymer. Preferred embodiments include process for the formation of as-spun and heat treated octalobal monofilaments of a few wholly aromatic polyesters and polyesteramides. The process involves (a) heating of a thermotropic liquid crystalline polymer to above its melting transition temperature; (b) passing said molten polymer through an extrusion chamber equipped with an extrusion capillary having a multilobal cross-section to form a multilobal filament; and (c) winding the filament at a suitable draw-down. The filaments so formed are of at least 50 denier per filament (dpf) and feature essentially uniform molecular orientation across their cross-section. In a final optional step, the filaments are heat treated in stages to form filaments exhibiting excellent tensile properties. Both as-spun and heat-treated filaments feature remarkably good tensile properties comparable to those of round filaments. Most importantly, the multilobal filaments of this invention feature much superior adhesion properties than the conventional round filaments.

Process for making high denier multilobal filaments of thermotropic liquid crystalline polymers and compositions thereof

Cut-resistant sheath/core fiber

The present invention discloses and claims a novel process for the heat treatment of high denier filaments of a thermotropic liquid crystalline polymer. Preferred embodiments include process for the formation of heat treated filaments of a few wholly aromatic polyesters and polyesteramides. The process involves: (a) heating of a thermotropic liquid crystalline polymer to above its melting transition temperature; (b) passing said molten polymer through an extrusion chamber equipped with an extrusion capillary of an aspect ratio of greater than about 1 and less than about 15 to form a filament; (c) winding the filament on to a bobbin at a low tension and draw-down ratio of at least about 4; and (d) heat treating the filament directly on the bobbin at suitable temperature and pressure conditions for a sufficient period of time. The filaments so formed are of at least 50 denier per filament (dpf) and feature essentially uniform molecular orientation across the cross-section. The heat-treated filaments feature remarkably good tensile properties retaining at least 80 to 90 percent of the properties expected of conventional low denier (5 to 10 dpf) filaments.

Process for direct on-bobbin heat treating of high denier filaments of

A fiber having increased cut resistance is made from a fiber-forming polymer and a hard filler having a Mohs Hardness Value greater than about 3. The filler is included in an amount of about 0.05% to about 20% by weight. In preferred embodiments, the fiber-forming polymer is poly(ethylene terephthalate) or a liquid crystalline polyester including monomer units derived from 6-hydroxy-2-naphthoic acid and 4-hydroxybenzoic acid. Preferred fillers include tungsten and alumina.

Composite yarn comprising filled cut-resistant fiber

Method of making a cut-resistant fiber and fabrics, and the fabric made

Filled cut-resistant fiber

A polyester fiber made from a polymer having ethylene glycol moieties, isosorbide moieties and terepthaloyl moieties, and the method of making the fiber is described. The polyester fiber is used to form articles suitable for commercial, especially textile, and industrial uses, and has an inherent viscosity of at least 0.35 dL/g when measured as a 1% (weight/volume) solution of the polyester in o-chlorophenol at a temperature of 25.degree. C.

Polyester fiber and methods for making same

Cut resistant non-woven fabrics

The present invention discloses and claims a novel process for the formation of high denier as-spun and heat-treated filaments of a thermotropic liquid crystalline polymer. Preferred embodiments include process for the formation of as-spun and heat treated monofilaments of a few wholly aromatic polyesters and polyesteramides. The process involves (a) heating of a thermotropic liquid crystalline polymer to above its melting transition temperature; (b) passing said molten polymer through an extrusion chamber equipped with an extrusion capillary of an aspect ratio of greater than about 1 and less than about 15 to form a filament; and (c) winding the filament at a draw-down ratio of at least about 4. The filaments so formed are of at least 50 denier per filament (dpf) and feature essentially uniform molecular orientation across the cross-section. In a final optional step, the filaments are heat treated in stages to form filaments exhibiting excellent tensile properties. Both as-spun and heat-treated filaments feature remarkably good tensile properties retaining at least 80 to 90 percent of the properties expected of conventional low denier (5 to 10 dpf) filaments.

Process for making high denier filaments of thermotropic liquid

Fibers and yarns of polyethylene terephthalate (PET) and PET copolymers with a sheath/filamentous core microstructure are formed from unoriented and non crystalline 'as spun' source fibers and yarns by drawing to high draw ratios in one step. Fibers and yarns with the sheath/filamentous core microstructure are stiffer than commercial PET fibers. Fibers and yarns with the sheath/filamentous core microstructure may be annealed and relaxed to increase their dimensional stability without loss of the sheath/filamentous core microstructure.

Method and apparatus of transferring a packet and generating an error

Biaxially oriented films containing at least one layer of polyethylene naphthalate bibenzoate (PENBB) copolyester wherein the copolyester contains from about 60 to about 40 mol % of a first recurring unit of the formula (II). ##STR1## and about 40 to about 60 mol % of a second recurring unit of formula (I). The copolyester preferably contains less than 10 mol % of recurring units derived from terephthalate or other dicarboxylic acids. The films have a total thickness of 0.05-500 .mu.m and may contain inert particles.

Biaxially oriented films containing layers of polyethylene naphthalate

Cut-resistant fiber containing a hard filler

Copolyester compositions comprising poly(ethylene naphthalate

The tensile modulus of fibers made from liquid crystalline polymers comprising 6-oxy-2-naphthoate and 4-oxybenzoate monomer units that have been heat treated can be increased by applying and then releasing a stress at room temperature in the range of about 25% to about 90% of the tensile strength of the heat treated fiber to yield a 'pre-stressed' fiber.

Pre-stressing of heat treated liquid crystalline polymer fiber to

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Berkeley Heights, NJ, United States of America

John A Flint