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Henkel Corporation

Johann F Fues

Wilfried Raehse

Heinz Mueller

Claus-Peter Herold

Alfred Meffert

Stephan Von Tapavicza

Kathleen Paatz

Andreas Syldatk

Wilhelm Beck

Brigitte Giesen

Ingo Wegener

Herbert Pattberg

Horst Hoeffkes

Andreas Syldath

Hans-Josef Beaujean

Karl Schwadtke

Bert Gruber

Gerhard Stoll

Eric Sung

Eduard Smulders

Karl Giede

Rainer Jeschke

Werner Kuenzel

Ulrich Jahnke

Otto Koch

Levent Yueksel

Erich Holz

Wolfgang Poly

Brigitte Glesen

Wolfgang Hlavacek

Horst Eisenblaetter

Reiner Vogler

Truc Tran Anh

Hans-Georg Toelken

Klaus-Peter Herold

Sven Welper

The use is disclosed of at least substantially water-insoluble ethers which are fluid and/or at least plastically deformable at working temperature and have flash points of at least 80&deg; C., of mono- and/or polyfunctional alcohols of natural and/or synthetic origin or corresponding solutions of such ethers in ecologically acceptable water-insoluble oils as the dispersed oil phase of water-based O/W-emulsion drilling fluids which are suitable for the environmentally acceptable development of geological formations and which contain, if desired, insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsion drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.

Use of selected oleophilic ethers in water-based drilling fluids of the O/W emulsion type and corresponding drilling fluids with improved ecological acceptability

Multicomponent mixtures based on water-soluble alkali metal silicate

Optimized process for conditioning steam-based vapor streams

A process for the production of wetting-, washing- or cleaning-active anionic surfactant salts by reacting inorganic or organic bases with anionic surfactant intermediates containing hydrophilic negatively charged groups attached to hydrophobic hydrocarbon radicals. The salts are combined in a spray which is introduced into an inert gas phase of superheated steam whereby the spray is at least partly dried. In an embodiment of the process, the anionic surfactant intermediates are neutralized during the spraying step to form the salts.

Process for the production of surface-active anionic surfactant salts

Process for producing free-flowing granules with superheated steam

Process of producing low-dust anionic surfactant concentrates in powder

Process for the production of granules suitable as wetting agents,

Described is the use of surface-active alpha-sulfofatty acid di-salts as ecologically compatible emulsifiers of the W/O type and O/W type, respectively, in fluid and pumpable drilling fluids and other fluid drilling-hole treatment agents which comprise a continuous or a dispersed oil phase together with an aqueous phase and which are suitable for an environmentally acceptable exploitation of geological resources, for example oil or natural gas deposits. The invention further relates to inverted drilling fluids based on a continuous oil phase and, present therein, a dispersed aqueous phase which, in addition to the emulsifiers, contain further conventional auxiliary agents such as thickeners, fluid-loss additives, weighting agents, water-soluble salts and/or alkali reserves. The inverted drilling fluids according to the invention are characterized in that they contain surface-active di-salts of the type indicated as emulsifier or as an emulsifier component together with an ecologically compatible continuous oil phase.

Use of surface-active alpha-sulfo-fatty acid di-salts in water and oil

Described is the use of oleophilic esters of ecologically compatible polycarboxylic acids with oil-soluble and ecologically compatible monofunctional alcohols and/or polyfunctional alcohols which may also be watersoluble as the oil phase or as a component of the oil phase of oil-based or water-based drilling fluids and other fluid drill-hole treatment agents. The oleophilic polycarboxylic acid esters are especially suitable as component of the continuous oil phase of inverted fluids of the W/O type. Here--if rheologically suitable compounds will be employed--they may comprise the at least predominant portion of the continuous oil phase; but also possible is the concomitant use of complex oleophilic polycarboxylic acid esters, which are not or just to a restricted degree fluid in a temperature range of from 0.degree. C. to 20.degree. C., as an additive in fluid oils of the class of the non-polluting oils. Here, suitable oil mixing phases especially are oleophilic alcohols, ethers, respective esters of monocarboxylic acids and fluid oils based on oleophilic carbonic acid diesters.

Fluid drill-hole treatment agents based on polycarboxylic acid diesters

The use is disclosed of water-dispersible esters, which are fluid or at least plastically deformable at working temperature and have flash points of at least 80.degree. C., from saturated and/or unsaturated carboxylic acids with up to 36 carbon atoms and mono- and/or polyhydric alcohols, as at least the main constituent of the dispersed oil phase of water-based O/W-emulsion drilling fluids which are suitable for the environmentally friendly development of geological formations and which contain, if desired, insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsion drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.

Use of selected ester oils in water-based drilling fluids of the O/W

Use of selected oleophilic alcohols in water-based drilling fluids of

Soiled textile articles are washed by the addition of a determined amount of a detergent concentrate containing surfactants to the textile articles to be cleaned while the textiles are dry or only damp. The aqueous washing liquor is formed by the gradual addition of water to the textile articles while they are rotated. At room temperature, the detergent concentrate is to a substantial extent a paste-to dough-like substance, stable in form, and is applied to the textile articles in such an amount that the major portion of the surfactants together with further detergent constituents, if desired, are applied to the textiles or on an article of textile provided with markings for the correct detergent dose, as a dosing aid.

Machine washing process for soiled textile articles

A process for cleaning a soiled solid molded article in an aqueous detergent wash bath in the presence of ultrasound whereby pigmented and/or fatty soils are loosened from the soiled article. The wash bath is contacted with a soil-collecting polyfunctional quaternary ammonium compound which is at least substantially insoluble and/or is fixed to a solid which is substantially insoluble in the wash bath to collect from the wash bath at least a portion of the soils loosened from the article.

Process for cleaning soiled solid molded articles

The method of using polyfunctional quaternary ammonium compounds which are at least substantially insoluble in an aqueous fabric detergent solution and/or are fixed to solids correspondingly insoluble in such aqueous solution, as a soil-collecting, concentration-reducing agent for reducing the demand for conventional detergent components in the aqueous solution.

Laundry detergents and cleaners with reduced requirement for

Soil-collecting detergency enhancers for detergent solutions comprising a substantially water-insoluble polyfunctional quaternary ammonium compound or a water-soluble polyfunctional quaternary ammonium compound fixed to a water-insoluble solid carrier. The detergency enhancers may be used in the cleaning of soiled articles, particularly those soiled with pigments, in aqueous detergent solutions such as for washing fabrics.

Soil-collecting cleaning enhancers in aqueous surfactant laundering and

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Grevenbroich, Germany

Johann F Fues