The Goodyear & Tire Rubber Company

Other

Joel Muse, Jr

Paul Harry Sandstrom

Lawson G Wideman

Howard Allen Colvin

Kenneth Floyd Castner

Nissim Calderon

Kantilal Dahyabhai Patel

Aqueous liquids, such as water, can normally penetrate through conventional carpet. Thus, in cases where water is spilled on conventional carpet, it typically seeps through and ultimately reaches the flooring below. This trapped water can lead to bacterial or fungal growth which can further cause odors and/or deterioration of the carpet backing or flooring. This invention relates to a technique for treating carpet to render it impervious to aqueous liquids. This invention specifically discloses a process for treating carpet which is comprised of a pile and a backing to render said carpet impervious to aqueous liquids, said process comprising the steps of (1) coating the bottom side of said backing with a water-resistant coating composition which is comprised of (i) a latex of a polymer which is comprised of repeat units which are derived from (a) about 30 weight percent to about 84 weight percent vinyl aromatic moochers, (b) about 15 weight percent to about 65 weight percent alkyl acrylate moochers and (c) about 1 weight percent to about 6 weight percent unsaturated carbonyl group containing moochers, (ii) a coalescing solvent and (iii) a thickener; and (2) allowing the water-resistant coating composition to dry on the bottom side of said backing to produce the treated carpet which is impervious to aqueous liquids.

Water impervious carpet backing

By utilizing the vapor phase polymerization techniques of the present invention, numerous distinct and highly beneficial advantages are realized. For instance, cis-1,4-polyisoprene rubber and high cis-1,4-polybutadiene rubber having a consistent and controllable molecular weight can be easily and practically prepared without utilizing a solvent. The subject invention more specifically discloses a method for vapor phase polymerizing isoprene into cis-1,4-polyisoprene in a process comprising the steps of:

Vapor phase synthesis of cis-1, 4-Polyisoprene

By utilizing the vapor phase polymerization techniques of the present invention, numerous distinct and highly beneficial advantages are realized. For instance, cis-1,4-polyisoprene rubber and high cis-1,4-polybutadiene rubber having a consistent and controllable molecular weight can be easily and practically prepared without utilizing a solvent. The subject invention more specifically discloses a method for vapor phase polymerizing isoprene into cis-1,4-polyisoprene in a process comprising the steps of: (1) charging into a reaction zone said isoprene and a preformed catalyst system which is made by reacting an organoaluminum compound with titanium tetrachloride, preferably in the presence of at least one ether; wherein the isoprene is maintained in the vapor phase in said reaction zone by a suitable combination of temperature and pressure; (2) allowing said isoprene to polymerize into cis-1,4-polyisoprene in said reaction zone at a temperature within the range of about 0.degree. C. to about 100.degree. C. in the presence of a diarylamine, wherein said reaction zone is a horizontal, stirred reactor of substantially circular cross section containing a centrally-located drive shaft extending longitudinally through said reactor to which are attached a plurality of adjacently located paddles, which paddles cause essentially no forward or backward movement of the cis-1,4-polyisoprene contained in said reactor; and (3) withdrawing said cis-1,4-polyisoprene from said reaction zone.

Vapor phase synthesis of rubbery polymers

The present invention relates to a sulfur vulcanized rubber composition containing 0.1 to 10.0 phr of an oligomeric maleimide of the formula: ##STR1## or a maleamic acid of the formula: ##STR2## wherein R and R.sup.1 are individually selected from the group of radicals consisting of hydrogen, an alkyl having 1 to 4 carbon atoms or a halogen; R.sup.2 is selected from the group of radicals consisting of 1 to 12 carbon atoms; X has a value of from 1 to 146 and n has a value of from 0 to 4. The presence of the maleimide oligomer or maleamic acid improve cord adhesion to the sulfur vulcanized rubber compound.

Sulfur vulcanized rubber compounds containing maleamic acid

Sulfur vulcanized rubber compounds containing oligomeric maleimide

The present invention relates to a sulfur vulcanized rubber composition containing a silica filler and a bismaleimide of the formula: ##STR1## wherein R and R.sup.1 are individually selected from the group of radicals consisting of hydrogen, an alkyl having 1 to 4 carbon atoms or a halogen; R.sup.2 is selected from the group of radicals consisting of 1 to 12 carbon atoms; and n has a value of from 0 to 4. The bismaleimide functions as a coupling agent in the silica filled sulfur vulcanized rubber compound.

Growing community of inventors

Hudson, OH, United States of America

Joel Muse, Jr