Gm Global Technolgoy Operations, Inc.

Joel G Toner

Paul M Najt

Kushal Narayanaswamy

Gerald Andrew Szekely, Jr

Xingcheng Xiao

Cherian A Idicheria

Xingyi Yang

Michael P Balogh

Calvin K Koch

An electrolyte composition for electrochemical cells including a silicon-containing electrode is provided herein as well as electrochemical cells including the electrolyte composition. The electrolyte composition includes a lithium salt, fluoroethylene carbonate (FEC), a linear carbonate, vinylene carbonate, and a fluorosilane additive. The FEC and the linear carbonate are present in the electrolyte composition in a ratio of about 1:3 v/v to about 1:9 v/v.

Electrolyte for electrochemical cells with a silicon-containing electrode

A negative electrode for a secondary lithium battery is provided herein, as well as a method for assembling a secondary lithium battery including the negative electrode. The negative electrode includes a current collector having a first side and an opposite second side. A first negative electrode layer is disposed on the first side of the current collector and a second negative electrode layer is disposed on the second side of the current collector. A lithium metal layer is disposed (i) between the first and second negative electrode layers or (ii) on a major facing surface of the first or second negative electrode layer. An electrolyte infiltrates the first and second negative electrode layers and is in contact with the lithium metal layer. The electrolyte establishes a lithium ion transport path between the lithium metal layer and at least one of the first or second negative electrode layers.

Negative electrodes for secondary lithium batteries and methods of making the same

An exhaust aftertreatment system for purifying an exhaust gas feedstream expelled from an internal combustion engine that is operable at an air/fuel ratio that is lean of stoichiometry is described. The exhaust aftertreatment system includes a plasma reactor disposed upstream of a selective catalytic reactor device. The plasma reactor is electrically connected to a plasma controller. The plasma controller controls the plasma reactor to generate ozone from constituents of the exhaust gas feedstream, and the ozone reacts to oxidize nitrogen oxide contained in the exhaust gas feedstream to form nitrogen dioxide. The nitrogen dioxide reacts with a reductant in the selective catalytic reactor device to form elemental nitrogen and water.

Method and apparatus for exhaust purification for an internal combustion engine

An exhaust aftertreatment system for purifying an exhaust gas feedstream that is expelled from an internal combustion engine that is operable at an air/fuel ratio that is lean of stoichiometry is described. The exhaust aftertreatment system includes a barrier discharge plasma reactor that is disposed upstream relative to a catalytic reactor and electrically connected to a plasma controller. The barrier discharge plasma reactor is controlled to generate ozone from constituents of the exhaust gas feedstream when the internal combustion engine is operating at a lean air/fuel ratio and at a low temperature condition. The generated ozone reacts, in the catalytic reactor, to oxidize non-methane hydrocarbons contained in the exhaust gas feedstream when the internal combustion engine is operating at lean air/fuel ratio and at low temperature conditions.

A method for controlling ammonia generation in an exhaust gas feedstream output from an internal combustion engine equipped with an exhaust aftertreatment system including a first aftertreatment device includes executing an ammonia generation cycle to generate ammonia on the first aftertreatment device. A desired air-fuel ratio output from the engine and entering the exhaust aftertreatment system conducive for generating ammonia on the first aftertreatment device is determined. Operation of a selected combination of a plurality of cylinders of the engine is selectively altered to achieve the desired air-fuel ratio entering the exhaust aftertreatment system.

Combustion driven ammonia generation strategies for passive ammonia SCR system

A spark-ignition, direct-injection internal combustion engine is coupled to an exhaust aftertreatment system including a three-way catalytic converter upstream of an NH3-SCR catalyst. A method for operating the engine includes operating the engine in a fuel cutoff mode and coincidentally executing a second fuel injection control scheme upon detecting an engine load that permits operation in the fuel cutoff mode.

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Bad Axe, MI, United States of America

Joel G Toner