Hoechst Aktiengesellschaft

Beiersdorf Ag

Cassella Aktiengesellschaft

Deutsche Gelatine-fabriken Stoess Ag

Jochen M Quack

Alwin K Reng

Gunter Blaschke

Werner Skrypzak

Friedrich Engelhardt

Hans-Peter Rieck

Herbert Stuhler

Manfred Hofinger

Hans-Jurgen Kalz

Walter Kunz

Joachim Ribka

Arno Holst

Willi Steckelberg

Udo Hoppe

Hans-Walter Bucking

Karl Hintermeier

Adolf May

Juliane Balzer

Ulrich Karsunky

Winfried Ehrl

Hans Ludwig Panke

Wolfram Schidlo

Johann F Hanauer

Angelika Turowski

Klaus-Peter Wittern

Armin Weiss

Kerstine Rabas

Josef Sauer

High molecular weight protein/fatty acid condensation products obtained by reaction of one mole of a protein hydrolysate of average molecular mass 3,000 to 7,000 with 0.5 to 3, preferably 2 to 2.5, moles of a C.sub.12 -C.sub.18 -fatty acid chloride in aqueous medium at a pH of 7 to 12. These protein/fatty acid condensation products are distinguished by eliciting no mucosal irritation whatever. They are therefore outstandingly suitable as surfactants for mild washing and cleansing agents.

High molecular weight protein/fatty acid condensation products which are

Fatty acid-modified polysters composed of polyalkylene oxide and dimerized fatty acids, of the formula ##STR1## in which R is C.sub.8 -C.sub.22 -alkyl or C.sub.8 -C.sub.22 -alkenyl, preferably C.sub.12 -C.sub.18 -alkyl, R.sup.1 is the alkyl skeleton of a dimerized fatty acid having 22 to 42, preferably 34 carbon atoms, A is --C.sub.2 H.sub.4 -- or --C.sub.3 H.sub.6 --, n is a number from 1 to 5, preferably 1 to 3, and x is a number from 20 to 150, preferably 23 to 140. These are prepared by simultaneous reaction of the underlying dimerized fatty acid, polyalkylene oxide and fatty acid. The polyesters obtained are used as agents for increasing the viscosity of surfactant-containing cosmetic, pharmaceutical and industrial products.

Method of increasing viscosity with fatty acid-modified polyesters and

An agent for treatment of hair and skin, containing a quarternary ammonium compound of the formula ##STR1## in which R.sub.1 and R.sub.2 may be identical or different and denote C.sub.8 -C.sub.22 -alkyl or C.sub.8 -C.sub.22 -alkenyl, R.sub.3 denotes C.sub.1 -C.sub.3 -alkyl, x denotes a number from 1 to 3, and A.sup..crclbar. denotes the anion of C.sub.2 -C.sub.6 -carboxylic acid, which may contain 1 to 3 hydroxyl groups, or the hydrogen phosphate anion.

Cosmetic agents for hair and skin treatment

Adsorbents for polar organic compounds can be prepared by reacting 5-80% of an organic ammonium compound with 20-95% of a crystalline alkali metal phyllosilicate belonging to the group comprising phyllosilicates of the formula

Adsorbents based on phyllosilicic acids which have been modified so as

Process for the preparation of copolymers from acrylamide and acrylic or methacrylic acid, wherein to prepare 100 parts by weight of the copolymer, (A) 10-90 parts by weight of acrylamide, (B) 90-100 parts by weight of acrylic acid and/or methacrylic acid or of a salt thereof, (C) 0-40 parts by weight of another copolymerizable monomer and (D) 0-5 parts by weight of a copolymerizable crosslinking agent which has two or more olefinic double bonds are polymerized in an alcohol having 1-4 carbon atoms by precipitation polymerization such that 10-90% by weight of the alcohol, 10-90% by weight of the total amount of monomers (A), (B) and (C) together with 100% by weight of the crosslinker substance are initially mixed, polymerization is started with 10-100% by weight of the initiator and then the remainder of the solvent, monomers, crosslinking agent and initiator to make up to 100% is metered in, as individual components or as a mixture, after the polymerization has started.

Process for the preparation of copolymers

Pearl luster dispersions comprising a fatty acid glycol ester, a fatty acid alkanolamide, a nonionic surfactant of the formula

Nonionic fluent pearl luster dispersions

Pearlescent dispersions consisting of a fatty acid glycol ester, a fatty acid alkanolamide, one or more surfactants of the formulae ##STR1## in which the individual symbols of these formulae have the meanings given in the description, salts and water in the amount to make up to 100%. Pearlescent dispersions based on these surfactants have the advantage that they already have good flow properties at temperatures below 20.degree. C.

Pearlescent dispersion with good flow properties and a low surfactant

Novel quaternary oxalkylated polyesters prepared from oxalkylated fatty amines by polycondensation with a dicarboxylic acid and subsequent reaction with an alkylene oxide and a carboxylic acid or a mineral acid or with a quaternizing agent such as methyl chloride, are described. The compounds are suitable for use as cosmetic active compounds, in particular for cosmetic care of the hair.

Quaternary oxalkylated polyesters, a process for their preparation and

The invention relates to novel O/W emulsifiers obtainable by reacting one mole of esters of wool wax acids and glycerol, in particular partial esters, with 0.5 to 30 moles of ethylene oxide, a process for the preparation of these novel products and cosmetic agents containing these in an amount of 1 to 15% by weight, based on the total formulation.

O/W Emulsifiers for cosmetic purposes

Softener-containing washing agents which, in addition to the customary components of washing agents, contain 0 to 10% by weight of a quaternary ammonium compound and 1 to 30% by weight of a softener system which comprises 10 to 90% by weight of a tertiary amine and 90 to 10% by weight of a crystalline sheet-silicate of the formula

Softener-containing washing agent

Betaine-amine oxides of the formula ##STR1## in which R denotes alkyl, alkenyl or hydroxyalkyl, each of which has 8-22 carbon atoms, R.sup.1 denotes hydrogen or methyl, R.sup.2 denotes ethylene, propylene or 2-hydroxypropylene, R.sup.3, R.sup.4 and R.sup.5 can be identical or different and denote C.sub.1 -C.sub.3 -alkyl or a group of the formula ##STR2## or R.sup.3 denotes a group of the formula --R.sup.2 --BR.sup.4 R.sup.5, X denotes a direct bond or a group of the formula

Betaine-amine oxides, a process for their preparation and their use as

Hair shampoo and body cleansing agent having a content of alkyl-sulfatobetaine of the formula ##STR1## wherein R.sub.1 is C.sub.8 -C.sub.22 alkyl or C.sub.8 -C.sub.22 alkenyl, preferably C.sub.12 -C.sub.18 alkyl, R.sub.2 is C.sub.1 -C.sub.4 alkyl, preferably methyl, R.sub.3 is C.sub.1 -C.sub.4 hydroxyalkyl or a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n H and n is an integer of from 1 to 10.

Hair shampoos and body cleansing agents having a content of

Bis-betaine-amine oxides of the formula ##STR1## in which R is a saturated or an olefinically unsaturated hydrocarbon radical having 1 to 3 double bonds and 8 to 22 carbon atoms,

Bis-betaine-amine oxides, process for their preparation, and cleaning

Bis-betaines of the formula ##STR1## in which R denotes a saturated or an olefinically unsaturated hydrocarbon radical which has 1 to 3 double bonds and 8 to 22 carbon atoms,

Bis-betaines, a process for their preparation, and cleaning agents

Triamine-trioxides of the formula ##STR1## in which R denotes a saturated or an olefinically unsaturated hydrocarbon radical which has 1 to 3 double bonds and 8 to 22 carbon atoms, n.sup.1 and n.sup.2 represent an integer from 2 to 3, and n.sup.1 and n.sup.2 can be identical or different, and a, b, c and d, which are identical or different, each is a number from 1 to 5, with the proviso that the sum (a+b+c+d) should be at most 10. The compounds are prepared from primary amines of the formula RNH.sub.2 by dicyanoalkylation, hydrogenation, ethoxylation and oxidation with hydrogen peroxide. They are suitable for formulating industrial and also cosmetic cleaning agents.

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Eppstein, Germany

Jochen M Quack