Exxon Research and Engineering Company

Exxonmobil Chemical Patents Inc.

Joanne K Pabst

Robert J Lang

Stephen Neil Vaughn

William E Winter, Jr

Claude C Culross

Joel Edward Schmieg

Steve D Reynolds

Wesley J Robertson

Carl Dean Heard

Tomasz J Gralinski

W Bing Kao

Thomas R Rios

Process for pelletizing polyethylene resin are disclosed, the processes providing pelletized resin having reduced occurrence of defects such as black specks. Polyethylene resin is conveyed in a downstream direction through a mixer having a feed zone, a melt-mixing zone downstream of the feed zone, and a melt-conveying zone downstream of the melt-mixing zone; contacted with nitrogen gas in the melt-conveying zone; and conveyed through a mixer discharge to form pellets. Also disclosed are processes of forming films from such resins, the films having reduced occurrence of gels, and articles such as blow molded or injection molded articles.

Method of processing polyethylene resins

This invention is directed to a staged process for producing liquids from coal or similar carbonaceous feeds combining a pretreatment stage and a liquefaction stage. In the process, the feed is reacted with carbon monoxide and water at an elevated temperature and pressure. The so pretreated coal is sent to a liquefaction reactor, wherein the coal is reacted at a somewhat higher temperature in the presence of hydrogen and catalyst to produce valuable liquid fuels or feedstocks.

Liquefaction of coal with aqueous carbon monoxide pretreatment

Carbonaceous solids are contacted in the presence of water with potassium sulfate and a calcium compound selected from the group consisting of calcium oxide, calcium hydroxide, and calcium carbonate thereby producing treated carbonaceous solids which are then gasified. The calcium compound apparently activates the relatively noncatalytic potassium sulfate thereby producing a substantial catalytic effect on the gasification reactions.

Process for the catalytic gasification of coal

A carbonaceous feed material, a potassium compound having a relatively poor catalytic activity as compared to that of potassium carbonate, and a sodium or lithium salt are introduced into a gasification reactor. The carbonaceous material is then gasified in the presence of the added potassium and sodium or lithium constituents. The added sodium or lithium salt apparently activates the relatively noncatalytic potassium compound thereby producing a substantial catalytic effect on the gasification reactions. In general, activation of the noncatalytic potassium compound will take place when the sodium or lithium compound introduced into the reactor is either a salt of a weak acid or a salt of a strong acid that is converted to a sodium or lithium salt of a weak acid in the reactor at gasification conditions.

Catalytic coal gasification process

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Crosby, TX, United States of America

Joanne K Pabst