Bayer Corporation

Joachim Werner

Herman P Doerge

Scott A Kane

Eric F Boonstra

Charles E Mortimer

Ronald Zibert

This invention relates to novel polyisocyanate compositions, to a process for these polyisocyanate compositions, to a process for the production of cold cure flexible molded foams wherein this novel polyisocyanate composition comprises the polyisocyanate component, and to the cold cure flexible molded foams produced by this process. The novel polyisocyanate compositions of the present invention are characterized by an NCO group content of more than about 15%, (preferably from about 20% to less than about 33%, more preferably from about 25% to about 32%), and comprising: (1) from about 70 to 99% by weight of a polymethylene poly(phenyl isocyanate) having an NCO group content of from about 30 to about 33%, and a monomer content of from about 40% to about 90% by weight and (2) from about 1 to about 30% by weight of a prepolymer of diphenylmethane diisocyanate having an NCO group content of from about 2% to about 20%, and comprising the reaction product of: (a) diphenylmethane diisocyanate; and (b) a polyether polyol.

Polyisocyanate compositions and a process for the production of low-density flexible foams with low humid aged compression sets from these polyisocyanate compositions

Azeotropic compositions made up of (a) from about 26 to about 72% by weight perfluorohexane and (b) one compound selected from (1) about 36 to about 74% by weight 2-methyl butane or (2) about 28 to about 53% by weight n-pentane in which the sum of the weight percent (a) and weight percent (b) is 100 percent may be used as blowing agents in the production of polyurethane/polyurea foams.

Azeotropic compositions of perfluorohexane and hydrocarbons having 5 carbon atoms and the use thereof in the production of foams

Azeotropic compositions made up of (a) from about 4 to about 50% by weight 1,3-dioxolane and (b) one compound selected from (1) about 75 to about 96% by weight cyclopentane, (2) about 60 to about 79% by weight 2-methyl pentane, (3) about 59 to about 77% by weight 3-methyl pentane, and (4) about 50 to about 69% by weight n-hexane in which the sum of the weight percent of (a) plus weight percent of (b) is approximately 100 percent are used as blowing agents in the production of polyurethane/polyurea foams.

Azeotropic compositions of 1,3-dioxolane and hydrocarbons having 5 or 6 carbon atoms and the use thereof in the production of foams

Azeotropic compositions made up of from about 60 to about 78% by weight of 1,1,1,3,3-pentafluoropropane and from about 22 to about 40% by weight of tetramethylsilane have been found to be particularly useful as blowing agents for the production of polyurethane foams.

Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and

Azeotropic compositions made up of from about 68.1 to about 69.1% by weight of dimethoxymethane, from about 29.7 to about 30.7% by weight of cyclopentane and from about 0.7 to about 1.7% by weight in which the sum of the weight percents of the components is 100% by weight. These azeotrope-like compositions are useful as blowing agents in the production of polyurethane foams.

Azeotrope-like compositions of dimethoxymethane, cyclopentane and

Azeotrope-like compositions of 1,1,1,3,3 pentafluoropropane and

An azeotropic composition made up of from about 58 to about 77% by weight of dimethoxymethane and from about 23 to about 42% by weight of cyclopentane is used as a blowing agent in a process for the production of polyurethane foams.

Azeotropic compositions of dimethoxymethane and cyclopentane and the use

Azeotropic compositions made up of (a) from about 73 to about 88% by weight perfluorohexane and (b) one compound selected from (1) about 14 to about 27% by weight 2-methyl pentane or (2) about 13 to about 25% by weight 3-methyl pentane or (3) about 12 to about 23% by weight, provided that the sum of the weight percent (a) plus weight percent (b) is 100 percent are suitable blowing agents for the production of foams.

Azeotropic compositions of perfluorohexane and hydrocarbons having 6

An azeotropic composition made up of from about 73 to about 87% by weight of 1,1,1,4,4,4-hexafluorobutane and from about 13 to about 27% by weight of n-pentane is used as a blowing agent in a process for the production of polyurethane foams.

Azeotropic compositions of 1,1,1,4,4,4-hexafuorobutane and n-pentane and

Azeotropic compositions made up of from about 65 to about 81% by weight of 1,1,1,3,3-pentafluoropropane and from about 19 to about 35% by weight of 2-methyl butane have been found to be particularly useful as blowing agents for the production of polyurethane foams.

Azeotrope-like compositions of 1,1,1,3,3-pentafluoropropane and 2-methyl

Azeotropic compositions made up of from about 64 to about 80% by weight of 1,1,1,4,4,4-hexafluorobutane and from about 20 to about 36% by weight of 2-methyl butane have been found to be particularly useful as blowing agents for the production of polyurethane foams.

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Bethel Park, PA, United States of America

Joachim Werner