Henkel Kommanditgesellschaft Auf Aktien

Henkel & Cie G.m.b.h.

Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa)

Joachim Galinke

Bernd Wegemund

Werner Gruber

Brigitte Hase

Jurgen Keil

Christian Hase

Norbert Wiemers

Konrad Engelskirchen

Wolfgang Gress

Peter Krings

Gunter Jakobi

Helmut Eschwey

Henning Abendroth

(Meth)acrylic acid esters of tricyclo [5.2.1.0..sup.2.6 ]-decane derivatives having the formula ##STR1## wherein A represents the radical ##STR2## wherein R is a divalent hydrocarbon having 2 to 6 carbon atoms selected from the group consisting of alkylene, alkenylene, cyclohexylene, phenylene and tetrahydrophenylene, and R.sub.1 is a member selected from the group consisting of hydrogen and methyl; as well as the process for the production of the esters, and their use in adhesive or sealing compositions which harden under exclusion of oxygen.

(Meth)acrylic acid esters of tricyclo[5.2.1.0..sup.2.6 ]-decane

Aqueous dispersions of cross-linkable alkyd and/or amino resins, which contain reactive surface active compounds produced by addition of glycide and/or ethylene oxide to a starting compound having a hydrophobic aliphatic radical, optionally substituted by an aryl radical, which contains al least one labile hydrogen atom which can react with an epoxide, wherein the number of hydroxyl groups in said surface active compounds is between 2 and 30, are useful as coating agents or varnish binding agents.

Aqueous dispersions of alkyd and/or amino resins containing glycide and

Water-in-oil emulsions containing from 2 to 20% by weight of polymeric emulsifiers comprising statistical copolymers composed of units of the general formulae ##STR1## in the molar ratio of (I) to (II) of 2:1 to 20:1; wherein X is hydrogen or methyl, R.sub.1 is alkyl having 6 to 24 carbon atoms and R.sub.2 is ##STR2## 20 to 75% by weight of water; and the remainder to 100% by weight of conventional oily substances used in cosmetic emulsions.

Cosmetic emulsions containing copolymers of

Water-in-oil emulsions containing from 2 to 20% by weight of polymeric emulsifiers comprising statistical copolymers composed of units of the general formulae ##STR1## in the molar ratio of (I) to (II) of 2:1 to 20:1, wherein X is hydrogen or methyl, R.sub.1 is alkyl having 6 to 24 carbon atoms, and R.sub.2 is --CH.sub.2 --CH.sub.2 --OH, --CH.sub.2 --CH(OH)--CH.sub.3,--CH.sub.2 --CH(OH)--CH.sub.2 OH or --CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --OH; 20 to 75% by weight of water; and the remainder to 100% by weight of conventional oily substances used in cosmetic emulsions.

Cosmetic emulsions containing copolymers of alkyl (meth) acrylates and

Water-in-oil emulsions containing from 2% to 20% by weight of polymeric emulsifiers comprising statistical copolymers composed of units of the general formulae ##STR1## in the molar ratio of (I) to (II) of 2:1 to 20:1, wherein X is hydrogen or methyl, R.sub.1 is alkyl having 6 to 24 carbon atoms, and R.sub.2 is --NH--CH.sub.2 OH, --NH--CH.sub.2 CH.sub.2 OH, or --N(CH.sub.2 CH.sub.2 OH).sub.2 ; 20 to 75% by weight of water; and the remainder to 100% by weight of conventional oily substances used in cosmetic emulsions.

Cosmetic emulsions containing copolymers of alkyl(meth)acrylates and

Reaction products of glycidyl (meth)acrylate with half esters containing carbonate groups are components of anaerobically-setting adhesive compositions based on (meth) acrylic esters and organic peroxides.

Anaeorbically hardening adhesives and sealants based on (meth)acrylic

An aqueous adhesion assistant or binder dispersion for use in the production of composite bodies by vulcanizing a vulcanizable rubber composition on a substrate which is stable under vulcanization conditions comprising water and at least one dispersing agent and a solids content of from 20% to 50% by weight of a solids composition of per

Aqueous adhesion assistant dispersion for producing composite bodies by

Polycarbonates terminated by (meth)acrylic ester groups are components of anaerobically setting adhesive compositions based on (meth)acrylic esters and organic peroxides.

Anaerobically hardening adhesives and sealants based on (meth)acrylic

Reaction products of glycidyl (meth)acrylate with linear half esters of dicarboxylic acids are components of anaerobically-setting adhesive compositions based on (meth)acrylic esters and organic peroxides.

Water-in-oil emulsions wherein the emulsifier consists essentially of a copolymer or terpolymer of N-vinylpyrrolidone with a C.sub.6-24 alkyl or cycloalkyl acrylate or methacrylate, and vinyl acetate if desired, and the continuous phase is a cosmetically acceptable oily material which can be prepared easily, safely and inexpensively. The emulsions are substantially odorless and are cosmetically acceptable for the care of the skin.

Cosmetic emulsions containing N-vinylpyrrolidone-alkyl acrylate

Water-in-oil emulsions wherein the emulsifier consists essentially of copolymers of N-vinylpyrrolidone and a vinyl C.sub.5-24 alkylcarboxylate (if desired with vinyl acetate) and the continuous phase is a cosmetically acceptable oily material can be prepared easily, safely and inexpensively. The emulsions are substantially odorless and are cosmetically acceptable for the care of the skin.

Cosmetic emulsions containing N-vinylpyrrolidone/vinyl alkylcarboxylate

Water-in-oil emulsions wherein the emulsifier is a copolymer of 1 mol of acrylamide with 2 to 20 mols of at least one ethylenically unsaturated ester copolymerizable therewith selected from the group consisting of vinyl alkylcarboxylates, alkyl and cycloalkyl acrylates, and alkly and cycloalkyl methacrylates, wherein the alkyl and cycloalkyl groups contain 6 to 24 carbon atoms, and the continuous phase is a cosmetically acceptable oil, which can be prepared easily, safely and inexpensively. The emulsions are substantially odorless and are cosmetically acceptable for the care of the skin.

Cosmetic emulsions containing acrylamide copolymer

Cosmetic emulsions containing from 2 to 20% by weight of polymeric emulsifiers capable of forming water-in-oil creams comprising a copolymer of N-vinylimidazole, an alkyl (meth)acrylate and optionally vinyl acetate; 20 to 75% by weight of water; and the remainder to 100% by weight of a cosmetically-acceptable oily substance.

Water-in-oil creams with polymeric emulsifiers

Anaerobically hardening adhesive compositions principally composed of a polymerizable acrylic ester and an organic aerobically-inactive, anaerobically-active peroxide polymerization catalyst therefor possess improved latent adhesive properties for metals when they contain an acrylic ester-acid of the formula: ##STR1## wherein R is --H or --CH.sub.3 ; R' is H, halogen, --COOH, --CN, and loweralkyl, and X is a divalent C.sub.1-6 hydrocarbon group, or a mixture of such ester-acids.

Anaerobically compositions containing acrylic ester-acids

Organic percarboxylic acids are stabilizers for anaerobically-setting adhesive compositions wherein the principal adhesive component is a (meth) acrylic acid ester and the catalyst is an organic peroxide. The percarboxylic acid improves the storage-stability of the adhesives in contact with air.

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Dusseldorf-Holthausen, Germany

Joachim Galinke