China Petroleum Chemical Corporation

Research Institute of Petroleum Processing, Sinopec

Other

China Petrochemical Corporation

Jiushun Zhang

Jun Long

Zhijian Da

Chaogang Xie

Huiping Tian

Yuxia Zhu

Jianhong Gong

Xingtian Shu

Hong Nie

Anguo Mao

Yibin Luo

Zhenyu Chen

Zhigang Zhang

Lishun Dai

Yujian Liu

Wei Wang

Youhao Xu

Dadong Li

Xieqing Wang

Mingyuan He

Shuandi Hou

Yaoqing Guo

Yan Cui

Shouye Cui

Haitao Song

Xiaoli Wei

Jingchuan Yu

Zhanzhu Zhang

Yongcan Gao

Jinlian Tang

Jianguo Ma

Peng Wang

Zheng Li

Wei Lin

Di Wang

Qiang Liu

Xuhong Mu

Kejia Xu

Xuefeng Wu

Chuanfeng Niu

Yuying Zhang

Xiaoxiang Zhong

Genquan Zhu

Wenhua Xie

Zaiting Li

Qiuqiao Jiang

Yinan Yang

Yihua Yang

Zekun Li

Zhiguo Wu

Qiang Fu

Tao Liu

Yan Sun

Nan Jiang

Xue Yang

Weilin Zhang

Jun He

Wenbin Jiang

Mingde Xu

Jun Fu

Ming Kai Dong

Xuefeng Li

Jinbiao Guo

Longsheng Tian

Zhenbo Wang

Weimin Lu

Jiasong Yan

Songnian Li

Hua Cui

Zhiqiang Qiao

Zeyu Wang

Haiping Shen

Jiguang Li

Cuihong Wang

Youbao Lu

Jialin Liang

Beiyan Chen

Jinlong He

Zhemin Zhang

Huandi Hou

Yalin Liu

Dawei Guo

Zhonghong Qiu

Wanhong Zhang

Shuandl Hou

Shaobing Yu

Chenghan Yan

Raichi Zhang

Zubi Chen

Shuxin Cui

Yamin Wang

Ruichi Zhang

Xuefeng Chen

Zhihong Tian

Bingtian Zhu

Lufeng Lv

Ming Dong

A structured monolithic catalyst has a structured monolithic carrier and a coating of active components. The coating of active components comprises active metal components and a substrate. The active metal components conclude a first metal element, a second metal element, a third metal element and a fourth metal element. The first metal element includes Fe and Co; the second metal element is at least one selected from the group consisting of the metal elements of the Group IA and/or IIA; the third metal element is at least one selected from the group consisting of the non-noble metal elements of the Groups IB to VIIB; and the fourth metal element is at least one selected from the group consisting of the noble metal elements.

Structured monolith catalyst for reducing NOX emission in flue gas, preparation method and applications thereof

In a method and system for treating a catalytic cracking gasoline, a catalytic cracking process, or a plant employs a fluidized reactor to carry out hydrodealkylation treatment on a catalytic cracking oil gas or catalytic cracking gasoline, so that heavy aromatics present therein can be efficiently converted into light olefins and light aromatics. The method and system can improve the yield of light olefins, allow a long-period stable operation, relieve the contradiction between supply and demand of light aromatics, and solve the problem of high content of heavy aromatics that have low value and are difficult to be utilized in aromatics present in oil gas from catalytic cracking units.

Method and system for treating catalytic cracking reaction product and use thereof

A method for producing light aromatics, includes the steps of: i) contacting a feedstock comprising heavy aromatic(s) with a catalyst in a fluidized reactor for aromatics lightening reaction in the presence of hydrogen to obtain a product rich in C6-C8 light aromatic(s) and a spent catalyst, wherein the heavy aromatic is one or more selected from C9+ aromatics; ii) separating the resulted product rich in C6-C8 light aromatic(s) to obtain hydrogen, a non-aromatic component, C6-C8 light aromatic(s) and a C9+ aromatic component; and iii) recycling at least a part of the C9+ aromatic component to the fluidized reactor. The method has strong adaptability to feedstocks and high flexibility in operation and allows a long-period stable operation. The method can produce high-value light aromatics from heavy aromatics that are difficult to be treated and utilized.

Method for producing light aromatic

A process for producing light olefins from inferior oils includes the steps of: subjecting an inferior oil to a thermal conversion reaction in the presence of hydrogen to obtain a conversion product; separating the conversion product to obtain a first separated product; separating the first separated product to obtain an upgraded oil and a pitch; subjecting the upgraded oil to hydro-upgrading to obtain a hydro-upgraded oil; separating the hydro-upgraded oil to obtain a hydro-upgraded heavy oil; and subjecting the hydro-upgraded heavy oil to catalytic cracking to obtain a catalytic cracking product comprising a light olefin.

Process and system for producing light olefins from inferior oils

The present invention relates to the field of catalytic cracking, and discloses a composition capable of reducing CO and NOx emissions, the preparation method and use thereof, and a fluidized catalytic cracking method. The inventive composition capable of reducing CO and NOx emissions comprises an inorganic oxide carrier, and a first metal element, optionally a second metal element, optionally a third metal element and optionally a fourth metal element supported on the inorganic oxide carrier, wherein the first metal element includes Fe and Co, and wherein the weight ratio of Fe to Co is 1:(0.1-10) on an oxide basis. The inventive composition has better hydrothermal stability and higher activity of reducing CO and NOx emissions in the flue gas from the regeneration.

Composition capable of reducing CO and NOx emissions, preparation method therefor and use thereof, and fluid catalytic cracking method

A process for producing catalytic cracking gasoline includes the following steps: i) subjecting a heavy feedstock oil to a catalytic cracking reaction in the presence of a first catalytic cracking catalyst to obtain a first reaction product; ii) subjecting a hydrogenated cycle oil to a catalytic cracking reaction in the presence of a second catalytic cracking catalyst to obtain a second reaction product; iii) separating a mixture of the first reaction product and the second reaction product to obtain a catalytic cracking gasoline and a catalytic cracking light cycle oil; iv) subjecting the catalytic cracking light cycle oil or a fraction thereof to hydrogenation to obtain a hydrogenated product; and v) recycling the hydrogenated product to the step ii) as the hydrogenated cycle oil.

Process for producing catalytic cracking gasoline with a high octane number

A catalytic cracking process includes the following steps: i) subjecting a heavy feedstock oil to flail catalytic cracking; ii) separating the catalytic cracking reaction product obtained from step i) to obtain a catalytic cracking gasoline and a catalytic cracking light cycle oil; iii) splitting the catalytic cracking gasoline to obtain a light gasoline fraction, a medium gasoline fraction and a heavy gasoline fraction; iv) subjecting the catalytic cracking light cycle oil to hydrogenation to obtain a hydrogenated light cycle oil); v) mixing a portion of the light gasoline fraction with at least a portion of the hydrogenated light cycle oil to obtain a mixed fraction; vi) subjecting the mixed fraction to catalytic cracking; and vii) subjecting a portion of the medium gasoline fraction to flail catalytic cracking. The process is capable of producing more catalytic cracking gasoline, reducing the olefin content of the catalytic cracking gasoline, and increasing its octane number.

Catalytic cracking process with increased production of a gasoline having a low olefin content and a high octane number

A process for producing light olefins and aromatics, which comprises reacting a feedstock by contacting with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone among the reaction zones downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone, separating the spent catalyst from the reaction product vapor, regenerating the separated spent catalyst and returning the regenerated catalyst to the reactor, and separating the reaction product vapor to obtain the desired products, light olefins and aromatics. This process produces maximum light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.

Process for producing light olefins and aromatics

The present invention provides a catalytic cracking catalyst, processing method and use thereof. When the catalyst is added into a commercial catalytic cracking unit, it has an initial activity of not higher than 80, preferably not higher than 75, more preferably not higher than 70, a self-balancing time of 0.1-50 h, and an equilibrium activity of 35-60. Said method enables the activity and selectivity of the catalyst in the catalytic cracking unit to be more homogeneous and notably improves the selectivity of the catalytic cracking catalyst, so as to obviously reduce the dry gas and coke yields, to sufficiently use steam and to reduce the energy consumption of the FCC unit.

Catalytic cracking catalyst having a higher selectivity, processing method and use thereof

The present invention relates to an airflow particle sorter, comprising: a top-sealed sorter main body, a discharge port, an outtake tube and at least one directing-intake port; the inner space of the sorter main body, from the above to the bottom, includes, a straight tube zone and a cone zone, the conical bottom of the cone zone is connected to the straight tube zone; the discharge port is located at the bottom of the cone zone; the directing-intake port is installed in the upper part of the straight tube zone in a tangential direction of the straight tube zone, and is communicated with the inner space of the sorter main body; the outtake tube is hermetically inserted into the top of the sorter main body, and extends downwardly to the lower part of the straight tube zone, and the outtake tube has a sealed bottom end; the lower part of the outtake tube is installed with at least one directing-outtake port, which communicates the outtake tube with the inner space of the sorter main body, the directing-outtake port is installed in a tangential direction of the outtake tube. The present invention further relates to a fluidized bed reactor and an adsorption desulfurization reaction apparatus as well as an adsorption desulfurization process.

Adsorption desulfurization process for hydrocarbons and a reaction apparatus therefor

Disclosed is a combination process for improved hydrotreating and catalytic cracking of hydrocarbon oils, including: contacting residual oil, catalytic cracking cycle oil, and optional distillate oil with a hydrotreating catalyst under hydrotreating conditions in the presence of hydrogen followed by separation of the reaction products to obtain gas, hydrogenated naphtha, hydrogenated diesel oil, and hydrogenated tail oil; contacting the hydrogenated tail oil and optional normal catalytic cracking feedstock oil with a cracking catalyst under catalytic cracking conditions followed by separation of the reaction products to obtain dry gas, hydrogenated naphtha, liquefied petroleum gas, catalytic cracked gasoline, catalytic cracked diesel oil, and catalytic cracking cycle oil; wherein the hydrogenated tail oil and/or normal catalytic cracking feedstock oil are separated into at least two fractions, the light and the heavy fractions or normal catalytic cracking heavy feedstock oil and normal catalytic cracking light feedstock oil, prior to contacting the hydrogenated tail oil and/or normal catalytic cracking feedstock oil with the cracking catalyst. The process according to the present invention is especially suitable for conversion of hydrocarbon oils to produce more products of gasoline or diesel oil.

Integrated process for hydrogenation and catalytic cracking of hydrocarbon oil

The present invention discloses a method of removing sulfur oxides and/or nitrogen oxides in a regeneration flue gas emitted from a regenerator of a catalytic cracking plant and recovering the elemental sulfur and an apparatus therefor.

Method of removing sulfur oxides and nitrogen oxides in the flue gas

The present invention relates to a mesopore material of a catalyst for upgrading acid-containing crude oil. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)NaO.(1-50)MO.(6-58)AlO.(40-92)SiO, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The present invention further relates to a process for manufacturing said mesopore material and the use thereof. The catalyst prepared from the mesopore material provided in the present invention is suitable for the catalytic upgrading of inferior acid-containing crude oil and for the removal of organic acids, carbon residues and metals in the crude oil, and thus has very good economic benefits.

Catalyst for upgrading inferior acid-containing crude oil, process for manufacturing the same, and application thereof

Disclosed is a combination process for improved hydrotreating and catalytic cracking of hydrocarbon oils, including: contacting residual oil, catalytic cracking cycle oil, and optional distillate oil with a hydrotreating catalyst under hydrotreating conditions in the presence of hydrogen followed by separation of the reaction products to obtain hydrogenated tail oil and other products; contacting the hydrogenated tail oil and optional normal catalytic cracking feedstock oil with a cracking catalyst under catalytic cracking conditions followed by separation of the reaction products; wherein the hydrogenated tail oil and/or normal catalytic cracking feedstock oil are separated into at least two fractions prior to contacting the hydrogenated tail oil and/or normal catalytic cracking feedstock oil with the cracking catalyst.

Combined process of hydrotreating and catalytic cracking of hydrocarbon oils

The present invention discloses catalytic cracking apparatus and process, which are useful for catalytic cracking of heavy oils with a high heavy oil conversion, a high propylene yield and low dry gas and coke yields.

Catalytic cracking apparatus and process

Growing community of inventors

Beijing, China

Jiushun Zhang