Sk Innovation Co., Ltd.

Sk Global Chemical Co., Ltd.

Sk Energy Co., Ltd.

Sabic Sk Nexlene Company Pte. Ltd.

Jisu Jeong

Myungahn Ok

Sujith Sudevan

Anish Cyriac

SungJae Na

Kwangjin Chung

Bunyeoul Lee

Jaeki Min

Yonggyu Han

JongEon Seong

BunYeoul Lee

Choonsik Shim

Daeho Shin

Jongsok Hahn

Hoseong Lee

Jieun Yoo

Sujith S

Dongcheol Shin

SangHwan Lee

Bun Yeoul Lee

Sungseok Chae

Seungbum Kwon

Dong-Won Kim

Sun Woong Choi

Myung Ahn Ok

Jaeho Lee

Ho-Seong Lee

Dong-cheol Shin

Ilgu Jung

S Sujith

Hyeongtaek Ham

Kodiyan Varghese Jobi

Sudevan Sujith

Hongdae Kim

YoungGyu Han

Lim Ok Pyun

Byul Ha Na Min

Junga Lee

Young Gyu Han

Sung-Jae Na

Jangjae Lee

Mingyoo Park

Gyungrok Kim

Seongjun Lee

YeonJeong Choi

Gwangbin Moon

Byoungmu Chang

Sungjae Na

Provided are a carbon dioxide absorbent including an ionic liquid including a choline-based cation and a phenolate-based anion, and an aliphatic alcohol, and a method of separating carbon dioxide using the same. Since the carbon dioxide absorbent of the present disclosure is thermally and chemically stable, it may decrease by-products released into the atmosphere and thus, is environmentally friendly. The method of separating carbon dioxide using the absorbent is an economical method which allows energy saving with low renewable energy.

Carbon dioxide absorbent including phenolate-based ionic liquid and aliphatic alcohol and method of separating carbon dioxide using the same

Provided are a complex prepared from ammonium salt-containing ligands and having such an equilibrium structural formula that the metal center takes a negative charge of 2 or higher, and a method for preparing polycarbonate via copolymerization of an epoxide compound and carbon dioxide using the complex as a catalyst. When the complex is used as a catalyst for copolymerizing an epoxide compound and carbon dioxide, it shows high activity and high selectivity and provides high-molecular weight polycarbonate, and thus easily applicable to commercial processes. In addition, after forming polycarbonate via carbon dioxide/epoxide copolymerization using the complex as a catalyst, the catalyst may be separately recovered from the copolymer.

Process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst

The present invention relates to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal &#x2212;1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst. According to the present invention, the initial induction time can be reduced when the polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.

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There is provided a method for preparing a low-molecular weight poly(alkylene carbonate) of which the molecular weight and chain shape are precisely controlled, by introducing a phosphorous compound having a hydroxyl group as a chain transfer agent in order to regulate the molecular weight, in alternating copolymerizing an epoxide compound and carbon dioxide by using trivalent metal complex prepared from a Salen type ligand containing a quaternary ammonium salt, and a polymer prepared by the method. Since poly(alkylene carbonate) prepared according to the present invention includes a phosphate or phosphonate group in the polymer chain, it has flame-retarding property.

Flame-retarding carbon dioxide/epoxide copolymer and method for preparing the same

Coordination complexes for producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst

This invention relates to a method of preparing poly(alkylene carbonate) that has a molecular weight and polymer chain structure precisely controlled by adding a chain transfer agent composed of a compound having an alcohol or carboxylic acid functional group upon alternating copolymerization of an epoxide compound and carbon dioxide using a catalyst composed of a trivalent metal complex compound synthesized from a quaternary ammonium salt-containing Salen type ligand, and to a polymer compound prepared thereby. According to this invention, the polymer compound having a star-shaped chain as well as the polymer having a linear chain can be prepared. The low-molecular-weight poly(alkylene carbonate) has an &#x2014;OH terminal group and can be used alone as a coating agent, etc., and also in mixtures with an isocyanate compound and thus can be easily utilized to prepare polyurethane.

Precise control of molecular weight and chain shape control in carbon dioxide/epoxide alternating copolymerization and preparation of low molecular weight poly(alkylene carbonate) thereby

The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal &#x2212;1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst. According to the present invention, the initial induction time can be reduced when the said polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.

Disclosed is a polymer electrolyte composition, a gel-type polymer electrolyte obtained by mixing the same at normal temperature, and a dye-sensitized solar cell containing the electrolyte. Since the poly(alkylene carbonate)-based polymer is included, a crosslinking process by radiation of heat or UV is not required when the polymer electrolyte is manufactured, such that a manufacturing process is simple. Accordingly, the polymer electrolyte is useful for mass production of a solar cell and maintained in a uniform state without a phase separation between two components due to excellent affinity between the polymer and the organic solvent included in the electrolyte, and has excellent electrode-electrolyte interface property in the solar cell due to an adhesive property of the gelled polymer electrolyte.

Polymer electrolyte composition and dye-sensitized solar cell containing the same

Provided is a method for preparing poly(alkylene carbonate) containing ether linkages, by the copolymerization of an epoxy compound and carbon dioxide, with a trivalent metal complex prepared from a salen type ligand containing a quaternary ammonium salt, and a double metal cyanide (DMC) catalyst together. The amount of ether linkages can be controlled by regulating the weight ratio of two catalysts and the carbon dioxide pressure.

Method for preparing carbon dioxide/epoxide copolymers containing ether linkages

Coordination complexes and process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst

Coordination complexes and process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same catalyst

Provided is preparation of poly(alkylene carbonate) by alternating copolymerization of carbon dioxide and epoxide. To be specific, provided are a method for preparing block or graft copolymers of the polymer compound and poly(alkylene carbonate) by alternating-copolymerization of an epoxide compound and carbon dioxide by using a metal (III) compound prepared from salen-type ligand with a quaternary ammonium salt as a catalyst in the presence of a polymer compound having a functional group of hydroxyl or carboxylic acid, and block or graft copolymers prepared by the method.

Block and graft copolymers of poly(alkylene carbonate) and various polymers

Disclosed is a continuous process for manufacturing aliphatic polycarbonate by polymerizing carbon dioxide and one or more epoxide compound in the presence of catalyst, in which carbon dioxide, one or more epoxide compound, and the catalyst are continuously supplied to polymerization reactor to produce aliphatic polycarbonate, separate unreacted carbon dioxide and epoxide compound and recycle them as raw materials.

Continuous process for manufacturing aliphatic polycarbonates from carbon dioxide and epoxides

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Daejeon, South Korea

Jisu Jeong