Sumitomo Chemical Company, Limited

Sumitomo Chemical Companylimited

Jinsho Nambu

Kentaro Mashita

Tadayuki Ohmae

Yoshiki Toyoshima

Noboru Yamaguchi

Nobuhiro Oosaki

Taiichi Sakaya

Takashi Sanada

Taichi Nishio

Toshio Kawakita

Takumi Shibuta

Shoji Ishii

Methods for producing a resin film or a layered article which are excellent in gas barrier properties under high humidity conditions are disclosed. In the methods, a precursor film of a resin composition composed of alkali metal ions and a resin component having both hydroxyl groups and carboxyl groups is subjected to treatments including (i) dry heating treatment of holding the precursor film under an atmosphere characterized by a temperature not lower than 100&#xb0; C. and a water vapor concentration less than 50 g/m, (ii) wet heating treatment of holding the precursor film resulting from the dry heating treatment under an atmosphere characterized by a temperature not lower than 100&#xb0; C. and a water vapor concentration more than 290 g/mor in water at a temperature not lower than 80&#xb0; C., and (iii) drying the precursor film resulting from the wet heating treatment.

Methods for producing resin film and layered article

A method for producing a multilayer article is provided. The method comprises: a step of applying a first dispersion liquid comprising a first liquid medium and a first polymer component, a first alkali metal ion and a first inorganic laminar compound each dispersed in the first liquid medium to a surface of a support having a layer composed of a first thermoplastic resin to form a first dispersion liquid film on the support, wherein the first polymer component contains hydroxyl groups and carboxyl groups at a molar ratio, hydroxyl groups:carboxyl groups, of from 30:70 to 95:5; a step of removing the first liquid medium from the first dispersion liquid film to form a first coating film, thereby producing a layered article comprising the support and the first coating film; a step of heating the layered article at or above a temperature at which a condensation reaction between a hydroxyl group and a carboxyl group in the first coating film can occur, thereby hardening the coating film; and a step of supplying a second thermoplastic resin having been plasticized onto the layer of the first thermoplastic layer of the substrate of the layered article and shaping it into a specified shape, thereby producing a multilayer article having the layered article and a layer of the second thermoplastic resin.

Method for producing multilayer article

There is provided a method for producing a barrier container having a barrier layer which constitutes the inner surface of the container by joining container parts, the method having step (1) of producing container parts from a thermoplastic resin, the container parts each having an inner surface, step (2) of applying a coating liquid containing a liquid medium and a polymer component (A) having hydroxyl groups and carboxyl groups with a ratio of the number of the hydroxyl groups to the number of the carboxyl groups of from 30:70 to 95:5 to the inner surfaces of the container parts produced in step (1), thereby forming a film on the inner surfaces, step (3) of joining the container parts having the film to form a primary container, and step (4) of dry heating the primary container to obtain a dry heated container having a barrier layer.

Method for producing a barrier container

Disclosed is a process for producing a layered article including a substrate and an inorganic particle layer formed thereon, the process including: preparing a mixed inorganic particle dispersion comprising a liquid dispersion medium containing inorganic particles (A) and inorganic particles (B), the mixed inorganic particle dispersion being characterized by conditions (1) regarding particle size, (2) regarding volume fraction of inorganic particles and (3) regarding weight fraction; applying the mixed inorganic particle dispersion to a substrate, and removing the liquid dispersion medium from the mixed inorganic particle dispersion applied to form an inorganic particle layer on the substrate.

Process for producing a layered article

A thermoplastic elastomer composition which is excellent in balance of properties such as mechanical properties and thermal properties and in appearance is prepared by melt-kneading (A) 20-58 parts by weight of a saturated polyester resin and (B) 42-80 parts by weight of an epoxy group-containing ethylene copolymer and then melt-kneading 100 parts by weight of the resulting composition with (C) 0.01-20 parts by weight of a polyfunctional compound containing in one molecule at least two functional groups selected from an amino group, a carboxylic acid anhydride group, a hydroxyl group and a ##STR1## wherein both X and Y are oxygen atoms or sulfur atoms, or either X or Y is an oxygen atom and another is a sulfur atom, or (D) 0.01-9 parts by weight of a polyfunctional compound having in one molecule at least two carboxyl groups or both at least one carboxyl group and at least one functional group selected from an amino group, a carboxylic acid anhydride group, a hydroxyl group and the ##STR2## wherein X and Y are defined above.

Method for producing thermoplastic elastomer composition

A thermoplastic elastomer composition which is excellent in balance of properties such as mechanical properties and thermal properties and in appearance is prepared by melt-kneading (A) 20-58 parts by weight of a saturated polyester resin and (B) 42-80 parts by weight of an epoxy group-containing ethylene copolymer and then melt-kneading 100 parts by weight of the resulting composition with (C) 0.01-20 parts by weight of a polyfunctional compound containing in one molecule at least two functional groups selected from an amino group, a carboxylic acid anhydride group, a hydroxyl group and a ##STR1## group wherein both X and Y are oxygen atoms or sulfur atoms, or either X or Y is an oxygen atom and another is a sulfur atom, or (D) 0.01-9 parts by weight of a polyfunctional compound having in one molecule at least two carboxyl groups or both at least one carboxyl group and at least one functional group selected from an amino group, a carboxylic acid anhydride group, a hydroxyl group and the ##STR2## group wherein X and Y are defined above.

Method for producing thermoplastic elastomer compositions

A polyamide resin composition having a multi-phase structure and a process for producing the same are disclosed, the composition comprising:

Multi-phase structure and process for producing the same

An impact-resistant polyamide resin is produced by

Process for producing impact-resistant polyamide resin compositions

Disclosed is a method for producing a thermoplastic resin composition which can be easily molded into articles having good balance in properties and good appearance. Said method comprises melt-kneading (A) 60-97 parts by weight of a saturated polyester resin and (B) 40-3 parts by weight of an epoxy group-containing ethylene copolymer and then melt-kneading the resulting composition with (C) 0.01-20 parts by weight of a polyfunctional compound containing in one molecule at least two functional groups having reactivity with epoxy group, carboxyl group or hydroxyl group to carry out partial crosslinking reaction.

Method for producing thermoplastic resin compositions

Method for producing thermoplastic resin composition

Disclosed is a method for producing a thermoplastic resin composition which can be easily molded into articles having good balance in properties and good appearance. Said method comprises melt-kneading (A) 60-97 parts by weight of a saturated polyester resin and (b) 40-3 parts by weight of an epoxy group-containing ethylene copolymer and then melt-kneading the resulting composition with (C) 0.01-20 parts by weight of a polyfunctional compound containing in one molecule at least two functional groups having reactivity with epoxy group, carboxyl group or hydroxyl group to carry out partial crosslinking reaction.

A thermoplastic resin composition having a flexural modulas as defined in ASTM D790 of from 500 to 15,000 kg/cm.sup.2, which is obtainable by partial crosslinking upon melt kneading a mixture comprising:

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Chiba, Japan

Jinsho Nambu