Taiwan Semiconductor Manufacturing Comp. Ltd.

Jin Ying

Hun-Jan Tao

Peng-Fu Hsu

Yong-Tian Hou

Fong-Yu Yen

Tze-Liang Lee

Cheng-Lung Hung

Kuo-Tai Huang

Peng-Soon Lim

Vencent Chang

Kang-Cheng Lin

Huan-Just Lin

Liang-Gi Yao

Shiang-Bau Wang

Vincent Chang

A semiconductor structure and methods for forming the same are provided. The semiconductor structure includes a first MOS device of a first conductivity type and a second MOS device of a second conductivity type opposite the first conductivity type. The first MOS device includes a first gate dielectric on a semiconductor substrate; a first metal-containing gate electrode layer over the first gate dielectric; and a silicide layer over the first metal-containing gate electrode layer. The second MOS device includes a second gate dielectric on the semiconductor substrate; a second metal-containing gate electrode layer over the second gate dielectric; and a contact etch stop layer having a portion over the second metal-containing gate electrode layer, wherein a region between the portion of the contact etch stop layer and the second metal-containing gate electrode layer is substantially free from silicon.

CMOS dual metal gate semiconductor device

A semiconductor device is disclosed that includes: a substrate; a first dielectric layer formed over the substrate and formed of a first high-k material, the first high-k material selected from the group consisting of HfO, HfSiO, HfSiON, HfTaO, HfTiO, HfTiTaO, HfAlON, and HfZrO; a second dielectric layer formed over the first dielectric layer and formed of a second high-k material, the second high-k material being different than the first high-k material and selected from the group consisting of HfO, HfSiO, HfSiON, HfTaO, HfTiO, HfTiTaO, HfAlON, and HfZrO; and a metal gate formed over the second dielectric layer. The first dielectric layer includes ions selected from the group consisting of N, O, and Si.

Semiconductor devices and methods with bilayer dielectrics

A method of forming a semiconductor structure includes providing a semiconductor substrate, performing a hydrogen annealing to the semiconductor substrate, forming a base oxide layer after the step of hydrogen annealing, and forming a high-k dielectric layer on the base oxide layer.

Base oxide engineering for high-K gate stacks

A semiconductor structure having a high-k dielectric and its method of manufacture is provided. A method includes forming a first dielectric layer over the substrate, a metal layer over the first dielectric layer, and a second dielectric layer over the metal layer. A method further includes annealing the substrate in an oxidizing ambient until the three layers form a homogenous high-k dielectric layer. Forming the first and second dielectric layers comprises a non-plasma deposition process such atomic layer deposition (ALD), or chemical vapor deposition (CVD). A semiconductor device having a high-k dielectric comprises an amorphous high-k dielectric layer, wherein the amorphous high-k dielectric layer comprises a first oxidized metal and a second oxidized metal. The atomic ratios of all oxidized metals are substantially uniformly within the amorphous high-k dielectric layer.

Multi-metal-oxide high-K gate dielectrics

Hybrid process for forming metal gates

A semiconductor structure includes a substrate, a gate stack on the substrate, a source/drain region adjacent the gate stack, a source/drain silicide region on the source/drain region, a protection layer on the source/drain silicide region, wherein a region over the gate stack is substantially free from the protection layer, and a contact etch stop layer (CESL) having a stress over the protection layer and extending over the gate stack.

MOS devices with continuous contact etch stop layer

A semiconductor device is disclosed that includes: a substrate; a first high-k dielectric layer; a second high-k dielectric layer formed of a different high-k material; and a metal gate. In another form, a method of forming a semiconductor device is disclosed that includes: providing a substrate; forming a first high-k dielectric layer above the substrate; forming a second dielectric layer of a different high-k material above the first dielectric layer; and forming a gate structure above the second dielectric layer. In yet another form, a method of forming a semiconductor device is disclosed that includes: providing a substrate; forming an interfacial layer above the substrate; forming a first high-k dielectric layer above the interfacial layer; performing a nitridation technique; performing an anneal; forming a second high-k dielectric layer of a different high-k material above the first dielectric layer; and forming a metal gate structure above the second dielectric layer.

An n-FET and a p-FET each have elevated source/drain structures. Optionally, the p-FET elevated-SOURCE/DRAIN structure is epitaxially grown from a p-FET recess formed in the substrate. Optionally, the n-FET elevated-SOURCE/DRAIN structure is epitaxially grown from an n-FET recess formed in the substrate. The n-FET and p-FET elevated-source/drain structures are both silicided, even though the structures may have different materials and/or different structure heights. At least a thermal treatment portion of the source/drain structure siliciding is performed simultaneously for the n-FET and p-FET elevated source/drain structures. Also, the p-FET gate electrode, the n-FET gate electrode, or both, may optionally be silicided simultaneously (same metal and/or same thermal treatment step) with the n-FET and p-FET elevated-source/drain structures, respectively; even though the gate electrodes may have different materials, different silicide metal, and/or different electrode heights. The silicides formed on n-FET and p-FET elevated-source/drain structures preferably do not extend below a top surface of the substrate more than about 250 angstroms; and the structure heights may be selected to provide this.

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Singapore, Singapore

Jin Ying