Enevate Corporation

Jill Renee Pestana

Benjamin Yong Park

Frederic C Bonhomme

Xiaohua Liu

Giulia Canton

Michael Buet

Liwen Ji

Ian Russell Browne

Heidi Leighette Anderson

Younes Ansari

Sanjaya D Perera

David J Lee

Sung Won Choi

Monika Chhorng

Fred Bonhomme

Systems and methods are provided for synthesizing solid-state polymer electrolyte and/or using solid-state polymer electrolyte in production of all-solid-state alkali-ion batteries.

Solid-state polymer electrolyte for use in production of all-solid-state alkali-ion batteries

Methods of forming electrochemical cells are described. In some implementations, the method can include providing an electrochemical cell having an electrode with at least about 20% to about 99% by weight of silicon. The method can include providing a formation charge current at a first rate and at a second rate to the electrochemical cell. The first rate can be in a range from about C/100 to about C/10 and the second rate can be greater than about C/10.

Methods of forming electrochemical cells with a combination formation charge rate

Systems and methods for an ultra-high voltage cobalt-free cathode for alkali ion batteries may include an anode, a cathode, and a separator, with the cathode comprising an active material ANiMnSbO, where x is a number between 0.0 and 1.0, y is an integer, and A comprises one or more of lithium, sodium, and potassium. The anode may include one or more of an alkali metal, silicon, and carbon. In one example, x is a value in the range between 0.05 and 0.9 and y is a value in the range between 1 and 8 where a specific capacity of the active material is greater than 50 milliamp-hours per gram. In another example, x is a value in the range between 0.4 and 0.6 and y is a value in the range between 1 and 8, where a specific capacity of the active material is greater than 70 milliamp-hours per gram.

Method and system for an ultra-high voltage cobalt-free cathode for alkali ion batteries

Methods of preparing an electrochemically active material can include providing electrochemically active particles, coating the particles with a binder, and exposing the particles to a source of metal. The methods can also include forming metal salt on the surface of the particles from the source of metal and heating the metal salt to form metal oxide coated particles.

Electrochemically active materials and methods of preparing the same

Silicon particles for use in an electrode in an electrochemical cell are provided. The silicon particles may have outer regions extending about 20 nm deep from the surfaces, the outer regions comprising an amount of aluminum such that a bulk measurement of the aluminum comprises at least about 0.01% by weight of the silicon particles. The bulk measurement of the aluminum may provide the amount of aluminum present at least in the outer regions.

Silicon particles for battery electrodes

Systems and methods for thermal gradient during electrode pyrolysis may include fabricating the battery electrode by pyrolyzing an active material on a metal current collector, wherein the active material comprises silicon particles in a binder material, the binder material being pyrolyzed such that a resistance at an inner surface of the active material in contact with the current collector is at least 50% higher than a resistance at an outer surface of the active material. The active material may be pyrolyzed by electromagnetic radiation, which may be provided by one or more lasers, which may include one or more COlasers. The electromagnetic radiation may be provided by one or more infrared lamps. An outer edge of the current collector may be gripped using a thermal transfer block that removes heat from the current collector during pyrolysis of the active material and subsequent cool down.

Method and system for thermal gradient during electrode pyrolysis

Systems and methods for configuring anisotropic expansion of silicon-dominant anodes using particle size may include a cathode, an electrolyte, and an anode, where the anode may include a current collector and an active material on the current collector. An expansion of the anode during operation may be configured by utilizing a predetermined particle size distribution of silicon particles in the active material. The expansion of the anode may be greater for smaller particle size distributions, which may range from 1 to 10 &#x3bc;m. The expansion of the anode may be smaller for a rougher surface active material, which may be configured by utilizing larger particle size distributions that may range from 5 to 25 &#x3bc;m. The expansion may be configured to be more anisotropic using more rigid materials for the current collector, where a more rigid current collector may comprise nickel and a less rigid current collector may comprise copper.

Configuring anisotropic expansion of silicon-dominant anodes using particle size

Systems and methods for use of silicon with impurities in silicon-dominant anode cells may include a cathode, an electrolyte, and an anode including an active material, where the anode active material includes silicon, and where an impurity level of the silicon may be more than 400 ppm. The impurity level of the silicon is more than 600 ppm. The impurity level may be for elements with an atomic number between 2 and 42. The silicon may have a purity of 99.90% or less. A resistance of the silicon when pressed into a 4 mm thick and 15 mm diameter pellet may be 25 k&#x3a9; or less. The active material may include silicon, carbon, and a pyrolyzed polymer on a metal current collector. The metal current collector may include a copper or nickel foil in electrical contact with the active material. The active material may include more than 50% silicon.

Use of silicon with impurities in silicon-dominant anode cells

Silicon particles for use in an electrode in an electrochemical cell are provided. The silicon particles can have surfaces providing an average contact angle less than about 87.2&#xb0;. The silicon particles can also have outer regions extending about 20 nm deep from the surfaces. The outer regions can include an amount of aluminum such that a bulk measurement of the aluminum comprises at least about 0.01% by weight of the silicon particles.

Systems and methods for thermal gradient during electrode pyrolysis may include fabricating the battery electrode by pyrolyzing an active material on a metal current collector, wherein the active material comprises silicon particles in a binder material, the binder material being pyrolyzed more than 75% at an outer surface and less than 50% at an inner surface in contact with the current collector. The active material may be pyrolyzed by electromagnetic radiation, which may be provided by one or more lasers, which may include one or more COlasers. The electromagnetic radiation may be provided by one or more infrared lamps. An outer edge of the current collector may be gripped using a thermal transfer block that removes heat from the current collector during pyrolysis of the active material and subsequent cool down. Heat transfer plates may be placed on or adjacent to the active material during pyrolysis.

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Long Beach, CA, United States of America

Jill Renee Pestana