Sk on Co., Ltd.

Sk Innovation Co., Ltd.

Jik Soo Kim

Sang Bok Kim

Ji Hoon Choi

Myoung Lae Kim

Mi Jung Noh

Hyo Shin Kwak

Jeong Bae Yoon

Sang Min Park

Kook Hyun Han

Tae Kyoung Lee

Sang Hye Shin

Duck Chul Hwang

Sung Soon Park

Jin Seok Seo

Yu Na Shim

Kwang Ho Lee

Ju Ho Chung

Gwi Ok Park

Se Rah Moon

Seung Ok Lee

Hee Jun Kweon

Dong Il Jang

Dong Wook Ha

Jeong Hoon Jeun

Jae Ho Choi

A cathode active material for a lithium secondary battery according to embodiments of the present invention includes a lithium metal oxide particle which includes a core part and a shell part and contains nickel (Ni), cobalt (Co) and manganese (Mn). A total Ni content of the lithium metal oxide particle is 70 mol % or more based on a total 100 mol % of Ni, Co and Mn. The shell part includes a depth region in a range of 10 to 100 nm from a surface of the lithium metal oxide particle, and a Co content thereof in the depth region is 1.4 to 6 times a Co content of the core part. Stability of the lithium secondary battery may be improved through surface treatment using high content of Co.

Positive electrode active material for lithium secondary battery, method for manufacturing same, and lithium secondary battery including same

A cathode active material for a lithium secondary battery includes a lithium metal oxide particle, and an organic poly-phosphate or an organic poly-phosphonate formed on at least portion of a surface of the lithium metal oxide particle. Chemical stability of the lithium metal oxide particle may be improved and surface residues may be reduced by the organic poly-phosphate or the organic poly-phosphonate.

Cathode active material for lithium secondary battery and method of manufacturing the same

A cathode active material for a lithium secondary battery is provided. The cathode active material includes lithium-transition metal composite oxide particles having a crystallite size of 120 nm or less in a () plane direction measured through X-ray diffraction (XRD) analysis, and a ratio of the crystallite size of the lithium-transition metal composite oxide particle in the () plane direction to a crystallite size thereof in a () plane direction isor more.

A cathode active material for a lithium secondary battery according to embodiments of the present invention has a high-nickel composition and includes a lithium-nickel composite metal oxide particle in which lithium, nickel and a metal having an oxidation number of +2 are combined in a predetermined range. A cation disorder caused when a nickel ion is present at a lithium-ion site is reduced to improve structural stability of the cathode active material. An initial capacity and a battery efficiency of a lithium secondary battery can be improved using the cathode active material.

Cathode active material for lithium secondary battery and lithium secondary battery including the same

A cathode active material for a lithium secondary battery of embodiments of the present invention includes a lithium composite oxide, a first coating part formed on a surface of the lithium composite oxide and containing aluminum, and a second coating part formed on the first coating part and containing boron. Thereby, stability and electrical characteristics of the secondary battery may be improved.

Cathode active material for lithium secondary battery, lithium secondary battery and method of manufacturing the same

The present invention provides a cathode active material for a secondary battery, which includes a lithium metal oxide particle having a form of a secondary particle in which a plurality of primary particles are agglomerated, wherein the primary particles comprise a particle having a triangular shape which has a size of a minimum internal angle of 45° or more and a maximum height of 0.5 μm or more.

The cathode active material for a lithium secondary battery according to embodiments of the present invention includes a lithium-transition metal composite oxide particle including a plurality of primary particles, and the lithium-transition metal composite oxide particle includes a lithium-sulfur-containing portion formed between the primary particles. Thereby, it is possible to improve life-span properties and capacity properties by preventing the layer structure deformation of the primary particles and removing residual lithium.

A cathode active material precursor according to embodiments of the present invention includes a composite hydroxide particle in which primary precursor particles are aggregated. The primary precursor particles include a particle having a triangular shape in which a minimum interior angle is 30° or more and a ratio of a length of a short side relative to a length of a long side is 0.5 or more. A cathode active material and a lithium secondary having improved high temperature stability is provided using the cathode active material precursor.

Cathode active material precursor, cathode active material, lithium secondary battery and method of manufacturing the same

The cathode active material according to embodiments of the present invention includes a lithium composite oxide particle having a form of secondary particle in which a plurality of primary particle are aggregated, wherein the primary particles respectively include a lithium conduction pathway through which lithium ions are diffused. Wherein the primary particles include a first particle, and the first particle has an angle of 45° to 90° formed by a direction from a center of the first particle to a center of the lithium composite oxide particle and a direction of the lithium conduction pathway included in the first particle, wherein a ratio of the number of the first particles among the primary particles located on a surface of the lithium composite oxide particle is 20% or more.

Cathode active material and lithium secondary battery including the same

The cathode active material for a lithium secondary battery according to embodiments of the present invention includes lithium-transition metal composite oxide particles including a plurality of primary particles, and the lithium-transition metal composite oxide particles have a lithium-potassium-containing portion formed between the primary particles. Thereby, it is possible to improve life-span properties and capacity properties by preventing the layer structure deformation of the primary particles and removing residual lithium.

A cathode active material for a lithium secondary battery includes a lithium-aluminum-titanium oxide formed on a surface of a lithium metal oxide particle having a specific formula. The cathode active material may have an improved structural stability even in a high temperature condition.

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Daejeon, South Korea

Jik Soo Kim