Arkema France

Trinseo Europe Gmbh

Other

Arkema Inc.

Jiaxin Jason Ge

Michael Timothy Burchill

Florence Mehlmann

Gary A Hall

Mark A Aubart

Gregory Scott O'Brien

Robert A Wanat

Estelle Meurice Pierrat

Scott R Gaboury

Saeid Zerafati

Amy A Lefebvre

Rong Maria Hu

Ravi R Gupta

Brian M Cromer

Steven W Gaskey

Noah E Macy

Michael T Burchill

Gregory S O'BRIEN

The invention relates to acrylic copolymers and terpolymers incorporating high Tg, hydrophobic (meth)acrylates that have high thermal stability and excellent optical properties. These copolymers are optically clear, and provide a copolymer having a Tg of 115-140 C, along with sufficiently high molecular weight. The copolymer is found to exhibit high heat resistance, high light transmission, low haze, low moisture uptake, excellent environmental stability, excellent high temperature thermal stability, and excellent mechanical properties, along with excellent UV resistance. The copolymer, or terpolymer may be used to form lighting pipes, thin wall parts, optical lenses, extruded films, (co-)extruded sheets/profiles, thermo-formable sheets, cast sheets, composites, etc.

Hydrophobic high heat optical acrylic copolymers

Acid-functionalized copolymers of methyl methacrylate having relatively high glass transition temperatures and molecular weights may be employed to manufacture articles having high light transmission values, low haze, high heat resistance, and high environmental stability, which are useful as optical protection films, zero-zero optical retardation films, and compensation films as well as lighting pipes and optical imaging lenses.

Acid-functionalized copolymers of methyl methacrylate and acrylic resin compositions based thereon

A high Tg acrylic copolymer includes methyl methacrylate with one or more high Tg hydrophobic monomers. The copolymer includes: a) at least one of tert-butyl cyclohexyl methacrylate, 3,3,5-trimethylcyclohexyl(meth)acrylate, tetrahydrofurfuryl methacrylate, or a mixture thereof; and b) (meth)acrylate monomer. The copolymer has the following properties: i) Tg of from 116° C. to 140° C.; ii) Mw of at least 110,000; and iii) a residual monomer level of less than 1.0 weight percent. The copolymer exhibits high heat resistance, high light transmission, low haze, low moisture uptake, excellent environmental stability, excellent high temperature thermal stability, and excellent mechanical properties, along with excellent UV resistance. The high molecular weight hydrophobic copolymer of the invention has the excellent environmental stability required for electronic components in automotive, displays, smartphones, photovoltaics, and others.

Heat resistant PMMA copolymers having high temperature and high humidity environmental stability for electronic component applications

Films having high light transmission values, low haze and high glass transition temperatures and useful, for example, as optical protection films and zero-zero optical retardation films, are prepared using one or more copolymers of methyl methacrylate having certain characteristics.

Transparent films based on resin components having a high glass transition temperature

The invention relates to high efficiency diffusion lighting coverings useful in LED lighting applications. The diffusing lighting coverings are made of organic diffusing particles homogeneously dispersed in a transparent polymer matrix. The primary organic diffusing particles are refractive index mis-matched to the matrix polymer. The refractive index contrast between the polymer matrix and diffusion particles, and particle size are selected to provide a high efficiency (minimized particle loading). The high efficiency diffusion coverings provides excellent light diffusion, high hiding properties and high light transmission. The secondary diffusion particles may optionally be added to further improve selected target properties of the covering. Nano-sized ZnO inorganic particles may also function as diffusion particles and optical brighteners as well UV stabilizers. Articles made of this translucent composition are useful in commercial and residential lighting, motor vehicle illumination (lights, panels), street lighting, displays and signs, desktop monitors, and LCD/LED TVs.

High efficiency diffusion lighting coverings

The invention relates to a thin, nano-structured coating that provides optical light efficiency enhancement. The dried coating contains nano-structures that provide a very low haze level of less than 2 percent, and a light transmission improvement of at least 1% over the non-coated substrate. For the nano-structured coating on an acrylic substrate the transmission is greater than 93 percent, and preferably greater than 94 percent. The coatings of the invention are especially useful for optical electronic displays and photovoltaic modules.

Nano-structure coated sheets/films for optical electronic displays and photovoltaic modules

The invention relates to an acrylic layer (in the form of a coating, film or sheet) useful as part of a photovoltaic module backsheet. The acrylic layer contains at least 40 percent of one or more acrylic polymers, including an acrylic polymer matrix and optionally acrylic impact modifiers. The acrylic polymer is preferably a polymer, copolymer, or terpolymer containing at least 50 weight percent of methylmethacrylate monomer units. The acrylic layer is flexible and optionally contains high levels of white pigment. It may also contain fluoropolymers such as polyvinylidene fluoride to improve weathering, processibility and film formation. The acrylic layer adheres to a polymer support layer such as polyethylene terephthalate (PET). A preferred substrate is PET that is pre-treated to improve adhesion, but unprimed PET can also be used. The backsheet provides excellent weatherability, environmental stability and reflectivity as part of a photovoltaic module.

Acrylic photovoltaic module backsheet

Films useful as optical reflectors are prepared by coating a sheet of polyethylene terephthalate or other thermoplastic with acrylic polymer, white pigment, and optionally other additives such as impact modifiers, matting agents and UV stabilizers.

Optical reflection films

The invention relates to optical light diffusers for use with point light sources, such as LED lighting. The optical diffusers achieve an optimum balance of light transmission and hiding power. The optical light diffuser is a transparent plastic matrix, such as Plexiglas&#xae; resin from Arkema Inc., having organic particles dispersed within the matrix. The particles are crosslinked beads having specific particle sizes and loading. Different beads can be combined to provide added properties such as a textured surface, and to optimize hiding power and light transmission. The invention also relates to a luminous device containing at least one light-emitting diode and a cover made of the optical light diffuser. The invention further relates to a method for assessing hiding power.

Optical light diffuser and method for measurement thereof

The invention relates to blend materials useful in LED lighting applications. The diffusing particle blend is a synergistic mixture of selected organic particles and selected inorganic particles of specific composition, loading, and a refractive index difference with the matrix polymer, that provide excellent light diffusion, high hiding properties and good light transmission. Articles made of this blend are useful in commercial and residential lighting, motor vehicle illumination (lights, panels), street lighting, displays and signs.

Optical diffusion blend materials for LED lighting

The invention relates to a photovoltaic module for capturing and using solar radiation having as a backsheet a composition containing polyvinylidene fluoride. The polyvinylidene fluoride backsheet layer is exposed to the environment and provides chemical resistance, low water vapor transmission, electrical insulation, and UV light protection.

Photovoltaic modules having a polyvinylidene fluoride backsheet

The invention relates to an acrylic sheet having a high Tg, and especially for the use of the high Tg acrylic sheet as a front sheet of a photovoltaic module. The high Tg acrylic polymer is a copolymer of polymethylmethacrylate and one or more higher Tg monomers.

High temperature acrylic sheet

The invention relates to flexible photovoltaic (PV) modules, and in particular to those having a polyvinylidene fluoride (PVDF) glazing layer. The PVDF layer may be a monolayer or a multi-layer structure.

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Lower Providence, PA, United States of America

Jiaxin Jason Ge