Sobute New Materials Co., Ltd

Bote New Materials Taizhou Co., Ltd.

Nanjing Bote New Materials Co., Ltd.

Bote Building Materials (Tianjin) Co., Ltd

Southeast University

Bote New Materials Taizhou Jiangyan Co., Ltd

Jiangsu Sobute New Materials Co., Ltd.

Sobute Materials Co., Ltd

Panzhihua Bote Building Materials Co., Ltd.

Zhenjiang Sobote New Materials Co., Ltd.

Zhenjiang Sobute New Material Co., Ltd.

Sobute New Materials Co., Ltd.

Jiangsu Research Institute of Building Science Co. Ltd

Jiangsu Bote New Materials Co. Ltd.

Jiaping Liu

Qianping Ran

Yong Yang

Tao Wang

Xin Shu

Jianfeng Ma

Shimin Fan

Shuai Qi

Yujiang Wang

Dongliang Zhou

Jinzhi Liu

Shentong Li

Han Yan

Qian Tian

Jinxiang Hong

Hang Zhang

Jianye Zhang

Zhen Huang

Bing Wang

Rui Wang

Lei Li

Hua Li

Yanwei Wang

Yong Zhang

Fei Guo

Hongxia Zhao

Jiangang Zhang

Xiumei Wang

Jianzhong Liu

Song Mu

Cheng Yu

Wenbin Wang

Ting Yao

Changwen Miao

Yang Chu

Zhisong Xu

Min Qiao

Shijun Yuan

Ming Jin

Yonglin Mao

Qi Ma

Zheng Han

Jingshun Cai

Pengcheng Wu

Shouzhi Zhang

Xiaocheng Zhou

Provided are a polyhydroxy aromatic intermediate, preparation thereof and use thereof in a polycondensate water-reducer with branched side chains. The polycondensate water-reducer with branched side chains has a branched side chain structure which provides a stronger steric hindrance. The synergistic effect of the branched side chains and the rigid skeleton of the aromatic ring greatly improves the water-reducing ability. Especially under a condition of low water/cement ratio, the improvement in water-reducing ability is more obvious. The branched polyether side chain is more conducive to the formation of a thicker water film layer, which has an obvious viscosity reduction effect. The conformation of the branched polyether side chain is less affected by different ionic environments in the pore solution in cement, and thus has a stronger adaptability to various raw materials. The water-reducer is suitable for the preparation of high-strength concrete, self-compacting concrete and concrete with low water-to-binder ratio and high volume of mineral admixtures, especially for the preparation of concrete containing machine-made sand.

Polyhydroxy aromatic intermediate, preparation thereof and use thereof in polycondensate water-reducer with branched side chains

The present disclosure discloses an organic silicon nano-precursor medium transmission inhibitor and its preparation method and use. The organic silicon nano-precursor medium transmission inhibitor is composed of an organic silicon and its derivatives, a catalyst, a dispersant, a stabilizer, a surfactant, and water. The organic silicon nano-precursor medium transmission inhibitor in-situ generates nanoparticles during a hydration process. The nanoparticles not only have a hydrophobic function, but also can effectively fill the pores of the concrete, which effectively solves a problem in which a hydrophobic material in a state of full water cannot reduce the diffusion of an erosive medium. The problems such as uneven dispersion and poor stability of nanoparticles added can be effectively solved by in-situ generating the nanoparticles, thereby effectively improving the ion corrosion resistance performance of the concrete.

Organic silicon nano-precursor medium transmission inhibitor, its preparation method and use

A testing device for a characteristic of resistance between fresh concrete and a boundary, and a testing method includes a counter-force frame, a driving mechanism, an outer cylinder, a rotor, and pressurization mechanisms, where a bottom of an inner side of the counter-force frame is provided with the driving mechanism, an output shaft of the driving mechanism is connected to the rotor, the rotor is placed in the outer cylinder, space between the rotor and the outer cylinder is filled with a concrete specimen, a plurality of pressurization mechanisms are symmetrically arranged at a top of the concrete specimen, tail ends of the pressurization mechanisms are mounted on the counter-force frame, and the pressurization mechanisms, the rotor and the driving mechanism are connected to a data receiver.

Testing device for characteristic of resistance between fresh concrete and boundary, and testing method

The present invention discloses a polycarboxylic acid water-reducing agent with high adaptability to temperature and a method for preparing the same. The polycarboxylic acid water-reducing agent is prepared by introducing an unsaturated macromonomer D with a temperature-sensitive side chain which could be bonded to the backbone of the polycarboxylic acid through free radical polymerization. The polycarboxylic acid water-reducing agent prepared by the invention has an adsorption group density that can be automatically adjusted with the change of ambient temperature, and thereby shows similar dispersing capability and dispersion retention capability at different ambient temperatures, demonstrating high adaptability to different ambient temperatures. It can be used in a larger temperature range with a constant dosage, which is beneficial to further popularization and application of the polycarboxylic acid water-reducing agent in regions of different climates.

Polycarboxylic acid water-reducing agent with high adaptability to temperature and method for preparing the same

Disclosed are a highly adaptable viscosity-reducing polycarboxylate water reducer and its preparation method and application. The highly adaptable viscosity-reducing polycarboxylate water reducer is composed of a polymer and water, and the polymer accounts for 30-50 wt %; since the main chain of the polymer contains a hydrophobic benzene ring and hydrophilic amine, the polymer has strong rigidity and good solubility in an aqueous solution, and is rich in two adsorption groups of carboxyl group/phosphono group. The highly adaptable viscosity-reducing polycarboxylate water reducer of the present invention has excellent water-reducing and slump retention properties and is suitable for general construction projects and commercial concrete projects. Compared with the conventional polycarboxylate water reducer, the highly adaptable viscosity-reducing polycarboxylate water reducer of the present invention has strong adaptability to concrete materials and can effectively reduce the viscosity of high-strength concrete (C50-C100), thus having bright application prospects in the high-end water reducer market.

High-adaptability viscosity-reducing polycarboxylic acid water reducer, preparation method therefor and use thereof

Disclosed are a multifunctional cement hydration heat control material and a manufacturing method therefor. The cement hydration heat control material in is a comb polymer having three side chain structures, the three side chain structures are respectively a carboxyl group, a sugar alcohol group, and a polyether structure, and the main chain of the polymer is a carbon chain structure formed by free-radical polymerization of a double bond in a double bond compound monomer. The multifunctional cement hydration heat control material can achieve integration of cement hydration heat control performance, water reduction performance, and shrinkage reduction performance in a same molecule, can achieve control focusing on a performance by means of structural adjustment, does not need multi-component compounding during use, and is more convenient. The control material is non-toxic and water-soluble, can be made to have an appropriate concentration, and is convenient to use.

Multifunctional cement hydration heat control material and manufacturing method therefor

The present invention discloses a multitype-adsorptive-group polycarboxylic acid water-reducing agent, consisting of 30-60 wt % of a macromolecule with multitype-adsorptive groups and water, the macromolecule with multitype-adsorptive groups has a polyethylene glycol side chain, and adsorption groups of the polymer backbone include a carboxylic acid group, a sulfonic acid group and a phosphoric acid group, the phosphoric acid group being linked to the backbone of the macromolecule with multitype-adsorptive groups by nucleophilic addition. The water-reducing agent of the present invention has significantly improved adaptability to different cements and aggregates while maintaining a high water reduction efficiency, compared with the conventional polycarboxylic acid water-reducing agent agent. It has a good water reducing efficiency in many different grades of cement, as well as a better resistance to aggregates containing more impurities such as machine-made sand.

Multitype-adsorptive-group polycarboxylic acid water-reducing agent, method for preparing the same and use thereof

Disclosed are a method for separately preparing light magnesium oxide and calcium oxide by using dolomite and an application thereof in preparation of a calcium-magnesium composite expanding agent. In the method for preparing light magnesium oxide and calcium oxide, based on the difference in decomposition temperature between magnesium carbonate and calcium carbonate during the calcination and decomposition of dolomite and the difference in the weight of the materials after decomposition, the effective separation of magnesium oxide and calcium oxide is realized by a one-step method, thus separately preparing light magnesium oxide and light calcium oxide. The calcium-magnesium composite expanding agent is prepared by using the foregoing light magnesium oxide and calcium oxide. On the one hand, the present invention solves the problem of the limited origin of the light magnesium oxide raw material of the magnesium expanding component in the calcium-magnesium composite expanding agent.

Method for preparing light magnesium oxide and calcium oxide and application thereof for preparing calcium-magnesium composite expanding agent

Embodiments of the invention relate to concrete admixtures, provide a phosphonato block polymer, a preparation method and an application. The method includes: the phosphonato block polymer prepared by copolycondensating an ether-type segment A, a phosphonato segment B, and a third part of aldehyde C. The ether-type segment A is obtained by polycondensating a polyether monomer and a first part of aldehyde C. The phosphonato segment B is obtained by polycondensating a monomer b containing phosphonato, a monomer c, and a second part of aldehyde C in an aprotic weak polar solvent E. By preparing a block polymer using arylalkane as a main chain and using a phosphonic acid or phosphinic acid functional group as an adsorption group, the invention improves the resistance of the block polymer to sulfate and clay interference, and can achieve initial high dispersion of concrete with a low water-cement ratio and decreasing of the system viscosity.

Phosphonato block polymer, preparation method therefor and application thereof

The present invention discloses a phosphorylated polycondensate high-performance water-reducing agent with a phosphorylated melamine derivative, instead of a conventional carboxyl group or sulfonic group, as a main adsorption group. The use of aryl alkoxypolyether as a side chain of the polymer provides a strong steric effect to improve the dispersibility and dispersion-retaining properties of the polymer. A polycondensate high-performance water-reducing agent and a method for preparing the same provided by the present invention have excellent overall performance, high adaptability for current low-grade raw materials of concrete, strong market demands, and vast application prospects. Additionally, the polycondensate has an advanced preparation process provided with the characteristics of industrially scalable production, which offers the prospect of a core technology in the field of water-reducing agent of concrete so as to promote development of the industry.

Phosphorylated polycondensate as high efficiency water reducing agent and preparation method thereof

The present invention discloses a method for preparing a concrete superplasticizer having a phosphorous acid group and a use of the concrete superplasticizer. The concrete superplasticizer having a phosphorous acid group according to the present invention is prepared by free radical copolymerization of a phosphorous-containing monomer A and a polyether macromonomer B. The concrete superplasticizer having a phosphorous acid group obtained in the present invention can effectively improve flowability of concrete and can retain good workability of concrete. The method is simple, economical and effective, and in particular, can be used for commercial mass production.

Method for preparing concrete superplasticizer having phosphorous acid group and use thereof

The present invention provides a method for preparing a polymer and a use of the polymer. The resulting polymer is used as a dispersant for an aqueous dispersion of a hydraulic binder and/or a latent hydraulic binder, such that water-reducing rate is improved, and suitable control of air content can be achieved, thereby improving the strength of concrete. The method for preparing a polymer includes polycondensation of a polyether macromonomer A of a specific structure, a monomer B and an aldehyde C to obtain the polymer. The monomer B is phenylsulfonic acid, p-/o-aminophenylsulfonic acid, p-/o-hydroxylbenzoic acid, p-/o-aminobenzoic acid, p-/o-hydroxylphenylsulfonic acid, or a phosphoric acid group or phosphorous acid group-containing monomer of a specific structure. A molar ratio of the polyether macromonomer A and the monomer B is 1:(0.5 to 12).

Preparation method for polymer and applications thereof

Disclosed is a method for testing the self-drying effect of a cement-based material, capable of testing the change in humidity of the cement-based material after the final setting until the Id stage of adding water, so as to reflect the water consumption therein and the self-drying course. In the time period after the final setting of the cement-based material until the 1 d stage of adding water and forming, the dew-point temperature inside the cement-based material is tested, and then the relative humidity inside the cement-based material is calculated using a formula. The present invention can test the change in humidity of the cement-based material after the final setting until the Id stage of adding water, so as to reflect the internal water consumption therein and the self-drying course. Further provided is a multi-stage test method for the whole course, capable of testing the whole course of continuous reduction in relative humidity from an initial 100%, in sealed conditions, starting with adding water and formation of the cement-based material, so as to provide a theoretical foundation for the quantitative calculation of the self-drying and shrinking thereof.

Method for testing self drying effect of cement-based material

Disclosed is a method for testing the setting time of a cement-based material: testing the capillary negative pressure of a non-bleeding cement-based material, with the time at which the capillary negative pressure reaches a threshold value A as the initial setting time, and/or the time at which the capillary negative pressure reaches a threshold value B as the final setting time, wherein threshold value A is 8-10 kPa, and threshold value B is 54-56 kPa. Alternatively, threshold value A and threshold value B are determined by the following method: formulating a cement-based material for the determination of threshold values with the same raw materials at the same formulation ratio; after vibration-compaction, placing a portion into a measuring mold; after vibration-compaction, testing the capillary negative pressure of the non-bleeding cement-based material placed in the measuring mold; under the same conditions, synchronously testing and determining the initial setting time and final setting time of the cement-based material for the determination of threshold values by a penetration resistance method; the capillary negative pressure corresponding to the initial setting time and final setting time of the cement-based material for the determination of threshold values are respectively threshold value A and threshold value B. The method can not only be used in standard tests for a laboratory cement setting time under standard temperature conditions, but can also be used to realize remote, automatic, and continuous in situ monitoring for the setting time of a cast-in-situ concrete structure.

Method for testing setting time of cement-based material

A slump retaining polycarboxylic acid superplasticizer. A weight average molecular weight of the superplasticizer is 20,000-80,000. The slump retaining polycarboxylic acid superplasticizer is prepared by performing polymerization reaction on a monomer A, a monomer B, a monomer C and a monomer D in an aqueous solution in the presence of a redox initiator, wherein a molar ratio of (the monomer A+the monomer B):the monomer C:the monomer D is 1:(3-8):(4-12), and a molar ratio of the monomer A to the monomer B is 1:(1-4).

Slump retaining polycarboxylic acid superplasticizer

Growing community of inventors

Nanjing, China

Jiaping Liu