Contemporary Amperex Technology Co., Ltd.

Contemporary Amperex Technology (hong Kong) Limited

Jianwei Zhu

Changlong Han

Xiaomei Wang

Jiqiong Liu

Yan Zhou

Feng Huan

Chenghua Fu

Kun Yu

Bin Jiang

Xiaochong Zhou

Wenhao Liu

Feng Xu

This application relates to the field of batteries, and in particular, to an electrolytic solution and a lithium-ion battery, a battery module, a battery pack and an apparatus that adopt the electrolytic solution. This application provides an electrolytic solution, including an electrolyte and a solvent, and further including an additive A and an additive B. The additive A is selected from at least one of compounds whose chemical structural formula is denoted by Formula I, and the additive B is selected from at least one of compounds whose chemical structural formula is denoted by Formula II. By using the additive A and the additive B together, this application enables films to be formed on surfaces of a positive electrode plate and a negative electrode plate concurrently, thereby significantly improving cycle performance and high-temperature storage performance of the lithium-ion battery, and also ensuring excellent kinetic performance of the lithium-ion battery.

Electrolytic solution, lithium-ion battery, battery module, battery pack and apparatus

The present disclosure relates to the technical field of lithium-ion battery, and particularly, to an electrolytic solution and a lithium-ion battery including the electrolytic solution. The electrolytic solution includes additives, and the additives include an additive A and an additive B. The additive A forms a film on the surface of the positive electrode and effectively prevents interface side reactions at the positive electrode. Comparing with the additive A, the additive B is preferentially reduced to form a film at the negative electrode, avoiding an increase in impedance and deterioration of cycling dynamic performance, etc., caused by film formation of the additive A on the negative electrode. The combination of the additive A and additive B imparts the battery with a reduced gas production, a higher capacity retention rate and a lower impedance at high temperature.

Electrolytic solution and lithium-ion battery

The present invention discloses a Lithium ion battery and an electrolyte thereof, the electrolyte comprising an organic solvent, a lithium salt and an additive. The additive comprises a cyclic fluoro carbonate (A), a cyclic phosphazene (B), a cyclic sulfate and a lithium fluoro oxalate borate (D). The lithium fluoro oxalate borate (D) has following formula:  Compared with the prior art, the electrolyte of the present invention may form a stable CEI and SEI film on the surface of positive and negative electrodes, protect the interface between positive and negative electrodes, improve the acidic atmosphere of Lithium ion battery electrolyte, and reduce the damage effect of HF on the interface between positive and negative electrodes, while reducing low temperature resistance of lithium-ion battery, improving cycle life, high temperature storage performance, safety performance and rate capability of lithium-ion battery.

Lithium-ion battery and its electrolyte

The present invention discloses a Lithium ion battery and an electrolyte thereof, the electrolyte comprising an organic solvent, a lithium salt and an additive. The additive comprises additive (A) cyclic fluoro carbonate, additive (B) cyclic phosphazene (B), and additive (C) cyclic sulfate. The additive B cyclic phosphazene has the following general structural formula:  Compared with the prior art, the electrolyte of the present invention may form a stable CEI and SEI film on the surface of positive and negative electrodes, protect the interface between positive and negative electrodes, improve the acidic atmosphere of Lithium ion battery electrolyte, and reduce the damage effect of HF on the interface between positive and negative electrodes, thereby improving cycle life, high temperature storage performance, and safety performance of lithium-ion battery.

The present disclosure provides an electrolyte and a lithium-ion battery. The electrolyte comprises: an organic solvent; a lithium salt dissolved in the organic solvent; and an additive. The additive comprises trifluoromethanesulfonate silyl compound, lithium fluorophosphate compound and cyclic phosphonitrile compound. The electrolyte of the present disclosure can significantly decrease the low temperature resistance of the lithium-ion battery, and improve the power performance of the lithium-ion battery, and the electrolyte of present disclosure can also significantly inhibit the gas generation during the cycle process and the storage process of the lithium-ion battery, and significantly improve the cycle performance, the high temperature storage performance and the safety performance of the lithium-ion battery.

Electrolyte and lithium-ion battery

The present disclosure provides an electrolyte and an electrochemical energy storage device. The electrolyte comprises an electrolyte salt and an additive. The additive comprises a sulfonic ester cyclic quaternary ammonium salt and a fluorocarbon surfactant. Under the combined effect of the sulfonic ester cyclic quaternary ammonium salt and the fluorocarbon surfactant, a dense, uniform and stable passive film can form on a surface of each of a positive electrode film and a negative electrode film of the electrochemical energy storage device, and infiltration capability of the electrolyte on each of the passive film of the positive electrode film and the negative electrode film can be increased at the same time, so as to decrease electrode polarization inside the electrochemical energy storage device and make the electrochemical energy storage device have excellent rate capability, low temperature discharge performance and high temperature storage performance.

Growing community of inventors

Ningde, China

Jianwei Zhu