China Shenhua Energy Company Limited

Jianguo Han

Zhaohua Guo

Cundi Wei

Yixin Zhao

Junzhou Chi

Wenhui Zhang

Dazhao Gu

Jianmin Zhang

Hong Dong

Yanbin Sun

Sa Lv

Chunbin Guo

Qingan Nan

Ping Zou

Deli Yu

Peiping Zhang

Yinshan Jiang

Yongwang Wang

Shaonan Xu

Disclosed is a method for extracting gallium from fly ash, which comprises the following steps: crushing the fly ash and removing Fe by magnetic separation; then dissolving it by using hydrochloric acid to obtain hydrochloric acid leachate; adsorbing gallium contained in the hydrochloric acid leachate with macro-porous cationic resin, followed by eluting to obtain an eluent containing gallium; adding masking agent to mask ferric ion to obtain an eluent containing gallium after masking; adsorbing gallium in the eluent containing gallium after masking with macro-porous cationic resin, followed by eluting to obtain a secondary eluent; adding sodium hydroxide solution into the secondary eluent to react; filtering and removing precipitates after reaction, and then concentrating the filtrate and electrolyzing to obtain metal gallium. The method simplifies the process and improves extraction efficiency of gallium.

Method for extracting gallium from fly ash

Provided a method for preparing metallurgical-grade alumina by using fluidized-bed fly ash, comprising: a) removing iron by wet magnetic separation after crushing the fly ash; b) reacting the fly ash after magnetic separation with hydrochloric acid to obtain a hydrochloric leachate; c) passing the hydrochloric leachate through macro-porous cationic resin to deeply remove iron to obtain a refined aluminum chloride solution; d) concentrating and crystallizing the refined aluminum chloride solution to obtain an aluminum chloride crystal; and e) calcining the aluminum chloride crystal to obtain the metallurgical-grade alumina. The method is simple, the procedure is easy to be controlled, the extraction efficiency of alumina is high, the production coast is low, and the product quality is steady.

Method for preparing metallurgical-grade alumina by using fluidized bed fly ash

A vertical ring magnetic separator for de-ironing of coal ash comprises a rotating ring (), an inductive medium (), an upper iron yoke (), a lower iron yoke (), a magnetic exciting coil (), a feeding opening (), a tailing bucket () and a water washing device (). The feeding opening () is used for feeding the coal ash to be de-ironed, and the tailing bucket () is used for discharging the non-magnetic particles after de-ironing. The upper iron yoke () and the lower iron yoke () are respectively arranged at the inner and outer sides of the lower portion of the rotating ring (). The water washing device () is arranged above the rotating ring (). The inductive medium () is arranged in the rotating ring (). The magnetic exciting coil () is arranged at the periphery of the upper iron yoke () and the lower iron yoke () so as to make the upper iron yoke () and the lower iron yoke () to be a pair of magnetic poles for generating a magnetic field in the vertical direction, wherein the inductive medium () is layers of steel plate meshes, each steel plate mesh is woven by wires, and ridge-shape sharp corners are formed at the edges of the wires. A method for magnetically separating and de-ironing of coal ash, utilizes the vertical ring magnetic separator for de-ironing of coal ash. By adopting the vertical ring magnetic separator and the method of magnetic separation for de-ironing, the de-ironing efficiency is improved by at least 20%.

Vertical ring magnetic separator for de-ironing of pulverized coal ash and method using the same

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Beijing, China

Jianguo Han