Guangdong Institute of Eco-environmental Science & Technology

Jianghu Cui

Fangbai Li

Chuanping Liu

Chengshuai Liu

Xianghua Xu

A ferrous modified selenium sol for inhibiting accumulation of cadmium and arsenic in rice and the preparation method and application thereof are disclosed. The method includes: dissolving an iron-containing compound and a selenium-containing compound into water; adding a reductant to the solution, and stirring until no more precipitation is generated, then adding carbonate, continuing to stir until no more precipitation is generated, and then filtering, taking the precipitation, and washing to obtain the precipitation of the selenium element and ferrous carbonate; adding an emulsifier to a citric acid buffer solution to obtain an emulsified citric acid buffer solution; adding the precipitation of the selenium element and ferrous carbonate to the emulsified citric acid buffer solution to obtain a sol system; and evaporating to concentrate the sol system, and adjusting the pH to 4.5-8.5 to obtain a ferrous modified selenium sol for inhibiting the accumulation of cadmium and arsenic in rice.

Ferrous modified selenium sol for inhibiting accumulation of cadmium and arsenic in rice and preparation method and application thereof

The present invention relates to the field of environmental protection, and in particular to a leaf surface barrier for accurately controlling cadmium absorption and transport related gene expression in rice, and an application thereof. The present invention comprises: reducing a raw material, i.e., selenious acid or selenite, by using ascorbic acid to generate a nanogel, and then emulsifying the nanogel for peptization to obtain a leaf surface barrier for accurately controlling cadmium absorption and transport related gene expression in rice; and then mixing the leaf surface barrier with a silica sol to obtain a composite selenium and silica sol leaf surface barrier. The present invention also provides a leaf surface barricading method for accurately controlling cadmium absorption and transport related gene expression in rice. By applying the leaf surface barrier, the silica sol or the composite selenium and silica sol leaf surface barrier having a particular atomization degree and a particular concentration by means of foliar spray during a particular growth period of rice and within a particular time, the cadmium accumulation in rice can be effectively reduced. Applying the present invention to a moderately or lightly polluted field can enable cadmium content in rice to satisfy the food hygiene standards, and therefore is significant for achieving the safe use of the large area of field polluted by heavy metal cadmium in China.

Foliage blocking agent for precise regulation of expression of cadmium absorption and transportation-related gene in rice and application thereof

A method for preparing the iron-based biochar material, the iron-based biochar material prepared there from and a method for controlling the heavy metal pollution in soil using the iron-based biochar material. For the iron-based biochar material of the present invention, by using a method of high-temperature carbonization, a biomass is used as a raw material and an iron-containing compound is add in the process of preparing biochar, wherein iron is incorporated in a specific ratio, to form the iron-based biochar material with a special structure and function. The material has a simple preparation process, low cost and a short production period; the prepared iron-based biochar material has an unique effect on the arsenic-cadmium combined pollution soil remediation, can effectively reduce the bioavailability of arsenic and cadmium in the soil, significantly reduces the arsenic and cadmium contents in the agricultural products planted in the arsenic-cadmium combined pollution soil, and has no toxic and side effects on the crops, is safe to apply and can be applied to the control of arsenic-cadmium combined pollution soil in a large scale.

Iron-based biochar material, preparation therefor and use thereof in soil pollution control

The present invention discloses a selenium-doped nano-silica sol capable of both inhibiting the absorption and accumulation of heavy metal in rice and producing a selenium-rich rice, and a preparation method thereof. The selenium-doped nano-silica sol of the present invention is prepared mainly by using a nano-silica sol as a carrier, sodium selenite and the like as a raw material, vitamin C and the like as a reducing agent, and polyvinylpyrrolidone and the like as an emulsifier, and doping and dispersing selenium in a specific ratio in a silica sol so as to form a selenium-doped nano-silica sol with a special structure and function. The selenium-doped nano-silica sol prepared according to the invention has high stability and high concentration, and is uniform and transparent, and has a silica content of up to 20% or more, a selenium content of up to 1% or more, and low impurity content. The selenium-doped nano-silica sol of the present invention has a pH close to neutral, wherein selenium, in a nano particle form, is dispersed in colloidal silica, with a particle size of less than 50 nm; and after the foliar application, it can significantly promote the growth of crops, inhibit the absorption and accumulation of arsenic and cadmium in crops, and increase the selenium content in crops, and has no toxic and side effects on crops, and is safe to application.

Selenium-doped nano silica sol used for producing selenium-enriched rice and capable of suppressing absorption and accumulation of heavy metals in paddy rice and preparation method therefor

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Guangzhou, China

Jianghu Cui