Indiana University

Other

Lubrizol Advanced Materials, Inc.

Jian Xie

Qiwei Lu

Donald A Meltzer

Jie Chen

Yaobin Chen

Yona Eckstein

Feina Cao

Lingxi Li

Le Xin

Zhe-Fei Li

Meixian Wang

Yadong Liu

Tesham Gor

Lihong Huang

An improved nanocomposite cathode material for lithium-ion batteries and method of making the same. The nanocomposite cathode material includes lithium iron silicate based nanoparticles with a conductive matrix of graphene sheets. The nanoparticles may be doped with at least one anion or cation.

Lithium silicate cathodes for lithium-ion batteries

An improved nanocomposite cathode material for lithium-ion batteries comprising vanadium pentoxide substrates with a conductive matrix of graphene sheets and a network former such as silicon dioxide and a method of making the same.

Graphene and network former-modified vanadium pentoxide silicon dioxide cathodes for lithium-ion batteries

Cathode active materials for lithium-ion batteries comprise a hybrid nanocomposite of graphene and copper fluoride. Such cathode active materials are used, together with a polymeric binder material and optionally a conductive additive to form a cathode for a lithium-ion battery. Methods of producing hybrid nanocomposites of graphene and copper fluoride include hydrothermally reacting functionalized graphene, such as graphene oxide, and precursors of copper fluoride, such as aqueous fluorosilicic acid. Such hydrothermal reactions include sequential heating and freeze drying steps to produce a CuF-graphene nanocomposite.

Ultra-high specific energy cathode materials for lithium-ion batteries and methods for producing the same

A catalyst comprising a functionalized substrate having a first charged functional group, a metal dispersed on the substrate, wherein the metal comprises at least one of Pt, Rh, Pd, Ag, Au, Ni, Os, Ir, Mn, Co, alloys thereof, oxides thereof, or mixtures thereof, and an ionomer are disclosed. Methods manufacturing a functionalized catalyst comprising catalyzing a substrate with a metal, functionalizing the catalyzed substrate with a first charged functional group, and add an ionomer to the loaded functionalized catalyst are also disclosed. Also, methods comprising catalyzing a substrate with a metal, functionalizing the substrate with a first charged functional group, and adding an ionomer to the loaded functionalized catalyst are disclosed.

Ionomer/catalyst interface

A device for extending the life of a battery, including an electrode having a metal portion, wherein the metal portion is selected from the group including lithium, calcium, magnesium, sodium, potassium and combinations thereof, an electrolyte permeable membrane, and a metal dendrite seeding material disposed between the electrode and the membrane. The electrode, the membrane and the metal dendrite seeding material are positioned in an electrolyte matrix. At least one dendrite extends from the electrode toward the electrolyte permeable membrane combines with at least one dendrite extending from the dendrite seeding material.

Rechargeable alkaline metal and alkaline earth electrodes having controlled dendritic growth and methods for making and using same

Functionalized graphene comprising graphene, a metal dispersed throughout the graphene, wherein the metal comprises Pt, Rh, Pd, Ag, Au, Ni, Os, Ir, alloys thereof, oxides thereof, or mixtures thereof, and a first functional group covalently bonded to the graphene, wherein the first functional group comprises sulfonate, SO, Carboxylate, COO, a tertiary amine, NR, where R is H, alkyl, aryl, or combinations thereof, polybenzimidazole (PBI), poly(ethylene oxide) (PEO), polyphenylene oxide (PPO), polyaniline, or mixtures thereof are disclosed. Methods of manufacture are also disclosed.

Systems and methods of graphene supported catalysts

A method for synthesizing a graphene-polyaniline hybrid composite, including oxidatively exfoliating natural graphite flakes to yield a graphene body, functionalizing the surface of a graphene substrate with aniline groups wherein the surface of the graphene body is functionalized with aniline groups via a diazonium reaction, and polymerizing the aniline groups, wherein covalently-grafted polyaniline-graphene nanocomposites are formed by in-situ polymerization of aniline in the presence of aniline-functionalized graphene oxide, an oxidant, and an acid dopant.

Covalently-grafted polyaniline on graphene oxide sheets and its application in electrochemical supercapacitors

A method for producing a graphene-composite material, including removing any oxide layer from each of a plurality of silicon nanoparticles, forming a polyaniline layer over each clean silicon nanoparticle, binding a graphene oxide sheet to the polyaniline layer of each particle, and carbonizing the polyaniline to yield a plurality of composite particles. Each composite particle has a graphene outer layer substantially encapsulating a silicon inner core.

Carbonized polyaniline-grafted silicon nanoparticles encapsulated in graphene sheets for li-ion battery anodes

A carbon composite material, including a plurality of spaced graphene sheets, each respective sheet having opposed generally planar surfaces, and a plurality of functionalized carbonaceous particles. At least some functionalized carbonaceous particles are disposed between any two adjacent graphene sheets, and each respective at least some functionalized carbonaceous particle is attached to both respective any two adjacent graphene sheets. Each respective graphene sheet comprises at least one layer of graphene and at least portions of respective any two adjacent graphene sheets are oriented substantially parallel with one another.

High surface area nano-structured graphene composites and capacitive devices incorporating the same

Rechargeable alkaline metal and alkaline earth electrodes having controlled dendritic growth and methods for making and using the same

A method of extending the life of a battery, including positioning a dendrite seeding material in an electrolyte solution disposed between a metal-containing electrode and an electrolyte permeable separator membrane, growing metal dendrites from the lithium dendrite seeding material toward the lithium-containing electrode, and contacting metal dendrites extending from the metal containing electrode with metal dendrites extending from the metal dendrite seeding material, wherein the electrolyte contains metal ions.

An method of producing an electronic device, including identifying a graphene sheet, functionalizing the graphene sheet to yield a functionalized sheet, attaching respective vanadium oxide molecules to respective functional groups to define an impregnated graphene sheet, removing organic solvents from the impregnated graphene sheet to define a composite sheet, and positioning the composite sheet onto a metallic substrate to yield a capacitor.

Graphene supported vanadium oxide monolayer capacitor material and method of making the same

Systems, apparatuses and methods for detecting internal cell faults using online and real-time sensing techniques, and providing an accurate and reliable early warning for the incoming failure of battery cells hours or days prior to failure. A system is configured to perform real-time and direct measurement of battery cell parameters of temperature, voltage, and AC impedance through online sensing. These parameters may be simultaneously processed using advanced probabilistic and/or fuzzy logic-based algorithms to provide an early warning for the incoming failure of battery cells in a battery pack. This technology may safeguard the LIB battery packs while allowing them to operate at or near 100% capacity in both transportation and stationary applications.

Growing community of inventors

Carmel, IN, United States of America

Jian Xie