Kingfa Sci.&tech.co., Ltd.

Zhuhai Wango Chemical Co., Ltd.

Tianjin Kingfa New Material Co., Ltd.

Other

Kingfa Science & Technology Co., Ltd.

Shanghai Kingfa Science & Technology Co., Ltd

Yang, Hongmei

Jian Jiao

Hui Yang

Xianbo Huang

Wei Zhao

Xiangbin Zeng

Tongmin Cai

Xueteng Dong

Kai Xiong

Kaijin Mai

Zhimin Yuan

Changli Lu

Renxu Yuan

Yuke Zhong

Zhilong Guo

Meijun Tang

Shiyong Xia

Yibin Xu

Weida Ou

Shihua He

Chunping Ouyang

Weida Qu

The present invention discloses a polylactic acid composite and use thereof. The polylactic acid composite includes the following components: (A) 89 to 98 parts by weight of polylactic acid; (B) 1 to 4 parts by weight of talcum powder; and (C) 1 to 7 parts by weight of a plasticizer. In the component (A), the polylactic acid has a polydispersity index P satisfying the following relationship: 1.55&#x2264;P&#x2264;2.02. In the component (B), the talcum powder has a particle size Dsatisfying: 1 &#x3bc;m&#x2264;D&#x2264;2.6 &#x3bc;m. In the component (C), the plasticizer has a relative molecular weight M satisfying: 180&#x2264;M&#x2264;670. Through research, the present invention has unexpectedly discovered that by using the polylactic acid having the polydispersity index P satisfying the relationship 1.55&#x2264;P&#x2264;2.02 as a matrix, adding a specific range of content of ultrafine talcum powder as a nucleating agent, and selecting the plasticizer of a specific molecular weight as a crystallization promotion agent, the prepared polylactic acid composite has a light transmittance T&#x2265;80%, a haze H&#x2264;40%, and a heat deflection temperature HDT&#x2265;90&#xb0; C., having significantly improved heat resistance and transparency.

Polylactic acid composite and use thereof

The present invention relates to a polylactic acid 3D printing material and a preparation method thereof, which belong to the technical field of polymer materials. The polylactic acid 3D printing material of the present invention comprises the following preparation raw materials in parts by weight: (a) 40-95 parts of crystalline or semi-crystalline polylactic acid, (b) 5-60 parts of noncrystalline polylactic acid, and (c) 0-1.0 parts of a processing aid. In the polylactic acid 3D printing material, a weight of dextral polylactic acid represents 0.5%-8% of a total weight of the polylactic acid. According to the present invention, a polylactic acid 3D printing material with a good aging resistance property can be obtained, by selecting and using two kinds of polylactic acids with different optical purities as raw materials, rationally distributing the proportional relationship between the two, and defining the content of dextral polylactic acid.

Polylactic acid 3D printing material and preparation method thereof

The present invention discloses a biodegradable polyester composition, wherein the biodegradable polyester composition comprises the following components in parts by weight: i) 58 to 80 parts by weight of an aliphatic-aromatic copolyester; ii) 20 to 32 parts by weight of starch; and iii) 0 to 10 parts by weight of a processing agent. The present invention unexpectedly found by research that by using an aliphatic-aromatic copolyester in which an amount of aromatic carboxylic acid accounts for a total amount of diacid is 44 mol % to 48 mol % as a matrix resin, where the aliphatic-aromatic copolyester has a crystallization peak width D of 5&#xb0; C. to 16&#xb0; C., and by using starch of which a particle size D (50) is 2 &#x3bc;m to 12 &#x3bc;m as the other phase, and meanwhile by adding a specific amount of a processing agent, the polyester composition prepared has excellent transversal and longitudinal tear strengths, and the polyester composition has a biodegradation rate of 90% or more during the 12-week degradation test, satisfying the industrial compost.

Biodegradable polyester composition and use thereof

The present invention discloses a PBAT resin composition comprising: (a) Poly (butyleneadipate-co-terephthalate); (b) a cyclic esterified product having a structure represented by the formula (I)  Wherein the content by weight of the cyclic esterified product is from 10 ppm to 2000 ppm, based on the total weight of the PBAT resin composition. In the present invention, the service life of the PBAT resin composition can be greatly extended by adding cyclic esterified product in the PBAT resin composition and controlling the content of the cyclic esterified product in the composition in the range of 10 ppm to 2000 ppm. And after boiled for 240 hours in 95% ethanol at 40&#xb0; C., the film produced from blowing or the articles produced from injection have less surface precipitates, with excellent surface appearance properties.

Composition of PBAT resin

The present invention discloses a PBAT resin composition comprising following components: (a) poly(butyleneadipate-co-terephthalate); (b) iron element; wherein, based on a total weight of the PBAT resin composition, a weight content of the iron element is 1 ppm-500 ppm. By adding iron-containing compounds into the composition and controlling the content of the iron element in a range of 1 ppm-500 ppm in the composition, a speed of reaction of aromatic structure in the PBAT resin under a hot and humid condition can be postponed, so that after the prepared PBAT resin composition is aged in boiling water for 24 hours and 48 hours, a variation of b-value is less than 2. The PBAT resin composition has obviously improved color stability in resistance to boiling water aging.

PBAT resin composition

A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of a cyclic ester compound having a structure shown as formula (I), which is 100 ppm-950 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5 ppm-85 ppm is provided. The cyclic ester compound and cyclopentanone is added into the composition and controlling the content of the cyclic ester compound and the content of cyclopentanone in a certain range in the composition to realize an anti-thermal oxidative aging property of the biodegradable polyester composition. In addition, a film is prepared by blow molding or a part is prepared by injection molding after being digested with 95% ethanol at 40&#xb0; C. for 240 hours. 

Biodegradable polyester composition

The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of glycidyl methacrylate is 0.05 ppm-10 ppm. In the present invention, by adding a trace amount of glycidyl methacrylate into a chosen formula of the biodegradable polyester composition and controlling the weight content of glycidyl methacrylate which finally remains in the biodegradable polyester composition as 0.05 ppm-10 ppm, a compatibility between aliphatic-aromatic polyester and polylactic acid in the biodegradable polyester composition can be greatly enhanced, which enables the biodegradable polyester composition to have excellent surface property of film material, and no fisheye occurs on the film material because of a fluctuation of processing technique.

The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of styrene is 0.1 ppm-30 ppm. When the weight content of styrene which is added into a chosen formula of the biodegradable polyester composition based on the total weight of the biodegradable polyester composition is controlled as 0.1 ppm-30 ppm, the present invention may guarantee the biodegradable polyester composition with excellent transmittance and haze effect, and meanwhile may guarantee the biodegradable polyester composition with suitable UV resistance function, without reducing a degradation rate of the biodegradable polyester composition.

A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of a cyclic ester compound having a structure shown as formula (I) which is 100 ppm-950 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of tetrahydrofuran is 3 ppm-200 ppm is provided. The cyclic ester compound and tetrahydrofuran is added into the composition and controlling the content of the cyclic ester compound and the content of tetrahydrofuran in a certain range in the composition to realize an anti-thermal oxidative aging property of the biodegradable polyester composition. In addition, a film is prepared by blow molding or a part is prepared by injection molding after being digested with 95% ethanol at 40&#xb0; C. for 240 hours. 

A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of tetrahydrofuran, which is 3 ppm-200 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5 ppm-85 ppm is provided. The tetrahydrofuran and cyclopentanone is added into the composition and controlling the content of tetrahydrofuran and the content of cyclopentanone in a certain range in the composition to realize printing performance. Moreover, when a velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2 &#x3bc;m and a relative deviation of the film thickness is less than 1%.

A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of a cyclic ester compound having a structure shown as formula (I), which is 100 ppm-950 ppm is provided. The cyclic ester compound is added into the composition and controlling the content of the cyclic ester compound in a range of 100 ppm-950 ppm to realize an anti-thermal oxidative aging property of the biodegradable polyester composition. In addition, a film is prepared by blow molding or a part prepared by injection molding after being digested with 95% ethanol at 40&#xb0; C. for 240 hours. 

A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of cyclopentanone which is 0.5 ppm-85 ppm is provided. The cyclopentanone is added into the composition and controlling the content of cyclopentanone in the composition within a range of 0.5 ppm-85 ppm to realize a lubrication degree of a film of biodegradable polyester during a blow molding process. When a velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2 &#x3bc;m and a relative deviation of the film thickness is less than 1%.

The present invention relates to a kind of biodegradable polyester and its preparation method, which belongs to the field of biodegradable co-polyester product technology. The number-average molecular weight of the biodegradable polyester material under this invention is 6000-135000 g/mol, the molecular weight distribution is 1.2-6.5, and the range of crystallization temperature is 15&#xb0; C.-105&#xb0; C., which could overcome the disadvantages of existing technical products and can be processed into membrane materials, sheet materials and foam materials. During processing, the picking property will be dramatically changed with the appearance quality improved; after heat resistance is improved, this new type of polyester material could also be applied to the processing course with long cycles, for example, the injection processing course, and the biodegradable aliphatic/aromatic polyester materials provided by this invention has excellent mechanical properties.

Growing community of inventors

Guangdong, China

Jian Jiao