Korea Institute of Science and Technology

Seoul National University

Global Frontier Center for Multiscale Energy Systems

Industry-University Cooperation Foundation Hanyang University

Global Frontier Center for Multiscale Energy S.

Ji-Won Son

Hae-Weon Lee

Jong Ho Lee

Hyoungchul Kim

Byung Kook Kim

Kyung Joong Yoon

Mansoo Park

Jongsup Hong

Hae-Ryoung Kim

Jong-Ho Lee

Seung-Hwan Lee

Jeong Hun Kim

Man Soo Choi

Ho Il Ji

Sung Soo Shin

Joo-Sun Kim

Hue-Sup Song

Hyoung-Chul Kim

Hwa-Young Jung

Seung Yong Lee

Junseok Kim

Sangbaek Park

Hun-Gi Jung

Sung Jun Choi

Eu Deum Jung

Sungeun Yang

Jong Cheol Kim

Yun Jung Lee

Hae June Je

Bin Na Yoon

Thieu Cam Anh

Eun Oak Oh

Sung-Il Lee

Ji-su Shin

Ho-Sung Noh

Sung-Moon Kim

Kyung-ryul Lee

Jisu Shin

Disclosed is a method of manufacturing a solid oxide fuel cell using a calendering process. The method includes preparing a stack including an anode support layer (ASL) and an anode functional layer (AFL), calendering the stack to obtain an anode, stacking an electrolyte layer on the anode to obtain an assembly, calendering the assembly to obtain an electrolyte substrate, sintering the electrolyte substrate, and forming a cathode on the electrolyte layer of the electrolyte substrate.

Method of manufacturing solid oxide fuel cell using calendaring process

The present invention presents a method for manufacturing a negative electrode of a solid oxide cell in a three-dimensional structure by using a pressurization process. In addition, the present invention proposes a structure in which the entire interface of a solid oxide cell is manufactured on the manufactured three-dimensional negative electrode substrate, through various deposition methods, in a three-dimensional structure so as to maximize a reaction area.

Method for manufacturing solid oxide cell having three-dimensional ceramic composite interface structure

Disclosed is a method for infiltrating a porous structure with a precursor solution by means of humidification. The infiltration method with a precursor solution using moisture control comprises the steps of: (S1) providing a substrate having porous structures deposited thereon; (S2) depositing, by electrospraying, a precursor solution on the substrate having porous structures deposited thereon; (S3) humidifying the porous structures having the precursor solution deposited thereon; and (S4) sintering the humidified porous structures.

Method for infiltrating with precursor solution using moisture control

The present disclosure relates to a nanocatalyst for an anode of a solid oxide fuel cell and a method for preparing the same. More particularly, the present disclosure relates to a nanocatalyst for an anode of a solid oxide fuel cell obtained by forming a ceramic nanocatalyst including a noble metal dispersed therein in an atomic unit and contained in an ionic state having an oxidation number other than 0 through an in situ infiltration process in the internal pores of a porous electrode, and to application of the nanocatalyst to a solid oxide fuel cell having significantly higher electrochemical characteristics as compared to the solid oxide fuel cells including the conventional nickel-based anode and oxide anode, and particularly showing excellent characteristics at an intermediate or low temperature of 600&#xb0; C. or less.

Nanocatalyst suitable for an anode of a solid oxide fuel cell

The present invention relates to a lithium-ion-conductive sulfide-based solid electrolyte which contains lithium (Li), sulfur (S), phosphorus (P), indium (In) and selenium (Se) and has a crystal structure of InSe and a method for preparing the same.

Lithium ion conductive sulfide-based solid electrolyte comprising indium selenide and a method for preparing the same

Provided is a solid oxide cell including a fuel electrode layer, electrolyte layer and an air electrode layer, wherein a diffusion barrier layer is provided between the air electrode layer and the electrolyte layer, the diffusion barrier layer includes: a first diffusion barrier layer formed on the electrolyte layer and including a sintered ceria-based metal oxide containing no sintering aid; and a second diffusion barrier layer formed on the first diffusion barrier layer and including a sintered product of a ceria-based metal oxide mixed with a sintering aid, the first diffusion barrier layer includes a sintered product of nanopowder and macropowder of a ceria-based metal oxide, and the first diffusion barrier layer and the second diffusion barrier layer are sintered at the same time. The diffusion barrier layer is densified, shows high interfacial binding force and prevents formation of a secondary phase derived from chemical reaction with the electrolyte.

High temperature solid oxide cell comprising diffusion barrier layer and method for manufacturing the same

Provided is a method for manufacturing a sintered body for an electrolyte and an electrolyte for a fuel cell using the same. More particularly, the following disclosure relates to a method for preparing an electrolyte having a firm thin film layer by using a sintered body having controlled sintering characteristics, and application of the electrolyte to a solid oxide fuel cell. It is possible to control the sintering characteristics of a sintered body through a simple method, such as controlling the amounts of crude particles and nanoparticles. In addition, an electrode using the obtained sintered body having controlled sintering characteristics is effective for forming a firm thin film layer. Further, such an electrolyte having a firm thin film layer formed thereon inhibits combustion of fuel with oxygen when it is applied to a fuel cell, and thus shows significantly effective for improving the quality of a cell.

Manufacturing method of sintered body for electrolyte and electrolyte for fuel cell using the same

Provided is an interlayer for a thin electrolyte solid oxide cell, a thin electrolyte solid oxide cell including the same, and a method of forming the same. In various embodiments, functional elements (a fuel electrode, an electrolyte and a cathode) of the solid oxide cell are formed by means of a thin film process, and thus a nanostructure of the catalyst is not seriously lost due to agglomeration, different from a powder process. Thus, it is possible to accomplish catalyst activation according to a high specific surface area.

Catalyst interlayer for the fuel electrode of thin electrolyte solid oxide cell and method of forming the same

Disclosed is a metal separator for a solid oxide regenerative fuel cell coated with a conductive spinel oxide film. In the conductive spinel oxide film, yttrium is added to a manganese-cobalt spinel oxide to suppress growth of an insulating oxide film on the surface of the metal separator and volatilization of metal. In the conductive oxide film coated on the metal separator, yttrium is segregated at the grain boundaries of the spinel so that migration of oxygen through the grain boundaries can be suppressed. Therefore, the surface of the metal separator can be protected from exposure to the atmosphere and water vapor when the solid oxide regenerative fuel cell is operated at high temperature. In addition, poisoning of electrodes by metal volatilization from the surface of the metal separator and growth of an insulating oxide film on the surface of the metal separator can be prevented. Therefore, the stability of the solid oxide regenerative fuel cell stack can be markedly improved.

Metal separator for solid oxide regenerative fuel cell coated with conductive spinel oxide film, method for producing the same and solid oxide regenerative fuel cell including the same

The present invention relates to a solid oxide fuel cell having a gradient structure in which pore size becomes gradually smaller from a porous electrode to an electrolyte thin film in order to form a dense electrolyte thin film of less than about 2 microns and preferably less than 1 micron on the porous electrode.

Anode-supported solid oxide fuel cell comprising a nanoporous layer having a pore gradient structure, and a production method therefor

The present invention provides a hybrid composite sealant, as a sealing material for a planar type solid oxide fuel cell stack, having a matrix of a glass composition, wherein a surface layer reinforced with platelet reinforcement particles is laminated on either one or both surfaces of an inner layer reinforced with fibrous reinforcement particles. Accordingly, by applying the composite sealant of the present invention to the solid oxide fuel cell stack, excellent gas-tightness of the stack can be obtained even under low coupling pressure, thermal cycling durability can be enhanced due to low coupling strength with a contact surface of an object to be sealed, stack disassembly and maintenance can be facilitated when parts within the stack are disabled, and stack stability as well as stack performance can be maintained under a pressurized operation condition where pressure differentials between the inside and outside of the stack reach to 5 atmospheric pressures (0.5 MPa).

Hybrid sealing composite for flat solid oxide fuel cell stack

A metal oxide thin film structure for a solid oxide fuel cell, prepared by a method comprising dispersing a metal oxide nanopowder in a metal oxide salt solution and subsequent coating of the resulting metal oxide powder dispersed sol and the metal oxide salt solution on a porous substrate, has excellent gas impermeability, excellent phase stability, and is devoid of cracks or pinholes.

Method for preparing metal oxide sol, method for preparing metal oxide thin film using said sol, and solid oxide fuel cell comprising said thin film

Disclosed is a paste for screen printing which is used in the fabrication of an anode functional layer, an electrolyte layer, or a cathode layer of an anode-supported solid oxide fuel cell. The paste contains a raw material powder, ethyl cellulose alpha terpineol, and an alcoholic solvent in which a thermosetting binder is soluble. Also provided is a method of fabricating an anode-supported solid oxide fuel cell using the paste. Thus, a reliable high-performance, large area solid oxide fuel cell that can be economically and efficiently fabricated is provided.

Paste for solid oxide fuel cells, anode-supported solid oxide fuel cells using the same, and fabricating method thereof

Growing community of inventors

Seoul, South Korea

Ji-Won Son