Lg Chem, Ltd

Lg Energy Solution, Ltd.

Ji Hoon Ryu

Wang Mo Jung

Chi Ho Jo

Sang Wook Lee

Byung Chun Park

Sun Sik Shin

Min Suk Kang

Sang Min Park

Hong Kyu Park

Gi Beom Han

Ju Kyung Shin

Sang Seung Oh

Jung Pil Lee

Eun Bee Kim

Hyun Kuk Noh

Song Yi Han

Suk Woo Lee

Sung Joong Kang

Seok Koo Kim

Ji Eun Lee

Dong Hun Lee

Eun Ju Lee

Dong Hwi Kim

Dae Jin Lee

Soon Ju Choi

Ji Hye Kim

Seong Hoon Kang

Ki Tae Kim

Hyun Min Kim

Rae Hwan Jo

Dong Myung Kim

Jung Min Han

Eun Sol Lho

Ki Won Sung

An all-solid-state secondary battery according to the present invention includes a positive electrode, a negative electrode, and a solid electrolyte formed between the positive electrode and the negative electrode, wherein the negative electrode is formed through a pre-lithiation process in which a powder mixture configured to form the negative electrode contacts lithium metal before battery assembly. Irreversible capacity is removed through the pre-lithiation process, whereby initial efficiency of the battery is improved, and the process is simplified, whereby mass production is possible and cost is reduced.

Method of pre-lithiating negative electrode for all-solid-state secondary batteries and secondary battery using the same

A secondary battery according to an embodiment of the present disclosure may include an electrode assembly and a pouch-type batter. The battery case may include a cup part to accommodate electrode assembly. A sealing part may extend outward from an edge of the cup part and may be sealed. A venting device may be inserted into the sealing part through which a gas inside the cup part may be discharged to the outside. The sealing part may include a vent sealing portion into which the venting device may be inserted, and a weak sealing portion which may be positioned between the vent sealing portion and the cup part and sealed more weakly than the periphery thereof.

Secondary battery and sealing block

In the present invention, a slurry for a second cathode mixture is applied to both edge regions of an electrode sheet holing portion during storage of an electrode sheet having a high content of nickel, wherein the edge regions are vulnerable to moisture penetration and high in rolling reduction ratio and the slurry contains a cathode active material more resistant to rolling than that applied to the center region of the holding portion, whereby the reactivity of nickel and moisture is suppressed as much as possible to improve the lifespan characteristics of the battery.

High-nickel electrode sheet having reduced reactivity with moisture and manufacturing method therefor

Disclosed is a method of manufacturing a negative electrode for all-solid-state batteries, the method including (a) preparing a powder mixture including a negative electrode active material, a solid electrolyte, and a conductive agent, (b) introducing the powder mixture into a reactor, (c) introducing an electrolytic solution into the reactor, and (d) forming a solid electrolyte interface (SEI) film while rotating the reactor, wherein the inner surface of the reactor is treated with lithium metal.

Method of manufacturing negative electrode for all-solid-state batteries

Disclosed is an all-solid-state battery comprising an electrode assembly and a solid electrolyte, wherein the electrode assembly comprises a structure in which plate-shaped electrodes are stacked; and the electrodes include a relatively high heat-generating first electrode and a relatively low heat-generating second electrode, wherein the first electrode is disposed in a center of the electrode assembly, the all-solid-state battery with improved performance by increasing the temperature of the battery without adding additional members.

All-solid-state batteries comprising composite electrode

The present invention relates to an electrode sheet comprising: a first cathode mixture layer which is formed in a central portion of a holding part and contains a first cathode active material of lithium nickel cobalt manganese oxide; and a second cathode mixture layer which is formed at one end or both ends of the first cathode mixture layer and contains a second cathode active material lower in nickel content than the first cathode active material, wherein a rolling density b of the second cathode mixture layer is lower than a rolling density a of the first cathode mixture layer, whereby the electrode sheet has the effect of improving the energy density while suppressing a reaction with water.

High-nickel electrode sheet and method for manufacturing same

The present invention relates to a method for manufacturing a secondary battery and a secondary battery. The method for manufacturing the secondary battery comprises an accommodation step of accommodating an electrode assembly in an accommodation part of a battery case, a vent membrane mounting step of mounting a vent membrane on a discharge hole, which passes between the inside and outside of the battery case, in the battery case, and a case sealing step of sealing the battery case, wherein the vent membrane allows only a gas to pass through the discharge hole of the battery case, but blocks a liquid.

Method for manufacturing secondary battery and secondary battery

The present invention relates to a method of manufacturing a secondary battery with improved resistance. According to the present invention, since the electrode assembly with succinonitrile interposed at the interface between the electrode and the separator is manufactured and then laminated, a high-pressure process is not required during lamination compared to the prior art, thereby improving processability, and since succinonitrile is dissolved in the electrolyte solution, it exhibits an effect of improving the resistance of the battery.

Method for manufacturing secondary battery with improved resistance

The present invention provided a positive electrode active material for a lithium secondary battery including lithium cobalt oxide particles. The lithium cobalt oxide particles include lithium deficient lithium cobalt oxide having Li/Co molar ratio of less than 1, belongs to an Fd-3m space group, and having a cubic crystal structure, in surface of the particle and in a region corresponding to a distance from 0% to less than 100% from the surface of the particle relative to a distance (r) from the surface to the center of the particle. In the positive electrode active material for a lithium secondary battery according to the present invention, the intercalation and deintercalation of lithium at the surface of a particle may be easy, and the output property and rate characteristic may be improved when applied to a battery. Accordingly, good life property and the minimization of gas generation amount may be attained even with large sized positive electrode active material.

Positive electrode active material for lithium secondary battery, method of preparing the same and lithium secondary battery including the same

The present invention relates to a method for recovering a positive electrode active material from a lithium secondary battery including: 1) separating a positive electrode into a collector and a positive electrode part; 2) removing an organic substance by firing the separated positive electrode part; 3) washing the fired resultant and removing remaining fluorine (F); 4) adding a lithium-containing material into the washed resultant and firing to recover a lithium transition metal oxide.

Method for recovering positive electrode active material from lithium secondary battery

The present invention provided a positive electrode active material for a lithium secondary battery including lithium cobalt oxide particles. The lithium cobalt oxide particles include lithium deficient lithium cobalt oxide having Li/Co molar ratio of less than 1, belongs to an Fd-3m space group, and having a cubic crystal structure, in surface of the particle and in a region corresponding to a distance from 0% to less than 100% from the surface of the particle relative to a distance (r) from the surface to the center of the particle. In the positive electrode active material for a lithium secondary battery according to the present invention, the intercalation and deintercalation of lithium at the surface of a particle may be easy, and the output property and rate characteristic may be improved when applied to a battery.

The present invention relates to positive electrode active material particles and a secondary battery including the same and provides positive electrode active material particles comprising: a core including a first lithium transition metal oxide; and a shell surrounding the core, wherein the shell has a form in which metal oxide particles are embedded in a second lithium transition metal oxide, and at least a part of the metal oxide particles is present by being exposed at a surface of the shell. The positive electrode active material particles according to the present invention prevent a transition metal and an electrolyte from causing a side reaction by exposing a part of a metal oxide, having low reactivity, at a surface of the active materials, thereby improving safety and lifespan. As the electrical conductivity of the active materials becomes lower, excellent stability can be maintained even at high temperature and in battery-breakdown situations.

Positive electrode active material particles and secondary battery including same

A method for positive electrode active material for a secondary battery includes preparing a precursor by reacting a nickel raw material, a cobalt raw material and an M1 raw material; forming a first surface-treated layer including an oxide of Formula 2 below, on a surface of a core including a lithium composite metal oxide of Formula 1 below, by mixing the precursor with a lithium raw material and an M3 raw material, firing the resultant mixture; and forming a second surface-treated layer including a lithium compound of Formula 3 below, on the core with the first surface-treated layer formed thereon,LiNiCoM1M3M2O&#x2003;&#x2003;[Formula 1]LiM4O&#x2003;&#x2003;[Formula 2]LiM5A&#x2003;&#x2003;[Formula 3]wherein, in Formulae 1 to 3, A, M1 to M5, a, x, y, z, w, m, n, p, and q are the same as those defined in the specification.

Positive electrode active material for secondary battery, and secondary battery including the same

The present invention provides a positive electrode active material for a secondary battery, the positive electrode active material being a secondary particle that includes a primary particle having a rectangular parallelepiped shape, the rectangular parallelepiped having at least one portion of vertices and edges formed in a round shape that is convex outward, wherein 1% to 40% of a total surface area of the secondary particle has open porosity, and the primary particle includes a lithium composite metal oxide of Formula 1 herein so that intercalation and deintercalation of lithium are facilitated, elution of an active material-constituting metal element is suppressed, and excellent structural stability is exhibited, thereby decreasing resistance and improving output and lifespan characteristics when applied to a battery, and a secondary battery comprising the same.

Positive electrode active materials for secondary battery and secondary battery comprising the same

The present invention relates to a positive electrode active material for a secondary battery and a secondary battery including the same, wherein the positive electrode active material includes a core, a shell disposed to surround the core, and a buffer layer which is disposed between the core and the shell and includes pores and a three-dimensional network structure connecting the core and the shell, wherein the core, the shell, and the three-dimensional network structure of the buffer layer each independently includes a polycrystalline lithium composite metal oxide of Formula 1 including a plurality of grains, and the grains have an average grain diameter of 50 nm to 150 nm.

Growing community of inventors

Daejeon, South Korea

Ji Hoon Ryu