Sk Innovation Co., Ltd.

Sk Global Chemical Co., Ltd.

Snu Rdb Foundation

Samhwa Capacitor Co., Ltd.

Ji Chul Jung

In Kyu Song

Tae Jin Kim

Seung Hoon Oh

Hee Soo Kim

Young Min Chung

Seong Jun Lee

Ho Won Lee

Yong Seung Kim

Young Joo Oh

Jung Rag Yoon

Ahn Seop Choi

Yong Tak Kwon

Jong Heop Yi

Yoon Jae Lee

The present invention relates to a zinc ferrite catalyst, a method of producing the same, and a method of preparing 1,3-butadiene using the same. Specifically, the present invention relates to a zinc ferrite catalyst which is produced in a pH-adjusted solution using a coprecipitation method, a method of producing the same, and a method of preparing 1,3-butadiene using the same, in which the 1,3-butadiene can be prepared directly using a C4 mixture including n-butene and n-butane through an oxidative dehydrogenation reaction. The present invention is advantageous in that 1,3-butadiene can be obtained at a high yield directly using a C4 fraction without performing an additional process for separating n-butene, as a reactant, from a C4 fraction containing impurities.

Zinc ferrite catalysts, method of preparing thereof and method of preparing 1,3-butadiene using thereof

A method of preparing multicomponent bismuth molybdate catalysts composed of four metal components and a method of preparing 1,3-butadiene using the catalyst, and particularly, to multicomponent bismuth molybdate catalysts composed of a divalent cationic metal, a trivalent cationic metal, bismuth and molybdenum, a preparation method thereof, and a method of preparing 1,3-butadiene from a C4 mixture including n-butene and n-butane using oxidative dehydrogenation are described.

Method of preparing multicomponent bismuth molybdate catalysts comprising four metal components and method of preparing 1,3-butadiene using said catalysts

Provided is a preparation method of a metal oxide doped monolith carbon aerogel for a high capacitance capacitor, the including: preparing a monolith carbon aerogel by performing a thermal decomposition of a moist gel dried in condition of a atmospheric pressure and a room temperature in a nitrogen atmosphere; impregnating the monolith carbon aerogel into alcohol where a metal precursor is dissolved; and calcinating the monolith carbon aerogel where the metal precursor is impregnated in an atmospheric atmosphere. By impregnating the metal oxide into the monolith carbon aerogel, a limit of capacitance may be enhanced using a pseudo capacitance effect by an interfacial oxidation reduction reaction.

Preparation method of metal oxide doped monolith carbon aerogel for capacitance capacitor

This invention relates to a method of preparing a multicomponent bismuth molybdate catalyst by changing the pH of a coprecipitation solution upon coprecipitation and a method of preparing 1,3-butadiene using the catalyst. The multicomponent bismuth molybdate catalyst, coprecipitated using a solution having an adjusted pH, the preparation method thereof, and the method of preparing 1,3-butadiene through oxidative dehydrogenation using a C4 mixture including n-butene and n-butane as a reactant are provided. The C4 raffinate, containing many impurities, is directly used as a reactant without an additional process for separating n-butane or extracting n-butene, thus obtaining 1,3-butadiene at high yield. The activity of the multicomponent bismuth molybdate catalyst can be simply increased through precise pH adjustment upon coprecipitation, which is not disclosed in the conventional techniques. This method can be applied to the increase in the activity of multicomponent bismuth molybdate catalysts reported in the art.

Method of preparing multicomponent bismuth molybdate catalysts with controlling pH and a method of preparing 1,3-butadiene using thereof

A method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a continuous-flow dual-bed reactor designed such that two kinds of catalysts charged in a fixed-bed reactor are not physically mixed. More particularly, a method of producing 1,3-butadiene by the oxidative dehydrogenation of n-butene using a C4 mixture including n-butene and n-butane as reactants and using a continuous-flow dual-bed reactor in which a multi-component bismuth molybdate catalyst and a zinc ferrite catalyst having different reaction activity in the oxidative dehydrogenation reaction of n-butene isomers (1-butene, trans-2-butene, cis-2-butene).

Method of producing 1,3-butadiene from N-butene using continuous-flow dual-bed reactor

This invention relates to a bismuth molybdate catalyst, a preparation method thereof, and a method of preparing 1,3-butadiene using the same, and to a bismuth molybdate catalyst, a preparation method thereof, and a method of preparing 1,3-butadiene using the same, in which 1,3-butadiene can be prepared through oxidative dehydrogenation directly using a C4 mixture including n-butene and n-butane as a reactant in the presence of a mixed-phase bismuth molybdate catalyst including &#x3b1;-bismuth molybdate (Bi2Mo3On) and &#x3b3;-bismuth molybdate (Bi2MoO6). According to this invention, the C4 raffinate, containing many impurities, is used as a reactant, without an additional n-butane separation process, thus obtaining 1,3-butadiene at high yield. Unlike complicated multicomponent-based metal oxides, the catalyst of the invention has simple constituents and synthesis routes, and can be easily formed through physical mixing, and thus is very advantageous in assuring reproducibility and can be directly applied to commercial processes.

Bismuth molybdate-based catalysts, method of preparing thereof and method of preparing 1,3-butadiene using thereof

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Seoul, South Korea

Ji Chul Jung