Lanxess Corporation

Arlanxeo Singapore Pte. Ltd.

Lanxess International Sa

Arlanxeo Canada Inc.

Jessica Watson

Gilles J Arsenault

Paul Nguyen

Steven John Teertstra

Gregory J E Davidson

Kevin Kulbaba

Ralf-Ingo Schenkel

Thomas Foellinger

A copolymer has low levels of cyclic oligomeric compounds, which are undesirable impurities in certain applications. The cyclic oligomeric compounds are provided in an advantageously low ratio of C21/C13 oligomers. The C13 oligomers are extractable using steam to further reduce the total amount of cyclic oligomers. A process for producing the copolymer having low levels of cyclic oligomers involves contacting at least one isoolefin monomer with at least one multiolefin and/or &#x3b2;-pinene monomer in the presence of at least one Lewis acid and at least one initiator in a diluent. The diluent contains a hydrofluorinated olefin (HFO) comprising at least three carbon atoms and at least three fluorine atoms. Hydrofluorinated olefins used in the present invention are better diluents for butyl slurry cationic polymerization than saturated hydrofluorocarbons.

Copolymer having low cyclic oligomer content

A copolymer has high levels of multolefin incorporation. A process for producing the copolymer having high levels of multiolefin incorporation involves contacting at least one isoolefin monomer with at least one multiolefin and/or &#x3b2;-pinene monomer in the presence of at least one Lewis acid and at least one initiator in a diluent. The diluent contains a hydrofluor-Mated olefin (HFO) comprising at least three carbon atoms and at least three fluorine atoms. Hydrofluorinated olefins used in the present invention are better diluents for butyl slurry cationic polymerization than saturated hydro-fluorocarbons.

Copolymer having high multiolefin content

The invention relates to an efficient polymerization process and its use to produce novel copolymers with a specific micro structure. In particular, the invention relates to butyl rubbers with novel micro structure, preferably those obtainable by copolymerization of monomer mixtures comprising isobutylene and isoprene in diluents comprising 2,3,3,3 -tetrafluoro-1-propene. In a further aspect the invention relates to halogenated copolymers obtainable from such novel copolymers by halogenation.

2,3,3,3-tetrafluoro-1-propene as diluent for the preparation of novel butyl rubbers

A copolymer has low levels of isoprenoid (short chain branching) structures. A process for producing the copolymer having low isoprenoid content involves contacting at least one isoolefin monomer with at least one multiolefin and/or &#x3b2;-pinene monomer in the presence of at least one Lewis acid and at least one initiator in a diluent. The diluent may contain a hydrofluorinated olefin (HFO) comprising at least three carbon atoms and at least three fluorine atoms. Hydrofluorinated olefins used in the present invention are better diluents for butyl slurry cationic polymerization than saturated hydrofluorocarbons. Blends of saturated hydrofluorocarbons (e.g. 1,1,1,2-tetrafluoroethane) with an inert solvent (e.g. methyl chloride) may also be used as diluents.

Copolymer having low isoprenoid content

A process for producing a copolymer involves contacting at least one isoolefin monomer with at least one multiolefin and/or &#x3b2;-pinene monomer in the presence of at least one Lewis acid and at least one initiator in a diluent. The diluent contains a hydrofluorinated olefin (HFO) comprising a tetrafluorinated propene. Copolymers produced by a process of the present invention have a cyclic oligomer content lower than comparable polymers produced in a butyl rubber slurry process using 1,1,1,2-tetrafluoroethane and/or methyl chloride as a diluent as well as a more favorable ratio of C21/C13. Hydrofluorinated olefins used in the present invention are better diluents for butyl slurry cationic polymerization than saturated hydro fluorocarbons.

Hydrofluorinated olefins (HFO's) as diluents for butyl rubber production

The present invention is directed to a method for preparing isobutene from a renewable source and their use in the preparation of renewable polymers. The invention also discloses purification of isobutene, selective removal of 1-butene, cis-2-butene and trans-2-butene using microporous adsorbent material, and the oligomerization of the purified liquid isobutene yielding diisobutenes and triisobutenes.

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London, Canada

Jessica Watson