Lawrence Livermore National Security, LLC

Jeremy Lenhardt

Eric B Duoss

Thomas S Wilson

Lemuel Perez Perez

Sarah Elyse Baker

Joshuah K Stolaroff

Du Nguyen

Jennifer Marie Knipe

Elaine Lee

Maira Ceron Hernandez

Andrew Neil Mabe

Simon Hoching Pang

Jason Philip Brodsky

Matthew A Worthington

Matt Durban

Dominique Henry Porcincula

Xianyi Zhang

An ink includes a siloxane polymer having at least 13 mol. % diphenylsiloxane content relative to the total mol. % of the siloxane polymer, and a filler having a refractive index about matching a refractive index of the siloxane polymer where the refractive indices are within about 5% of one another but are ideally as closely matched as possible.

Transparent 3D printed siloxane elastomers

An ink for forming a scintillator product includes a phenylated siloxane polymer having at least one functional group per molecule for crosslinking, a filler having a refractive index about matching a refractive index of the phenylated siloxane polymer, where the refractive indices are within about 5% of one another, a rheology modifier, and at least one fluorescent dye.

Optically transparent 3D printed polysiloxane scintillators

An ink includes a vinyl-terminated polydimethylsiloxane polymer, a polydimethylsiloxane copolymer having a hydride component, wherein a hydride to a vinyl ratio (hydride:vinyl) is in a range of greater than 1:1 to about 4:1, a hydrophobic filler, a crosslinking agent, and a carbon dioxide-binding component. A method includes extruding an ink for forming a three-dimensional (3D) structure, the ink including a vinyl-terminated polydimethylsiloxane polymer, a polydimethylsiloxane copolymer having a hydride component, wherein a hydride to a vinyl ratio (hydride:vinyl) is in a range of greater than 1:1 to about 4:1, a hydrophobic filler, a crosslinking agent, and a carbon dioxide-binding component. The method further includes curing the 3D structure for forming a silicone polymer product having the carbon dioxide-binding component.

Polymer formulations for extrusion of composite COsorbents

A product of additive manufacturing with a silicone-based ink includes a plurality of continuous filaments comprised of a siloxane matrix, wherein the continuous filaments are arranged in a geometric pattern, a plurality of inter-filament pores defined by the geometric pattern of the continuous filaments, and a plurality of intra-filament pores having an average diameter in a range of greater than 1 micron to less than 50 microns.

Three dimensional porous siloxanes using leachable porogen particles

The silicone-based ink for additive manufacturing includes a siloxane macromer, and a porogen mixture comprising a water-soluble porogen and a surfactant. The product of additive manufacturing with a silicone-based ink includes a three-dimensional printed structure including a plurality of continuous filaments arranged in a predefined pattern and a plurality of inter-filament pores defined by the predefined pattern of the continuous filaments. In addition, each continuous filament of the three-dimensional printed structure includes a silicone matrix having an open cell structure with a plurality of intra-filament pores, and the intra-filament pores form continuous channels through the silicone matrix.

Three-dimensional printed porous silicone matrix using leachable porogen

According to one embodiment, a silicone-based ink for additive manufacturing includes a vinyl-terminated diphenyl siloxane macromer, a treated silica hydrophobic reinforcing filler, a rheology modifying additive, and a plurality of porogen particles. According to another embodiment, a product of additive manufacturing with a silicone-based ink includes a plurality of continuous filaments comprised of a siloxane matrix, where the continuous filaments are arranged in a geometric pattern, a plurality of inter-filament pores defined by the geometric pattern of the continuous filaments, and a plurality of intra-filament pores having an average diameter in a range of greater than 1 micron to less than 50 microns.

Three-dimensional porous siloxanes using leachable porogen particles

In one embodiment, a silicone-based ink for additive manufacturing includes a vinyl-terminated siloxane macromer, a hydrophobic reinforcing filler, and a rheology modifying additive. In another embodiment, a method of additive manufacturing with silicone-based ink includes adding a mixture that includes a vinyl-terminated siloxane macromer, a hydrophobic reinforcing filler, and a rheology modifying additive to a cartridge for additive manufacturing, extruding the mixture through the cartridge to form a structure, and curing the mixture to at least a predefined extent.

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Tracy, CA, United States of America

Jeremy Lenhardt