Lg Chem, Ltd

Toray Industries, Inc.

Toray Battery Separator Film Co., Ltd.

Jeong-Min Ha

Jong-Hun Kim

Sun-Mi Jin

Joo-Sung Lee

Bo-Kyung Ryu

Jin-Woo Kim

Byeong-Gyu Cho

No-Ma Kim

Su-Jin Yoon

Byoung-Jin Shin

Kee-Young Kim

Da-Kyung Han

Jong Hun Kim

Jang-Hyuk Hong

Suk-Ky Chang

In-Cheon Han

Sun Mi Jin

An-Na Lee

Seung-Joon Park

The present invention provides a method for manufacturing a separator, comprising the steps of (S1) preparing a porous planar substrate having multiple pores; (S2) coating a coating solution obtained by dissolving a binder polymer in a solvent and dispersing inorganic particles therein on the porous substrate to form a porous coating layer and drying the porous coating layer; and (S3) applying a binder solution on the surface of the dried porous coating layer to form an adhesive layer, wherein the binder solution has a surface energy of at least 10 mN/m higher than that of the porous coating layer and a contact angle of the binder solution to the surface of the porous coating layer maintained at 80&#xb0; or more for 30 seconds. In accordance with the present invention, a separator capable of obtaining sufficient adhesion force with minimizing the amount of an adhesive used for the adhesion with an electrode, and minimizing the deterioration of battery performances can be easily manufactured.

Method for manufacturing separator, separator manufactured therefrom, and electrochemical device comprising the same

The present invention provides a method of coating a substrate for a lithium secondary battery with inorganic particles, comprising charging the inorganic particles to form charged inorganic particles; transferring the charged inorganic particles on the substrate for a lithium secondary battery to form a coating layer; and fixing the coating layer with heat and pressure. Such a coating method according to one embodiment of the present invention uses electrostatic force without the addition of a solvent, and therefore, non use of a solvent can result in cost-reducing effects since there is no burden on the handling and storing of the solvent, and since a drying procedure after slurry coating is not needed, it allows for the preparation of a lithium secondary battery in a highly effective and rapid manner.

Method of coating substrate for lithium secondary battery with inorganic particles and lithium secondary battery comprising substrate coated by the method

The present invention refers to a separator for an electrochemical device and an electrochemical device having the same. More specifically, the separator of the present invention comprises a porous substrate; a first porous coating layer formed on one surface of the porous substrate and comprising a mixture of inorganic particles and a first binder polymer; and a second porous coating layer formed on the other surface of the porous substrate and comprising a product obtained by drying a mixture of a solvent, a non-solvent and a second binder polymer. Such separator of the present invention can have good thermal safety due to a porous organic-inorganic coating layer formed on one surface thereof, and superior adhesiveness due to a porous coating layer made of a binder thin film formed by applying and drying a mixture of a binder polymer and a non-solvent on the other surface thereof. Also, the separator can have a decreased thickness to reduce the resistance of electrochemical device and improve the capacity thereof.

Separator and electrochemical device having the same

The present disclosure provides a separator comprising a porous substrate, a porous coating layer and a binder layer, the binder comprising at least one homopolymer of polyvinylidene fluoride and at least one copolymer of polyvinylidene fluoride (PVDF)-co-hexafluoropropylene (HFP) so that a content difference of hexafluoropropylene (HFP) present in the two compounds is about 3 wt % or higher.

Separator having binder layer, and electrochemical device comprising the separator and method of preparing the separator

A separator includes a porous substrate, a porous organic-inorganic coating layer formed on at least one surface of the porous substrate, and an organic coating layer formed on the surface of the organic-inorganic coating layer. The porous organic-inorganic coating layer includes a mixture of inorganic particles and a first binder polymer. The first binder polymer contains a copolymer including (a) a first monomer unit including either at least one amine group or at least one amide group or both in the side chain thereof and (b) a (meth)acrylate having a C-Calkyl group as a second monomer unit. The organic coating layer is formed by dispersing a second binder polymer on the surface of the organic-inorganic coating layer, leaving scattered uncoated areas. The porous organic-inorganic coating layer of the separator has a high packing density, enabling the fabrication of a thin battery in an easy manner without losing stability. The porous organic-inorganic coating layer has good ability to bind to the porous substrate, which prevents the inorganic particles from separating from the porous organic-inorganic coating layer. In addition, the organic coating layer enhances the bindability of the separator to an electrode without a substantial increase in resistance.

Separator, method for producing the same and electrochemical device including the same

The present invention provides a separator having a porous substrate; and a porous coating layer formed on one surface of the porous substrate and comprising a mixture of inorganic particles and a binder polymer, which has a value of a porosity&#xd7;an air permeability per thickness in the range of 5 to 40, the porosity and the air permeability per thickness. The separator having a porous coating layer according to the present invention has a porosity which is controlled depending on the air permeability of the porous substrate, and thus exhibit superior ionic conductivity as well as good mechanical properties, thereby contributing to improve the performance and safety of an electrochemical device.

The present invention refers to a separator and an electrochemical device having the same. The separator of the present invention comprises a non-woven fabric substrate obtained from fibers and having multiple pores formed between the fibers; and a polymer coating layer formed on a part or the whole of the surface of the fibers, wherein the polymer coating layer comprises a polymer having a tensile strength of 80 MPa or more, a tensile modulus of 3,000 MPa or more and a flexural modulus of 3,000 MPa or more. The separator of the present invention can reduce costs for manufacturing electrochemical devices, and it can control the size of pores present in the non-woven fabric substrate to prevent the generation of a leak current and provide improved mechanical strength.

A separator may include (A) a porous substrate having pores, and (B) a porous coating layer formed on at least one surface of the porous substrate and made from a mixture of inorganic particles and a binder polymer, and the binder polymer may contain a copolymer of (a) a first monomer unit with at least one of an amine group and an amide group at a side chain, and (b) a second monomer unit of (meth)acrylate with an alkyl group having 1 to 14 carbon atoms. The porous coating layer of the separator may have a high packing density, thereby easily forming a thin film battery without hindering safety, and may have good adhesive strength with the porous substrate, thereby preventing detachment of the inorganic particles in the porous coating layer during assembly of an electrochemical device.

Separator having improved porous coating layer having high packing density and electrochemical device comprising the same

A separator including a porous substrate, and a porous coating layer formed on at least one surface of the porous substrate and including a mixture of inorganic particles and a binder polymer. A continuous or discontinuous patterned layer is formed on the surface of the porous coating layer to allow an electrolyte solution to permeate therethrough. The continuous or discontinuous patterned layer may be formed with continuous grooves to allow an electrolyte solution to permeate therethrough. Due to this structure, the wettability of the separator with an electrolyte solution is improved, shortening the time needed to impregnate the electrolyte solution into the separator.

Separator and electrochemical device comprising the same

A separator includes a porous substrate, a porous organic-inorganic coating layer formed on at least one surface of the porous substrate, and an organic coating layer formed on the surface of the organic-inorganic coating layer. The porous organic-inorganic coating layer includes a mixture of inorganic particles and a first binder polymer. The first binder polymer contains a copolymer including (a) a first monomer unit including either at least one amine group or at least one amide group or both in the side chain thereof and (b) a (meth)acrylate having a C-Calkyl group as a second monomer unit. The organic coating layer is formed by dispersing a second binder polymer on the surface of the organic-inorganic coating layer, leaving scattered uncoated areas.

The present invention provides an electrode comprising a current collector; an electrode active material layer formed on at least one surface of the current collector and comprising a mixture of electrode active material particles and a first binder polymer; and a porous coating layer formed on the surface of the electrode active material layer, comprising a mixture of inorganic particles and a second binder polymer and having a thickness deviation defined by the following Formula (1), and a manufacturing method thereof:()/&#x2266;0.35&#x2003;&#x2003;(1)

Electrode having porous coating layer, manufacturing method thereof and electrochemical device containing the same

The present invention relates to an acrylic pressure-sensitive adhesive composition which comprises a (meth)acrylic copolymer comprising 70 to 95 parts by weight of an alkyl(meth)acrylic acid ester monomer, in which alkyl has 2 to 14 carbon atoms, and 5 to 30 parts by weight of a (meth)acrylic acid ester monomer containing a copolymerizable aromatic group, wherein the composition has a gel fraction of 10 to 55% and a swelling ratio of 30 to 110, and a sol (uncross-linked polymer) eluted therein with a solvent has a weight average molecular weight of 600,000 or more; a polarizing plate comprising the composition; and a liquid crystal display device comprising the same. The composition according to the present invention provides workability such as an excellent durability and re-workability, and has an effect of improving a light leakage phenomenon, since the size of birefringence occurred under stress is very small.

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Daejeon, South Korea

Jeong-Min Ha