Henkel Ag & Company, Kgaa

Jens Krömer

Jan-Willem Brouwer

Frank-Oliver Pilarek

William E Fristad

Peter Kuhm

Matthias Hamacher

Patrick Droniou

Fernando Jose Resano Artalejo

Marc Balzer

Franz-Adolf Czika

Nicole Teubert

Annette Willer

Stephan Winkels

Michael Frank

Roland Popp

Stefan Dietz

Helene Maechel

Thibault Leseur

Silvia Hohagen

Nicole Heischkamp

Udo Irmscher

Karl Manderscheid

Olaf Scheffler

Hans-Bernhard Eppler

Iradj Peirow

A method for recovering demineralized water from zirconium-containing rinse water having a pH lower than 6.0, wherein a) the rinse water has added to it an aqueous solution of Ca(OH)containing no more than 0.1 wt % undissolved Ca(OH), in a quantity such that the pH of the rinse water rises to a value in the range from 6.2 to 8.0, b) a precipitate that forms is separated from the rinse water, and c) the rinse water from which the precipitate was removed in step b) is subjected to an ion exchange method or to reverse osmosis.

Process for obtaining desalted water from zirconium-containing wash water

The invention relates to an aqueous composition and to a method for the anticorrosion conversion treatment of metallic surfaces, particularly metallic materials which are assembled into composite structures, comprising steel or galvanized or alloy-galvanized steel and any combinations thereof, the composite structure being composed at least in part of aluminum or the alloys thereof. The aqueous composition according to the invention is based on a phosphating solution and contains, in addition to water-soluble compounds of zirconium and titanium, a quantity of free fluoride in a ratio that both permits phosphating of the steel and galvanized and/or alloy-galvanized steel surfaces and determines low pickling rates of the aluminum substrate with simultaneous passivation of the aluminum. The metallic materials, components and composite structures conversion treated in accordance with the underlying invention are used in automotive body construction, in shipbuilding, in construction and for the production of white goods.

Zr-/Ti-containing phosphating solution for passivation of metal composite surfaces

The present invention relates to an aqueous composition and to a method for the anticorrosion conversion treatment of metallic surfaces, particularly metallic materials which are assembled into composite structures, comprising steel or galvanized or alloy-galvanized steel and any combinations of these materials, the composite structure being composed at least in part of aluminum or the alloys thereof. The aqueous composition according to the invention is based on a phosphating solution and contains, in addition to water-soluble compounds of zirconium and titanium, a quantity of free fluoride in a ratio that both permits phosphating of the steel and galvanized and/or alloy-galvanized steel surfaces and determines low pickling rates with regard to the aluminum substrate with simultaneous passivation of the aluminum. The metallic materials, components and composite structures conversion treated in accordance with the underlying invention are used in automotive body construction, in shipbuilding, in construction and for the production of white goods.

The invention relates to an acidic, aqueous, chromium-free composition (A) for the anti-corrosive treatment of steel and/or galvanized steel surfaces comprising metal ions (M) selected from ions at least of the elements nickel, cobalt, molybdenum, iron or tin and a multi-stage method applying the composition (A) for the anti-corrosive pre-treatment of metal components which have steel and/or galvanized steel surfaces. The invention further relates to metal surfaces of zinc or iron having a passive layer system comprising at least 30 mg/mnickel and at least 10 mg/mzircon, titanium and/or hafnium and sulfur, wherein nickel is present in metallic form at up to at least 30 At. %, obtainable in a method according to the invention.

Multi-stage pre-treatment method for metal components having zinc and iron surfaces

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Düsseldorf, Germany

Jens Krömer