Nashua Corporation

Battelle Memorial Institute

Advanced Image Resources, LLC

Jeffrey L Clark

Jan Bartus

Bhima Rao Vijayendran

James W Boswell

Albert W Leclair

Jerry L King

Robert Janules

A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The resins were formulated into toner formulations such as those useful in printers and copiers.

Bio-based toner

A method for preparing thermoplastic toner resins is disclosed and the toner resins produced by said method. More particularly, an emulsion polymerized resin, constituting a high molecular weight component, is used as a seed for subsequent suspension polymerization of a lower molecular weight component. The emulsion micelles are swelled with monomers and subsequent suspension polymerization produces particles where the high and low molecular weight components are interpenetrated to form a resin with a bimodal distribution of molecular weight. A toner composition is made using the resin as the main component. The resin particle has a first resin portion having a particle size in the range of about 50 to about 200 nm. and a number average molecular weight in the range of about 10,to about 10,, and a second resin portion formed around the first resin portion with a number average molecular weight lower than that of said first resin portion, the resin having a polydispersity in the range of 5 to 50.

Toner containing resin prepared by a combination of emulsion followed by suspension polymerization

Disclosed are toner compositions which comprise a toner particle having cleaning and lubricating agents added externally thereto. The cleaning and lubricating agents improve copy quality and extend the developer lifetime as they are electrically compatible with the toner particles over the duration of the developer lifetime. The external lubricating additive comprises a modified wax component having a relatively small percentage of a charge enhancing additive dissolved in a low molecular weight wax material. Optionally, the external additive may comprise amorphous silica particles and magnetite particles.

Toner and developer compositions having cleaning and lubricating

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Nashua, NH, United States of America

Jeffrey L Clark