The Standard Oil Company

Jeffrey Earle Rinker

Paul Trigg Wachtendorf

Sanjay Purushottam Godbole

Vincent G Reiling

Joseph C Sarna

Timothy R McDonel

Vincent Astor Little, Iii

Sanjay Parushottam Godbole

James S Gibson

A process for manufacturing acrylonitrile comprising reacting propylene, ammonia and oxygen in a reactor zone in the presence of a catalyst to produce a reactor effluent containing crude acrylonitrile, transferring the reactor effluent containing crude acrylonitrile to a quench column wherein the reactor effluent containing crude acrylonitrile is contacted with an aqueous stream to cool the reactor effluent, transferring the cooled reactor effluent containing the crude acrylonitrile to an absorption column wherein the reactor effluent containing crude acrylonitrile is contacted with a second aqueous stream to separate and remove the crude acrylonitrile as a bottom stream from the absorption column, transferring the bottom stream containing the crude acrylonitrile to a recovery and purification section where the acrylonitrile is recovered and purified, wherein the improvement comprises supplying the second aqueous stream to the absorption column by means of liquid spray nozzles.

Reduced pressure drop in acrylonitrile absorber via direct contact spray

A process for the recovery of acrylonitrile or methacrylonitrile obtained from the reactor effluent of an ammoxidation reaction of propylene or isobutylene comprising passing the reactor effluent through an absorber column and recovery column and stripper column wherein the improvement comprises increasing the recovery column top pressure by mechanical means by about 0.1 to 5 psi to improve the hydraulic capacity of the recovery and stripper columns.

Acrylonitrile recovery process

A process for the recovery of acrylonitrile or methacrylonitrile obtained from the reactor effluent of an ammoxidation reaction of propylene or isobutylene comprising passing the reactor effluent through an absorber column, a first decanter, recovery column, a second decanter and stripper column wherein the improvement comprises maintaining inside temperature of the first and second decanter at between about 32.degree. F. to 75.degree. F.

A process for the reduction in the amount of waste material generated during the manufacture of acrylonitrile comprising introducing an additional amount of oxygen containing gas, preferably air, in the substantial absence of any oxygenate compounds, into the upper portion of the fluid bed reactor to react with at least some of the unreacted ammonia to reduce the amount of unreacted ammonia present in the reactor effluent.

Growing community of inventors

Elida, OH, United States of America

Jeffrey Earle Rinker