Minnesota Mining and Manufacturing Company

Jeffrey E Ford

Robbyn L Engen

Harold E Rude

Douglas S Spencer

Ellen Y Chu

Film-backed and paper-backed coated abrasives and methods of making same are described using coatable urea-aldehyde binder precursor compositions including a urea-aldehyde resin and a cocatalyst, which yield more consistent quality coated abrasives. In addition, the compositions have longer pot life and allow curing at lower temperatures. The urea-aldehyde resins have an aldehyde/urea molar ratio of at least about 1.0, more preferably ranging from about 1.0 to about 2.0, and a free aldehyde content ranging from about 0.1 to about 3.0 weight percent based on weight of total aldehyde. The cocatalyst consists essentially of a Lewis acid and a salt selected from the group consisting of ammonium ion salts and organic amine salts. Paper-backed abrasive articles may employ a fabric nonwoven layer between the abrasive coating and the paper layer to reduce abrasive particle shelling.

Abrasive articles and methods of making same

An abrasive article and methods for making such abrasive articles, including coated and nonwoven abrasive articles, comprising (a) a plurality of abrasive particles and (b) a bond system which adheres the plurality of abrasive particles together, the bond system comprising a binder; the binder being formed from a binder precursor essentially free of organic solvent, the binder precursor comprising a blend of an urea-aldehyde resin and a water dilutable resole phenolic resin, the blend being catalyzed by an acid catalyst system and, in particular, a coated abrasive comprising (a) a backing having a major surface, (b) a plurality of abrasive particles, and (c) a bond system which adheres the plurality of abrasive particles to the major surface of the backing, the bond system comprising a binder; the binder being formed from a binder precursor comprising a blend of an urea-aldehyde resin and a water dilutable resole phenolic resin, the blend being catalyzed by an acid catalyst, wherein the blend comprises from about 5 to about 90 weight percent of the water dilutable resole phenolic resin and from about 95 to about 10 weight percent of the urea-aldehyde resin.

Coatable urea-aldehyde binder precursor compositions including a urea-aldehyde resin and a cocatalyst yield more consistent quality coated abrasives. In addition, the compositions have longer pot life and allow curing at lower temperatures. The urea-aldehyde resins have an aldehyde/urea ratio of at least about 1.0, more preferably ranging from about 1.0 to about 2.0, and a free aldehyde content ranging from about 0.1 to about 3.0 weight percent based on weight of total aldehyde. The cocatalyst consists essentially of a Lewis acid and a salt selected from the group consisting of ammonium ion salts and organic amine salts. Methods of making coated and other abrasive articles using the compositions are also described.

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Woodbury, MN, United States of America

Jeffrey E Ford